Chemistry: Principles and Reactions
8th Edition
ISBN: 9781305079373
Author: William L. Masterton, Cecile N. Hurley
Publisher: Cengage Learning
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Chapter 10, Problem 64QAP
Carbon tetrachloride (CCl4) boils at 76.8°C and has a density of 1.59 g/mL.
(a) A solution prepared by dissolving 0.287 mol of a nonelectrolyte in 255 mL of CCl4 boils at 80.3°C. What is the boiling point constant (kb) for CCl4?
(b) Another solution is prepared by dissolving 37.1 g of an electrolyte
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Chapter 10 Solutions
Chemistry: Principles and Reactions
Ch. 10 - A solution is prepared by dissolving 12.15 g of...Ch. 10 - Prob. 2QAPCh. 10 - Prob. 3QAPCh. 10 - Solutions Introduced directly into the bloodstream...Ch. 10 - Silver ions can be found in some of the city water...Ch. 10 - Prob. 6QAPCh. 10 - Complete the following table for aqueous solutions...Ch. 10 - Complete the following table for aqueous solutions...Ch. 10 - Complete the following table for aqueous solutions...Ch. 10 - Complete the following table for aqueous solutions...
Ch. 10 - Prob. 11QAPCh. 10 - Prob. 12QAPCh. 10 - Prob. 13QAPCh. 10 - A solution is prepared by diluting 0.7850 L of...Ch. 10 - A bottle of phosphoric acid is labeled 85.0% H3PO4...Ch. 10 - Prob. 16QAPCh. 10 - Complete the following table for aqueous solutions...Ch. 10 - Complete the following table for aqueous solutions...Ch. 10 - Assume that 30 L of maple sap yields one kilogram...Ch. 10 - Juice (d=1.0g/mL) from freshly harvested grapes...Ch. 10 - Prob. 21QAPCh. 10 - Which of the following is more likely to be...Ch. 10 - Prob. 23QAPCh. 10 - Prob. 24QAPCh. 10 - Consider the process by which lead chloride...Ch. 10 - Prob. 26QAPCh. 10 - The Henry's law constant for the solubility of...Ch. 10 - The Henry's law constant for the solubility of...Ch. 10 - A carbonated beverage is made by saturating water...Ch. 10 - Air contains 78% nitrogen. At 25C, Henry's law...Ch. 10 - Vodka is advertised to be 80 proof. That means...Ch. 10 - What is the freezing point of maple syrup (66%...Ch. 10 - Calculate the vapor pressure of water over each of...Ch. 10 - Calculate the vapor pressure of water over each of...Ch. 10 - Prob. 35QAPCh. 10 - Consider an aqueous solution of urea, (CO(NH2)2)...Ch. 10 - Prob. 37QAPCh. 10 - Prob. 38QAPCh. 10 - Calculate the freezing point and normal boiling...Ch. 10 - How many grams of the following nonelectrolytes...Ch. 10 - What is the freezing point and normal boiling...Ch. 10 - Antifreeze solutions are aqueous solutions of...Ch. 10 - When 13.66 g of lactic acid, C3H6O3, are mixed...Ch. 10 - A solution consisting of 4.50 g of propylene...Ch. 10 - Insulin is a hormone responsible for the...Ch. 10 - Epinephrine (or adrenaline) is a hormone and...Ch. 10 - Lauryl alcohol is obtained from the coconut and is...Ch. 10 - The Rast method uses camphor (C10H16O) as a...Ch. 10 - Caffeine is made up of 49.5% C, 5.2% H, 16.5% O,...Ch. 10 - A compound contains 42.9% C, 2.4% H, 16.6% N, and...Ch. 10 - A biochemist isolates a new protein and determines...Ch. 10 - Prob. 52QAPCh. 10 - Estimate the freezing and boiling points of normal...Ch. 10 - Arrange 0.10 m aqueous solutions of the following...Ch. 10 - Aqueous solutions introduced into the stream y...Ch. 10 - What is the osmotic pressure of a 0.135 M solution...Ch. 10 - The freezing point of a 0.11 m solution of HNO2 is...Ch. 10 - The freezing point of a 0.21 m aqueous solution of...Ch. 10 - An aqueous solution of LiX is prepared by...Ch. 10 - An aqueous solution of M2O is prepared by...Ch. 10 - A sucrose (C12H22O11) solution that is 45.0%...Ch. 10 - An aqueous solution made up of 32.47 g of...Ch. 10 - How would you prepare 5.00 L of a solution that is...Ch. 10 - Carbon tetrachloride (CCl4) boils at 76.8C and has...Ch. 10 - Twenty-five milliliters of a solution...Ch. 10 - The Henry's law constant for the solubility of...Ch. 10 - Prob. 67QAPCh. 10 - Consider two solutions at a certain temperature....Ch. 10 - A pharmacist prepares an isotonic saline solution...Ch. 10 - One mole of CaCl2 is represented as where...Ch. 10 - One mole of Na2S is represented as where...Ch. 10 - Prob. 72QAPCh. 10 - Consider three test tubes. Tube A has pure water....Ch. 10 - The freezing point of 0.20 m HF is -0.38C. Is HF...Ch. 10 - A certain gaseous solute dissolves in water,...Ch. 10 - The freezing point of 0.10 M KHSO3 is -0.38C....Ch. 10 - Consider 2 vapor pressure curves A and B. They are...Ch. 10 - A gaseous solute dissolves in water. The solution...Ch. 10 - In your own words, explain (a) why seawater has a...Ch. 10 - Prob. 80QAPCh. 10 - Beaker A has 1.00 mol of chloroform, CHCl3, at...Ch. 10 - Prob. 82QAPCh. 10 - Prob. 83QAPCh. 10 - Prob. 84QAPCh. 10 - Prob. 85QAPCh. 10 - A martini, weighing about 5.0 oz (142 g), contains...Ch. 10 - When water is added to a mixture of aluminum metal...Ch. 10 - Prob. 88QAPCh. 10 - Prob. 89QAP
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- An aluminum-containing compound has the empirical formula (C2HS)2AIF. Find the molecular formula if 0.448 g of the compound dissolved in 23.46 g of benzene has a freezing point of 5.265 C.arrow_forwardTwo samples of sodium chloride solutions are brought to a boil on a stove. One of the solutions boils at 100.10C and the other at 100.15C. a Which of the solutions is more concentrated? b Which of the solutions would have a lower freezing point? c If you split the solution that boils at 100.1C into two portions, how would the boiling points of the samples compare? Which of the following statements do you agree with regarding the determination of your answer for part c? I. The question cannot be answered with certainty without knowing the volumes of each portion. II. Making the necessary assumption that the two samples have equal volumes, I was able to correctly answer the question. III. The volumes that the sample was split into are irrelevant when determining the correct answer.arrow_forwardSamples of each of the substances listed below are dissolved in 125 g of water. Which of the solutions has the highest boiling point? (a) 3.0 g sucrose, C12H22O11 (b) 1.0 g glycerol, C3H3(OH)3 (c) 1.0 g propylene glycol, C3H6(OH)2 (d) 2.0 g glucose, C6H12(OH)2arrow_forward
- 6-111 As noted in Section 6-8C, the amount of external pressure that must be applied to a more concentrated solution to stop the passage of solvent molecules across a semipermeable membrane is known as the osmotic pressure The osmotic pressure obeys a law similar in form to the ideal gas law (discussed in Section 5-4), where Substituting for pressure and solving for osmotic pressures gives the following equation: RT MRT, where M is the concentration or molarity of the solution. (a) Determine the osmotic pressure at 25°C of a 0.0020 M sucrose (C12H22O11) solution. (b) Seawater contains 3.4 g of salts for every liter of solution. Assuming the solute consists entirely of NaCl (and complete dissociation of the NaCI salt), calculate the osmotic pressure of seawater at 25°C. (c) The average osmotic pressure of blood is 7.7 atm at 25°C. What concentration of glucose (C6H12O6) will be isotonic with blood? (d) Lysozyme is an enzyme that breaks bacterial cell walls. A solution containing 0.150 g of this enzyme in 210. mL of solution has an osmotic pressure of 0.953 torr at 25°C. What is the molar mass of lysozyme? (e) The osmotic pressure of an aqueous solution of a certain protein was measured in order to determine the protein's molar mass. The solution contained 3.50 mg of protein dissolved in sufficient water to form 5.00 mL of solution. The osmotic pressure of the solution at 25°C was found to be 1.54 torr. Calculate the molar mass of the protein.arrow_forwardWhat is the freezing point and normal boiling point of a solution made by adding 39 mL of acetone, C3H6O, to 225 mL of water? The densities of acetone and water are 0.790 g/cm3 and 1.00 g/cm3, respectively.arrow_forwardWill red blood cells crenate, hemolyze, or remain unaffected when placed in each of the solutions in Problem 8-102?arrow_forward
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Solutions: Crash Course Chemistry #27; Author: Crash Course;https://www.youtube.com/watch?v=9h2f1Bjr0p4;License: Standard YouTube License, CC-BY