Chemistry & Chemical Reactivity
Chemistry & Chemical Reactivity
9th Edition
ISBN: 9781133949640
Author: John C. Kotz, Paul M. Treichel, John Townsend, David Treichel
Publisher: Cengage Learning
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Textbook Question
Chapter 10, Problem 61GQ

Butyl mercaptan, C4H9SH, has a very bad odor and is among the compounds added to natural gas to help detect a leak of otherwise odorless natural gas. In an experiment, you burn 95.0 mg of C4H9SH and collect the product gases (SO2, CO2, and H2O) in a 5.25-L flask at 25 °C. What is the total gas pressure in the flask, and what is the partial pressure of each of the product gases?

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Chapter 10 Solutions

Chemistry & Chemical Reactivity

Ch. 10.3 - Prob. 1CYUCh. 10.3 - At 1.00 atm and 25 C, the density of dry air is...Ch. 10.3 - A 0.105-g sample of a gaseous compound has a...Ch. 10.3 - Which gas has the greatest density at 25 and 1.00...Ch. 10.3 - Prob. 2RCCh. 10.3 - Prob. 3RCCh. 10.4 - Prob. 1CYUCh. 10.4 - Diborane reacts with O2 to give boric oxide and...Ch. 10.4 - 2. If you mix 1.5 L of B2H6 with 4.0 L of O2, each...Ch. 10.5 - The halothane-oxygen mixture described in this...Ch. 10.5 - Prob. 1RCCh. 10.6 - Prob. 1CYUCh. 10.6 - What is the rms speed of chlorine molecules at...Ch. 10.6 - 2. The species identified with each curve in the...Ch. 10.7 - Prob. 1CYUCh. 10.7 - In Figure 10.17, ammonia gas and hydrogen chloride...Ch. 10.8 - Prob. 1RCCh. 10.8 - At sea level, atmospheric pressure is 1.00 atm....Ch. 10.8 - Prob. 2QCh. 10.8 - To stay aloft, a blimp must achieve neutral...Ch. 10 - Pressure (See Section 10.1 and Example 10.1.) The...Ch. 10 - The average barometric pressure at an altitude of...Ch. 10 - Indicate which represents the higher pressure in...Ch. 10 - Put the following in order of increasing pressure:...Ch. 10 - Prob. 5PSCh. 10 - Prob. 6PSCh. 10 - You have 3.5 L of NO at a temperature of 22.0 C....Ch. 10 - Prob. 8PSCh. 10 - Prob. 9PSCh. 10 - You have a sample of CO2 in flask A with a volume...Ch. 10 - You have a sample of gas in a flask with a volume...Ch. 10 - A sample of gas occupies 135 mL at 22.5 C; the...Ch. 10 - One of the cylinders of an automobile engine has a...Ch. 10 - A helium-filled balloon of the type used in...Ch. 10 - Nitrogen monoxide reacts with oxygen to give...Ch. 10 - Ethane bums in air to give H2O and CO2. 2 C2H6(g)...Ch. 10 - A 1.25-g sample of CO2 is contained in a 750.-mL...Ch. 10 - A balloon holds 30.0 kg of helium. What is the...Ch. 10 - A flask is first evacuated so that it contains no...Ch. 10 - Prob. 20PSCh. 10 - Prob. 21PSCh. 10 - Prob. 22PSCh. 10 - Forty miles above Earths surface, the temperature...Ch. 10 - Prob. 24PSCh. 10 - A gaseous organofluorine compound has a density of...Ch. 10 - Prob. 26PSCh. 10 - A 1 007-g sample of an unknown gas exerts a...Ch. 10 - A 0.0130-g sample of a gas with an empirical...Ch. 10 - A new boron hydride, BxHy, has been isolated. To...Ch. 10 - Acetaldehyde is a common liquid compound that...Ch. 10 - Iron reacts with hydrochloric acid to produce...Ch. 10 - Silane, SiH4, reacts with O2 to give silicon...Ch. 10 - Prob. 33PSCh. 10 - The hydrocarbon octane (C8H18) bums to give CO2...Ch. 10 - Prob. 35PSCh. 10 - A self-contained underwater breathing apparatus...Ch. 10 - What is the total pressure in atmospheres of a gas...Ch. 10 - A cylinder of compressed gas is labeled...Ch. 10 - A halothane-oxygen mixture (C2HBrCIF3 + O2) can be...Ch. 10 - A collapsed balloon is filled with He to a volume...Ch. 10 - You have two flasks of equal volume. Flask A...Ch. 10 - Equal masses of gaseous N2 and Ar are placed in...Ch. 10 - If the rms speed of an oxygen molecule is 4.28 ...Ch. 10 - Prob. 44PSCh. 10 - Place the following gases in order of increasing...Ch. 10 - Prob. 46PSCh. 10 - In each pair of gases below, tell which will...Ch. 10 - Prob. 48PSCh. 10 - Prob. 49PSCh. 10 - A sample of uranium fluoride is found to effuse at...Ch. 10 - Prob. 51PSCh. 10 - Prob. 52PSCh. 10 - In the text, it is stated that the pressure of...Ch. 10 - You want to store 165 g of CO2 gas in a 12.5-L...Ch. 10 - Consider a 5.00-L tank containing 325 g of H2O at...Ch. 10 - Consider a 5.00-L tank containing 375 g of Ar at a...Ch. 10 - Complete the following table:Ch. 10 - On combustion, 1.0 L of a gaseous compound of...Ch. 10 - You have a sample of helium gas at 33 C, and you...Ch. 10 - Prob. 60GQCh. 10 - Butyl mercaptan, C4H9SH, has a very bad odor and...Ch. 10 - Prob. 62GQCh. 10 - The temperature of the atmosphere on Mars can be...Ch. 10 - If you place 2.25 g of solid silicon in a 6.56-L...Ch. 10 - What volume (in liters) of O2, measured at...Ch. 10 - Nitroglycerin decomposes into four different gases...Ch. 10 - Ni(CO)4 can be made by reacting finely divided...Ch. 10 - Ethane bums in air to give H2O and CO2. 2 C2H6(g)...Ch. 10 - You have four gas samples: 1. 1.0 L of H2 at STP...Ch. 10 - Propane reacts with oxygen to give carbon dioxide...Ch. 10 - Iron carbonyl can be made by the direct reaction...Ch. 10 - Prob. 72GQCh. 10 - There are five compounds in the family of...Ch. 10 - A miniature volcano can be made in the laboratory...Ch. 10 - The density of air 20 km above Earths surface is...Ch. 10 - Prob. 76GQCh. 10 - Chlorine dioxide, ClO2, reacts with fluorine to...Ch. 10 - A xenon fluoride can be prepared by heating a...Ch. 10 - Prob. 79GQCh. 10 - Prob. 80GQCh. 10 - Prob. 81GQCh. 10 - Carbon dioxide, CO2, was shown lo effuse through a...Ch. 10 - Prob. 84GQCh. 10 - Prob. 85GQCh. 10 - Prob. 86GQCh. 10 - You are given 1.56 g of a mixture of KClO3 and...Ch. 10 - A study of climbers who reached the summit of...Ch. 10 - Nitrogen monoxide reacts with oxygen to give...Ch. 10 - Ammonia gas is synthesized by combining hydrogen...Ch. 10 - Nitrogen trifluoride is prepared by the reaction...Ch. 10 - Chlorine trifluoride, ClF3, is a valuable reagent...Ch. 10 - Prob. 93GQCh. 10 - Prob. 94GQCh. 10 - You have a 550.-mL tank of gas with a pressure of...Ch. 10 - Prob. 96ILCh. 10 - Prob. 97ILCh. 10 - Group 2A metal carbonates are decomposed to the...Ch. 10 - One way to synthesize diborane, B2H6, is the...Ch. 10 - You are given a solid mixture of NaNO2 and NaCl...Ch. 10 - You have 1.249 g of a mixture of NaHCO3 and...Ch. 10 - Prob. 102ILCh. 10 - Many nitrate salts can be decomposed by heating....Ch. 10 - You have a gas, one of the three known...Ch. 10 - Prob. 106ILCh. 10 - A 1.0-L flask contains 10.0 g each of O2 and CO2...Ch. 10 - If equal masses of O2 and N2 are placed in...Ch. 10 - You have two pressure-proof steel cylinders of...Ch. 10 - Prob. 110SCQCh. 10 - Prob. 111SCQCh. 10 - Each of four flasks is filled with a different...Ch. 10 - Prob. 113SCQCh. 10 - The sodium azide required for automobile air bags...Ch. 10 - Prob. 115SCQCh. 10 - Prob. 116SCQ
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  • In a typical automobile engine, a gasoline vapor-air mixture is compressed and ignited in the cylinders of the engine. This results in a combustion reaction that produces mainly carbon dioxide and water vapor. For simplicity, assume that the fuel is C8H18 and has a density of 0.760 g/mL. (a) Calculate the partial pressures of N2 and 02 in the air before it goes into the cylinder; assume the atmospheric pressure is 734 mmHg. (b) Consider the case where the air, without any fuel added, is compressed in the cylinder to seven times atmospheric pressure, the compression ratio of many modem automobile engines. Calculate the partial pressures of N2 and O2 at this pressure. (c) Now consider the case where 0.050 mL gasoline is added to the air in the cylinder just before compression and completely vaporized. Assume that the volume of the cylinder is 485 mL and the temperature is 150C. Calculate the partial pressure of the gasoline vapor. (d) Calculate the amount (mol) of oxygen required to bum the gasoline in part (c) completely to CO2 and H2O. (e) The combustion reaction in the cylinder creates temperatures in excess of 1200K. Due to the high temperature, some of the nitrogen and oxygen in the air reacts to form nitrogen monoxide. If 10% of the nitrogen is converted to NO, calculate the mass (g) of NO produced by this combustion. (f) Hot-rod cars use another oxide of nitrogen, dinitrogen monoxide, to create an extra burst in power. When such a power boost is needed, dinitrogen monoxide gas is injected into the cylinders where it reacts with oxygen to form NO. Calculate the mass of dinitrogen monoxide that would have to be injected to form the same quantity of NO as produced in part (e). Assume that sufficient oxygen is present to do so.
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