Chemistry: Principles and Reactions
8th Edition
ISBN: 9781305079373
Author: William L. Masterton, Cecile N. Hurley
Publisher: Cengage Learning
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Chapter 10, Problem 25QAP
Consider the process by which lead chloride dissolves in water:
(b) Based only on
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Chapter 10 Solutions
Chemistry: Principles and Reactions
Ch. 10 - A solution is prepared by dissolving 12.15 g of...Ch. 10 - Prob. 2QAPCh. 10 - Prob. 3QAPCh. 10 - Solutions Introduced directly into the bloodstream...Ch. 10 - Silver ions can be found in some of the city water...Ch. 10 - Prob. 6QAPCh. 10 - Complete the following table for aqueous solutions...Ch. 10 - Complete the following table for aqueous solutions...Ch. 10 - Complete the following table for aqueous solutions...Ch. 10 - Complete the following table for aqueous solutions...
Ch. 10 - Prob. 11QAPCh. 10 - Prob. 12QAPCh. 10 - Prob. 13QAPCh. 10 - A solution is prepared by diluting 0.7850 L of...Ch. 10 - A bottle of phosphoric acid is labeled 85.0% H3PO4...Ch. 10 - Prob. 16QAPCh. 10 - Complete the following table for aqueous solutions...Ch. 10 - Complete the following table for aqueous solutions...Ch. 10 - Assume that 30 L of maple sap yields one kilogram...Ch. 10 - Juice (d=1.0g/mL) from freshly harvested grapes...Ch. 10 - Prob. 21QAPCh. 10 - Which of the following is more likely to be...Ch. 10 - Prob. 23QAPCh. 10 - Prob. 24QAPCh. 10 - Consider the process by which lead chloride...Ch. 10 - Prob. 26QAPCh. 10 - The Henry's law constant for the solubility of...Ch. 10 - The Henry's law constant for the solubility of...Ch. 10 - A carbonated beverage is made by saturating water...Ch. 10 - Air contains 78% nitrogen. At 25C, Henry's law...Ch. 10 - Vodka is advertised to be 80 proof. That means...Ch. 10 - What is the freezing point of maple syrup (66%...Ch. 10 - Calculate the vapor pressure of water over each of...Ch. 10 - Calculate the vapor pressure of water over each of...Ch. 10 - Prob. 35QAPCh. 10 - Consider an aqueous solution of urea, (CO(NH2)2)...Ch. 10 - Prob. 37QAPCh. 10 - Prob. 38QAPCh. 10 - Calculate the freezing point and normal boiling...Ch. 10 - How many grams of the following nonelectrolytes...Ch. 10 - What is the freezing point and normal boiling...Ch. 10 - Antifreeze solutions are aqueous solutions of...Ch. 10 - When 13.66 g of lactic acid, C3H6O3, are mixed...Ch. 10 - A solution consisting of 4.50 g of propylene...Ch. 10 - Insulin is a hormone responsible for the...Ch. 10 - Epinephrine (or adrenaline) is a hormone and...Ch. 10 - Lauryl alcohol is obtained from the coconut and is...Ch. 10 - The Rast method uses camphor (C10H16O) as a...Ch. 10 - Caffeine is made up of 49.5% C, 5.2% H, 16.5% O,...Ch. 10 - A compound contains 42.9% C, 2.4% H, 16.6% N, and...Ch. 10 - A biochemist isolates a new protein and determines...Ch. 10 - Prob. 52QAPCh. 10 - Estimate the freezing and boiling points of normal...Ch. 10 - Arrange 0.10 m aqueous solutions of the following...Ch. 10 - Aqueous solutions introduced into the stream y...Ch. 10 - What is the osmotic pressure of a 0.135 M solution...Ch. 10 - The freezing point of a 0.11 m solution of HNO2 is...Ch. 10 - The freezing point of a 0.21 m aqueous solution of...Ch. 10 - An aqueous solution of LiX is prepared by...Ch. 10 - An aqueous solution of M2O is prepared by...Ch. 10 - A sucrose (C12H22O11) solution that is 45.0%...Ch. 10 - An aqueous solution made up of 32.47 g of...Ch. 10 - How would you prepare 5.00 L of a solution that is...Ch. 10 - Carbon tetrachloride (CCl4) boils at 76.8C and has...Ch. 10 - Twenty-five milliliters of a solution...Ch. 10 - The Henry's law constant for the solubility of...Ch. 10 - Prob. 67QAPCh. 10 - Consider two solutions at a certain temperature....Ch. 10 - A pharmacist prepares an isotonic saline solution...Ch. 10 - One mole of CaCl2 is represented as where...Ch. 10 - One mole of Na2S is represented as where...Ch. 10 - Prob. 72QAPCh. 10 - Consider three test tubes. Tube A has pure water....Ch. 10 - The freezing point of 0.20 m HF is -0.38C. Is HF...Ch. 10 - A certain gaseous solute dissolves in water,...Ch. 10 - The freezing point of 0.10 M KHSO3 is -0.38C....Ch. 10 - Consider 2 vapor pressure curves A and B. They are...Ch. 10 - A gaseous solute dissolves in water. The solution...Ch. 10 - In your own words, explain (a) why seawater has a...Ch. 10 - Prob. 80QAPCh. 10 - Beaker A has 1.00 mol of chloroform, CHCl3, at...Ch. 10 - Prob. 82QAPCh. 10 - Prob. 83QAPCh. 10 - Prob. 84QAPCh. 10 - Prob. 85QAPCh. 10 - A martini, weighing about 5.0 oz (142 g), contains...Ch. 10 - When water is added to a mixture of aluminum metal...Ch. 10 - Prob. 88QAPCh. 10 - Prob. 89QAP
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- Actually, the carbon in CO2(g) is thermodynamically unstable with respect to the carbon in calcium carbonate(limestone). Verify this by determining the standardGibbs free energy change for the reaction of lime,CaO(s), with CO2(g) to make CaCO3(s).arrow_forwardWhen 7.11 g NH4NO3 is added to 100 mL water, the temperature of the calorimeter contents decreases from 22.1 C to 17.1 C. Assuming that the mixture has the same specific heat as water and a mass of 107 g, calculate the heat q. Is the dissolution of ammonium nitrate exothermic or endothermic?arrow_forwardConsider a metal ion A2+ and its nitrate salt, In an experiment, 35.00 mL of a 0.217 M solution of A(NO3)2 is made to react with 25.00 mL of 0.195 M NaOH. A precipitate, A(OH)2, forms. Along with the precipitation, the temperature increases from 24.8C to 28.2C. What is H for the precipitation of A(OH)2? The following assumptions can be made. • The density of the solution is 1.00 g/mL. • Volumes are additive. • The specific heat of the solution is 4.18 J/g C.arrow_forward
- Another step in the metabolism of glucose, which occurs after the formation of glucose6-phosphate, is the conversion of fructose6-phosphate to fructose1,6-bisphosphate(bis meanstwo): Fructose6-phosphate(aq) + H2PO4(aq) fructose l,6-bisphosphate(aq) + H2O() + H+(aq) (a) This reaction has a Gibbs free energy change of +16.7 kJ/mol of fructose6-phosphate. Is it endergonic or exergonic? (b) Write the equation for the formation of 1 mol ADP fromATR for which rG = 30.5 kJ/mol. (c) Couple these two reactions to get an exergonic process;write its overall chemical equation, and calculate theGibbs free energy change.arrow_forwardDescribe a nonchemical system that is not in equilibrium, and explain why equilibrium has not been achieved.arrow_forwardThe equilibrium constant for a certain reaction increases by a factor of 6.67 when the temperature is increased from 300.0 K to 350.0 K. Calculate the standard change in enthalpy (H) for this reaction (assuming H is temperature-independent).arrow_forward
- 9.96 Most first aid "cold packs" are based on the endothermic dissolution of ammonium nitrate in water: NH4NO3(s)NH4+(aq)+NO3(aq) H= 25.69 kJ A particular cold pack contains 50.0 g of NH4NO3 and 125.0 g of water. When the pack is squeezed, the NH4NO3dissolves in the water. If the pack and its contents are initially at 24.0°C, what is the lowest temperature that this bag could reach? (Assume that the ammonium nitrate solution has a specific heat of 4.25J g-l K-l, and that the heat capacity of the bag itself is small enough to be neglected.)arrow_forwardCalculate H when a 38-g sample of glucose, C6H12O6(s), burns in excess O2(g) to form CO2(g) and H2O() in a reaction at constant pressure and 298.15 K.arrow_forwardDetermine the standard Gibbs free energy change, rG, for the reactions of liquid methanol, of CO(g), and ofethyne, C2H2(g), with oxygen gas to form gaseous carbondioxide and (if hydrogen is present) liquid water at298 K. Use your calculations to decide which of thesesubstances are kinetically stable and which are thermodynamically stable: CH3OH(), CO(g), C2H9(g), CO2(g),H2O().arrow_forward
- Reword the statement in Question 109 so that it is always true. Criticize this statement: Provided it occurs at an appreciable rate, any chemical reaction for which rG 0 will proceed until all reactants have been converted toproducts.arrow_forwardWhat is the sign of the standard Gibbs free-energy change at low temperatures and at high temperatures for the explosive decomposition of TNT? Use your knowledge of TNT and the chemical equation, particularly the phases, to answer this question. (Thermodynamic data for TNT are not in Appendix G.) 2C7H5N3O6(s) 3N2(g) + 5H2O() + 7C(s) + 7CO(g)arrow_forwardThe standard Gibbs free energy change at 100oC is 18.8 kJ/mol for the solubility equilibrium: Li3PO4(s) →← 3Li+(aq) + PO43–(aq); ∆Gorxn = 18.8 kJ/mol What is the molar solubility of lithium phosphate at this temperature? Enter your answer with correct units and significant figures.arrow_forward
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