Introductory Chemistry: An Active Learning Approach
6th Edition
ISBN: 9781305079250
Author: Mark S. Cracolice, Ed Peters
Publisher: Cengage Learning
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Chapter 10, Problem 79E
A sludge containing silver chloride is a water product from making mirrors. The silver may be recovered by dissolving the silver chloride in a sodium cyanide
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Chapter 10 Solutions
Introductory Chemistry: An Active Learning Approach
Ch. 10 - The first step in the Ostwald process for...Ch. 10 - When hydrogen sulfide reacts with oxygen, water...Ch. 10 - Magnesium hydroxide is formed from the reaction of...Ch. 10 - In our bodies, sugar is broken down by reacting...Ch. 10 - Prob. 5ECh. 10 - Aqueous solutions of potassium hydrogen sulfate...Ch. 10 - The first step in the Ostwald process for...Ch. 10 - Butane, C4H10 is a common fuel used for heating...Ch. 10 - The explosion of nitroglycerine is described by...Ch. 10 - According to the reaction 2AgNO3+CuCu(NO3)2+2Ag,...
Ch. 10 - Prob. 11ECh. 10 - Prob. 12ECh. 10 - Prob. 13ECh. 10 - Prob. 14ECh. 10 - The hard water scum that forms a ring around the...Ch. 10 - Prob. 16ECh. 10 - Prob. 17ECh. 10 - Prob. 18ECh. 10 - The Solvay process is multistep industrial method...Ch. 10 - Prob. 20ECh. 10 - Prob. 21ECh. 10 - What mass of NaHCO3 must decompose to produce 448g...Ch. 10 - Prob. 23ECh. 10 - Solid ammonium chloride decomposes to form ammonia...Ch. 10 - What mass of magnesium hydroxide will precipitate...Ch. 10 - Prob. 26ECh. 10 - Prob. 27ECh. 10 - Prob. 28ECh. 10 - The reaction of a dry cell battery may be...Ch. 10 - Prob. 30ECh. 10 - Prob. 31ECh. 10 - Prob. 32ECh. 10 - Calcium cyanamide is a common fertilizer. When...Ch. 10 - Prob. 34ECh. 10 - The Haber process for making ammonia from nitrogen...Ch. 10 - Prob. 36ECh. 10 - Prob. 37ECh. 10 - The simplest example of the hydrogenation of a...Ch. 10 - Prob. 39ECh. 10 - Prob. 40ECh. 10 - Ammonia can be formed from a combination reaction...Ch. 10 - Carbon monoxide reacts with oxygen to form carbon...Ch. 10 - An experiment is conducted in which varying...Ch. 10 - The flasks below illustrated three trials of a...Ch. 10 - A solution containing 1.63g of barium chloride is...Ch. 10 - Prob. 46ECh. 10 - Prob. 47ECh. 10 - Prob. 48ECh. 10 - A mixture of tetraphosphorus trisulfide and...Ch. 10 - Sodium carbonate can neutralize nitric acid by the...Ch. 10 - Prob. 51ECh. 10 - Prob. 52ECh. 10 - Prob. 53ECh. 10 - Prob. 54ECh. 10 - Prob. 55ECh. 10 - Prob. 56ECh. 10 - Prob. 57ECh. 10 - Prob. 58ECh. 10 - Prob. 59ECh. 10 - Prob. 60ECh. 10 - Question 57 through 62: Thermochemical equations...Ch. 10 - Prob. 62ECh. 10 - Quicklime, the common name for calcium oxide, CaO,...Ch. 10 - What mass in grams of hydrogen has to react to...Ch. 10 - The quicklime produced in Question 63 is...Ch. 10 - Prob. 66ECh. 10 - What mass in grams of octane, a component of...Ch. 10 - Calculate the quantity of energy (kJ) transferred...Ch. 10 - Prob. 69ECh. 10 - Classify each of the following statements as true...Ch. 10 - Prob. 71ECh. 10 - What mass in grams of calcium phosphate will...Ch. 10 - Prob. 73ECh. 10 - Prob. 74ECh. 10 - A laboratory test of 12.8g of aluminum ore yields...Ch. 10 - How much energy is required to decompose 1.42g of...Ch. 10 - Prob. 77ECh. 10 - Prob. 78ECh. 10 - A sludge containing silver chloride is a water...Ch. 10 - Prob. 80ECh. 10 - Prob. 81ECh. 10 - Prob. 82ECh. 10 - Prob. 83ECh. 10 - Prob. 84ECh. 10 - In 1866, a young chemistry student conceived the...Ch. 10 - Prob. 86ECh. 10 - A student was given a 1.6240-g sample of a mixture...Ch. 10 - A researcher dissolved 1.382g of impure copper in...Ch. 10 - What mass in grams of magnesium nitrate, Mg(NO3)2,...Ch. 10 - Prob. 90ECh. 10 - Prob. 10.1TCCh. 10 - Solutions of zinc bromide and sodium hydroxide are...Ch. 10 - Prob. 2PECh. 10 - Prob. 3PECh. 10 - How mass of fluorine is formed when 3.0grams of...Ch. 10 - Prob. 5PECh. 10 - Prob. 6PECh. 10 - Prob. 7PECh. 10 - Prob. 8PECh. 10 - Prob. 9PECh. 10 - A solution containing 43.5g of calcium nitrate is...Ch. 10 - Prob. 11PECh. 10 - Prob. 12PECh. 10 - Prob. 13PECh. 10 - Prob. 14PECh. 10 - Prob. 15PECh. 10 - Prob. 1PCECh. 10 - Prob. 2PCECh. 10 - Prob. 3PCECh. 10 - Prob. 4PCECh. 10 - Prob. 5PCECh. 10 - Prob. 6PCECh. 10 - Eight problem-classification examples follow. Test...Ch. 10 - Prob. 8PCE
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- Potassium permanganate (KMnO4) solutions are used for the determination of Fe2+ in samples of unknown concentration. As a laboratory assistant, you are supposed to prepare 500 mL of a 0.1000 M KMnO4 solution. What mass of KMnO4, in grams, do you need?arrow_forwardA soluble iodide was dissolved in water. Then an excess of silver nitrate, AgNO3, was added to precipitate all of the iodide ion as silver iodide, AgI. If 1.545 g of the soluble iodide gave 2.185 g of silver iodide, how many grams of iodine are in the sample of soluble iodide? What is the mass percentage of iodine, I, in the compound?arrow_forwardTriiodide ions are generated in solution by the following (unbalanced) reaction in acidic solution: IO3(aq) + I(aq) I3(aq) Triiodide ion concentration is determined by titration with a sodium thiosulfate (Na2S2O3) solution. The products are iodide ion and tetrathionate ion (S4O6). a. Balance the equation for the reaction of IO3 with I ions. b. A sample of 0.6013 g of potassium iodate was dissolved in water. Hydrochloric acid and solid potassium iodide were then added. What is the minimum mass of solid KI and the minimum volume of 3.00 M HQ required to convert all of the IO3 ions to I ions? c. Write and balance the equation for the reaction of S2O32 with I3 in acidic solution. d. A 25.00-mL sample of a 0.0100 M solution of KIO. is reacted with an excess of KI. It requires 32.04 mL of Na2S2O3 solution to titrate the I3 ions present. What is the molarity of the Na2S2O3 solution? e. How would you prepare 500.0 mL of the KIO3 solution in part d using solid KIO3?arrow_forward
- A 0.608-g sample of fertilizer contained nitrogen as ammonium sulfate, (NH4)2SO4. It was analyzed for nitrogen by heating with sodium hydroxide. (NH4)2SO4(s)+2NaOH(aq)Na2SO4(aq)+2H2O(l)+2NH3(g) The ammonia was collected in 46.3 mL of 0.213 M HCl (hydrochloric acid), with which it reacted. NH3(g)+HCl(aq)NH4Cl(aq) This solution was titrated for excess hydrochloric acid with 44.3 mL of 0.128 M NaOH. NaOH(aq)+HCl(aq)NaCl(aq)+H2O(l) What is the percentage of nitrogen in the fertilizer?arrow_forwardSodium chloride is used in intravenous solutions for medical applications. The NaCl concentration in such solutions must be accurately known and can be assessed by reacting the solution with an experimentally determined volume of AgNO3 solution of known concentration. The net ionic equation is Ag+(aq)+Cl(aq)AgCl(s) Suppose that a chemical technician uses 19.3 mL of 0.200-M AgNO3 to convert all the NaCl in a 25.0-mL sample of an intravenous solution to AgCl. Calculate the molarity of NaCl in the solution.arrow_forwardThe exposed electrodes of a light bulb are placed in a solution of H2SO4 in an electrical circuit such that the light bulb is glowing. You add a dilute salt solution, and the bulb dims. Which of the following could be the salt in the solution? a. Ba(NO3)2 b. NaNO3 c. K2SO4 d. Ca(NO3)2 Justify your choices. For those you did not choose, explain why they are incorrect.arrow_forward
- You wish to determine the weight percent of copper in a copper-containing alloy. After dissolving a 0.251 -g sample of the alloy in acid, an excess of KI is added, and the Cu2+ and I ions undergo the reaction 2 Cu2+(aq) + 5 I(aq) 2 CuI(s) + I3(aq) The liberated I3 is titrated with sodium thiosulfate according to the equation I3 (aq) + 2 S2O32(aq) S4O62(aq) + 3 I (aq) (a) Designate the oxidizing and reducing agents in the two reactions above. (b) If 26.32 mL of 0.101 M Na2S2O3 is required for titration to the equivalence point, what is the weight percent of Cu in the alloy?arrow_forwardA 25.0-mL sample of vinegar (which contains the weak acid acetic acid, CH3CO2H) requires 28.33 mL of a 0.953 M solution of NaOH for titration to the equivalence point. What is the mass of acetic acid (molar mass = 60.05 g/mol), in grams, in the vinegar sample, and what is the concentration of acetic acid in the vinegar? CH3CO2H(aq) + NaOH(aq) NaCH3CO2(aq) + H2O(l)arrow_forwardElemental bromine is the source of bromine compounds. The element is produced from certain brine solutions that occur naturally. These brines are essentially solutions of calcium bromide that, when treated with chlorine gas, yield bromine in a displacement reaction. What are the molecular equation and net ionic equation for the reaction? A solution containing 40.0 g of calcium bromide requires 14.2 g of chlorine to react completely with it, and 22.2 g of calcium chloride is produced in addition to whatever bromine is obtained. How many grams of calcium bromide are required to produce 10.0 pounds of bromine?arrow_forward
- One method for determining the purity of aspirin (C9H8O4) is to hydrolyze it with NaOH solution and then to titrate the remaining NaOH. The reaction of aspirin with NaOH is as follows: A sample of aspirin with a mass of 1.427 g was boiled in 50.00 mL of 0.500 M NaOH. After the solution was cooled, it took 31.92 mL of 0.289 M HCl to titrate the excess NaOH. Calculate the purity of the aspirin. What indicator should be used for this titration? Why?arrow_forwardCalcium in blood or urine can be determined by precipitation as calcium oxalate, CaC2O4. The precipitate is dissolved in strong acid and titrated with potassium permanganate. The equation for reaction is 2MnO4(aq)+6H+(aq)+5H2C2O4(aq)2Mn2+(aq)+10CO2(g)+8H2O A 24-hour urine sample is collected from an adult patient, reduced to a small volume, and titrated with 26.2 mL of 0.0946 M KMnO4. How many grams of calcium oxalate are in the sample? Normal range for Ca2+ output for an adult is 100 to 300 mg per 24 hour. Is the sample within the normal range?arrow_forwardOne way of determining blood alcohol levels is by performing a titration on a sample of blood. In this process, the alcohol from the blood is oxidized by dichromate ions (Cr2O72-) according to the following net ionic equation: C2H5OH+2Cr2O72+16H+2CO2+4Cr3++11H2O A 10.00-g sample of blood was drawn from a patient, and 13.77 mL of 0.02538 M K2Cr2O7 was required to titrate the alcohol. What was the patient’s blood alcohol level? (See the previous problem for definition of blood alcohol level. K2Cr2O7 is a strong electrolyte, so it dissociates completely in solution.)arrow_forward
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