Introductory Chemistry: A Foundation
8th Edition
ISBN: 9781285199030
Author: Steven S. Zumdahl, Donald J. DeCoste
Publisher: Cengage Learning
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Chapter 10, Problem 80AP
Calculate the enthalpy change when 5.00 g of propane is burned with excess oxygen according to the reaction
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The standard enthalpy change of combustion [to CO2(g) and H2O()] at 25°C of the organic solid 9,10-phenanthrenediol, C14H10O2(s), is determined to be -6482.1 kJ mol-1. What is the Hf° of C14H10O2(s) based on this value? Use the following data: Hf° H2O () = -285.83 kJ mol-1 ; Hf° CO2(g) = -393.51 kJ mol-1
a) What is the standard enthalpy of reaction per mole of either HCl or NaOH when 50.00 cm3 of 0.1 moldm-3 of hydrochloric acid (HCl) and 50.00 cm3 of 0.1 moldm-3 of sodium hydroxide (NaOH) are mixed?
According to your simulation, the temperature rose by 0.68 oC. (Density of water = 1gcm-3, Specific heat capacity of water = 4.18 J g-1 oC-1)
b) What is the standard enthalpy of reaction per mole of KOH when 50.00 cm3 of 1.0 moldm-3 of Nitric Acid (HNO3) and 50.00 cm3 of 1.0 moldm-3 of Potassium Hydroxide (KOH) are mixed?
According to your simulation, the temperature rose by __6.81__ oC. (Density of water = 1gcm-3, Specific heat capacity of water = 4.18 J g-1 oC-1)
A coffee cup calorimeter was calibrated using 5.01 mL of 0.901 M HCl and 10.01 mL of 0.751 M NaOH. Thereafter, T changed from 29.5oC to 32.5oC. Using the same calorimeter, the enthalpy of reaction between NaOH and HNO3 is determined by mixing 5.10 mL of 0.800 M HNO3 and 10.10 mL of 0.600 M NaOH. The T changed from 30.5oC to 32.5oC. Suppose that the delta H of reaction between H+ and OH- is -55.9 kJ/mol.
i. Find the heat capacity of the calorimeter and the limiting reactant of the reaction studied.
ii. Find qrxn and enthalpyexperimental of the reaction.
iii. Find the % error.
Chapter 10 Solutions
Introductory Chemistry: A Foundation
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Ch. 10.10 - at if the first law of thermodynamics was true,...Ch. 10 - Prob. 1ALQCh. 10 - friend of yours reads that the process of water...Ch. 10 - ou place hot metal into a beaker of cold water. ol...Ch. 10 - Prob. 4ALQCh. 10 - Prob. 5ALQCh. 10 - xplain why aluminum cans make good storage...Ch. 10 - n Section 10.7, two characteristics of enthalpy...Ch. 10 - Prob. 8ALQCh. 10 - hat is meant by the term driving forces? Why are...Ch. 10 - Prob. 10ALQCh. 10 - Explain in your own words what is meant by the...Ch. 10 - Prob. 12ALQCh. 10 - What if energy was not conserved? How would this...Ch. 10 - The internal energy of a system is said to be the...Ch. 10 - Hydrogen gas and oxygen gas react violently to...Ch. 10 - Consider four 100.0-g samples of water, each in a...Ch. 10 - For each of the following situations ac. use the...Ch. 10 - Prob. 18ALQCh. 10 - Does the entropy of the system increase or...Ch. 10 - Prob. 20ALQCh. 10 - Prob. 1QAPCh. 10 - Prob. 2QAPCh. 10 - Prob. 3QAPCh. 10 - Prob. 4QAPCh. 10 - Prob. 5QAPCh. 10 - n Fig. 10.1, what kind of energy does ball A...Ch. 10 - Prob. 7QAPCh. 10 - f you spilled a cup of freshly brewed hot tea on...Ch. 10 - Prob. 9QAPCh. 10 - Prob. 10QAPCh. 10 - In studying heat flows for chemical processes,...Ch. 10 - When a chemical system evolves energy, where does...Ch. 10 - The combustion of methane, is an exothermic...Ch. 10 - Are the following processes exothermic or...Ch. 10 - What do we mean by thermodynamics? What is the...Ch. 10 - Prob. 16QAPCh. 10 - Calculate A£ for each of the following cases q =...Ch. 10 - If q for a process is a positive number, then the...Ch. 10 - For an endothermic process, q will have a...Ch. 10 - A system releases 125 kJ of heat and 104 kJ of...Ch. 10 - Prob. 21QAPCh. 10 - Prob. 22QAPCh. 10 - If 8.40 kJ of heat is needed to raise the...Ch. 10 - If it takes 654 J of energy to warm a 5.51-g...Ch. 10 - Prob. 25QAPCh. 10 - Prob. 26QAPCh. 10 - Covert the following numbers of kilojoules into...Ch. 10 - Prob. 28QAPCh. 10 - Prob. 29QAPCh. 10 - Prob. 30QAPCh. 10 - .5 kJ of heat is applied to a 1012-g block of...Ch. 10 - What quantity of heat energy must have en applied...Ch. 10 - If 125 J of heat energy is applied to a block of...Ch. 10 - If 100. J of heat energy is applied to a 25-g...Ch. 10 - What quantity of heat is required to raise the...Ch. 10 - Prob. 36QAPCh. 10 - The “Chemistry in Focus” segment Nature Has Hot...Ch. 10 - In the “Chemistry in Focus” segment Firewalking:...Ch. 10 - Prob. 39QAPCh. 10 - A _________ is a device used to determine the heat...Ch. 10 - The enthalpy change for the reaction of hydrogen...Ch. 10 - For the reaction kJ per mole of formed. Calculate...Ch. 10 - Prob. 43QAPCh. 10 - When ethanol (grain alcohol, is burned in oxygen,...Ch. 10 - Prob. 45QAPCh. 10 - Prob. 46QAPCh. 10 - Prob. 47QAPCh. 10 - Prob. 48QAPCh. 10 - Prob. 49QAPCh. 10 - Prob. 50QAPCh. 10 - Prob. 51QAPCh. 10 - Prob. 52QAPCh. 10 - Prob. 53QAPCh. 10 - Prob. 54QAPCh. 10 - Prob. 55QAPCh. 10 - Prob. 56QAPCh. 10 - Prob. 57QAPCh. 10 - Prob. 58QAPCh. 10 - Prob. 59QAPCh. 10 - Prob. 60QAPCh. 10 - If a reaction occurs readily but has an...Ch. 10 - Prob. 62QAPCh. 10 - Prob. 63QAPCh. 10 - Prob. 64QAPCh. 10 - Prob. 65APCh. 10 - Calculate the enthalpy change when 1.0(1 g of...Ch. 10 - Prob. 67APCh. 10 - Calculate the amount of energy required (in...Ch. 10 - If takes 1.25 kJ of energy to heat a certain...Ch. 10 - What quantity of heat energy would have to be...Ch. 10 - The specific heat capacity of gold is 0.13 J/g °C....Ch. 10 - Calculate the amount of energy required (in...Ch. 10 - If 10. J of heat is applied to 5.0-g samples of...Ch. 10 - A 50.1)-g sample of water at 100. °C is poured...Ch. 10 - A 25.0-g sample of pure iron at 85 °C is dropped...Ch. 10 - If 7.24 kJ of heat is applied to a 952-g block of...Ch. 10 - For each of the substances listed in Table 10.1,...Ch. 10 - A system releases 213 kJ of heat and has a...Ch. 10 - Prob. 79APCh. 10 - Calculate the enthalpy change when 5.00 g of...Ch. 10 - Prob. 81APCh. 10 - Prob. 82APCh. 10 - It has been determined that the body can generate...Ch. 10 - Prob. 84APCh. 10 - Prob. 85CPCh. 10 - The specific heat capacity of graphite is 0.71 J/g...Ch. 10 - A swimming pool, 10.0 in by 4.0 m, is filled with...Ch. 10 - Prob. 88CPCh. 10 - Prob. 89CP
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