Physical Chemistry
Physical Chemistry
2nd Edition
ISBN: 9781133958437
Author: Ball, David W. (david Warren), BAER, Tomas
Publisher: Wadsworth Cengage Learning,
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Chapter 10, Problem 10.63E
Interpretation Introduction

(a)

Interpretation:

The average value of position, x for the given wavefunction is to be evaluated.

Concept introduction:

In quantum mechanics, the wavefunction is given by Ψ. The wavefunction contains all the information about the state of the system. The wavefunction is the function of the coordinates of particles and time. The square of the probability function, |Ψ|2, relates to the probability density.

Expert Solution
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Answer to Problem 10.63E

The average value of position, x for the given wavefunction is 34.

Explanation of Solution

The given wavefunction is Ψ=x.

The normalization constant of the given wavefunction is assumed to be N. Hence, the normalized wavefunction is Ψ=Nx.

The normalization of given wavefunction is done by the formula,

01(Ψ)*Ψdx=1 …(1)

Substitute the value of Ψ in the equation (1).

01(Nx)*Nxdx=1N201x2dx=1N2[x33]01=1N2[1303]=1

Solve the above equation.

N213=1N2=3N=±3

Only positive square roots are taken for normalization constant. Therefore, the normalized wavefunction is Ψ=3x.

The position operator is defined as x().

The average value of x is calculated as,

x=01Ψx^Ψdx …(2)

Where,

x^represents the position operator.

Ψrepresents the wavefunction.

Substitute the value of Ψ and x^ in the equation (2).

x=01(3x)x(3x)dx=301x3dx=3[x44]01=3[(1)44(0)44]

Solve the above expression for the value of x.

x=34

Therefore, the average value of position, x for the given wavefunction is 34.

Conclusion

The average value of position, x for the given wavefunction is 34.

Interpretation Introduction

(b)

Interpretation:

The average value of position, x for the given wavefunction is to be evaluated.

Concept introduction:

In quantum mechanics, the wavefunction is given by Ψ. The wavefunction contains all the information about the state of the system. The wavefunction is the function of the coordinates of particles and time. The square of the probability function, |Ψ|2, relates to the probability density.

Expert Solution
Check Mark

Answer to Problem 10.63E

The average value of position, x for the given wavefunction is 32.

Explanation of Solution

The given wavefunction is Ψ=x.

The normalization constant of the given wavefunction is assumed to be N. Hence, the normalized wavefunction is Ψ=Nx.

The normalization of given wavefunction is done by the formula,

02(Ψ)*Ψdx=1 …(3)

Substitute the value of Ψ in the above formula.

02(Nx)*Nxdx=1N202x2dx=1N202x2+12+1=1N2[x33]02=1

Solve the above equation.

N2[8303]=1N2[83]=1N2=38N=±38

Only positive square root is taken for normalization constant. Therefore, the normalized wavefunction is ψ=38x.

The position operator is defined as x().

The average value of x is calculated as,

x=02Ψx^Ψdx …(4)

Where,

x^represents the position operator.

Ψrepresents the wavefunction.

Substitute the value of Ψ and x^ in the equation (4).

x=02(38x)x(38x)dx=3802x3dx=38[x44]02=38[(2)44(0)44]

Solve the above expression for the value of x.

x=32

Therefore, the average value of position, x for the given wavefunction is 32.

Conclusion

The average value of position, x for the given wavefunction is 32.

Interpretation Introduction

(c)

Interpretation:

The average value of position, x for the given wavefunction is to be evaluated.

Concept introduction:

In quantum mechanics, the wavefunction is given by Ψ. The wavefunction contains all the information about the state of the system. The wavefunction is the function of the coordinates of particles and time. The square of the probability function, |Ψ|2, relates to the probability density.

Expert Solution
Check Mark

Answer to Problem 10.63E

The average value of position, x for the given wavefunction is π2.

Explanation of Solution

The given wavefunction is Ψ=sin2x.

The normalization constant of the given wavefunction is assumed to be N. Hence, the normalized wavefunction is Ψ=Nsin2x.

From Appendix 1,

sin2bxdx=x214bsin(2bx) …(5)

The normalization of given wavefunction is done by the formula,

0π(Ψ)*Ψdx=1 …(6)

Substitute the value of ψ in the above formula.

0π(Nsin2x)*Nsin2xdx=1N20πsin22xdx=1

Assume b=2 and expand the above expression similarly as equation (5).

N2[x218sin4x]0π=1N2[(π218sin4π)(0218sin(0))]0π=1

Substitute the value of sin0=0 and sin4π=0 in the above expression.

N2[(π218(0))(0218(0))]0π=1N2(π2)=1

Solve the above equation.

N=±2π

Only positive square root is taken for normalization constant. Therefore, the normalized wavefunction is 2πsin2x.

From Appendix 1,

xsin2(bx)dx=x24x4bsin(2bx)18b2cos(2bx) …(7)

The average value of x is calculated as,

x=02Ψx^Ψdx …(8)

Where,

x^represents the position operator.

Ψrepresents the wavefunction.

Substitute the value of Ψ and x^ in the equation (8).

x=0π(2πsin2x)x(2πsin2x)dx=2π0πxsin22xdx

Assume b=2 and expand the above expression similarly as equation (7).

x=2π[x24x4(2)sin((2)(2)x)1(8)(2)2cos((2)(2)x)]0π=2π[((π)24(π)8sin(4(π))132cos(4(π)))((0)24(0)8sin(4(0))132cos(4(0)))]

Substitute the value of cos4π=1, cos0=1, sin0=0 and sin4π=0 in the above expression.

x=2π[((π)24(π)8(0)132(1))((0)24(0)8(0)132(1))]=2π((π)24)=π2

Therefore, the average value of position, x for the given wavefunction is π2.

Conclusion

The average value of position, x for the given wavefunction is π2.

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