BuyFind

Chemistry for Engineering Students

3rd Edition
Lawrence S. Brown + 1 other
Publisher: Cengage Learning
ISBN: 9781285199023
BuyFind

Chemistry for Engineering Students

3rd Edition
Lawrence S. Brown + 1 other
Publisher: Cengage Learning
ISBN: 9781285199023

Solutions

Chapter 11, Problem 11.27PAE
Textbook Problem

11.27 Show that if the units of rate are mol L_1 s-1, then the units of the rate constant for the following second-order reaction are L mol-1 s-1:

H,(g) + Br2(g) — 2 HBrrate = * (HJ[BrJ

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Chapter 11 Solutions

Chemistry for Engineering Students
Ch. 11 - Describe what would happen to the ozone molecules...Ch. 11 - In what region of the atmosphere is ozone...Ch. 11 - What are the steps in the Chapman cycle? Explain...Ch. 11 - What is the net chemical reaction associated with...Ch. 11 - At what points in the Chapman cycle do...Ch. 11 - Which photochemical reaction in the Chapman cycle...Ch. 11 - Describe what is meant by the term ozone hole....Ch. 11 - Is the ozone hole permanent?Ch. 11 - For each of the following, suggest appropriate...Ch. 11 - For each of the following, suggest an appropriate...Ch. 11 - Rank the following in order of increasing reaction...Ch. 11 - Distinguish between instantaneous rate and average...Ch. 11 - Candle wax is a mixture of hydrocarbons. In the...Ch. 11 - In the description of the candle in Figure 11.2,...Ch. 11 - The reaction for the Haber process, the industrial...Ch. 11 - 11.17 Ammonia can react with oxygen to produce...Ch. 11 - The following data were obtained in the...Ch. 11 - A gas, AB, decomposes and the volume of B?...Ch. 11 - Experimental data are listed here for the reaction...Ch. 11 - Azomethane, CH3NNCH3, is not a stable compound,...Ch. 11 - Which of the following would be likely to have a...Ch. 11 - A reaction has the experimental rate equation Rate...Ch. 11 - Second-order rate constants used in modeling...Ch. 11 - For each of the rate laws below, what is the order...Ch. 11 - 11.26 The reaction of C(Xg) with NO2(g) is second...Ch. 11 - 11.27 Show that if the units of rate are mol L_1...Ch. 11 - One reaction that destroys O} molecules in the...Ch. 11 - The hypothetical reaction, A + B —*C, has the rate...Ch. 11 - The rate of the decomposition of hydrogen...Ch. 11 - 11.31 Give the order with respect to each reactant...Ch. 11 - 11.32 The following experimental data were...Ch. 11 - The following experimental data were obtained for...Ch. 11 - 11.34 Rate data were obtained at 25°C for the...Ch. 11 - 11.35 For the reaction 2 NO(g) + 2 H?(g) — N,(g) +...Ch. 11 - The reaction NO(g) + O,(g) — NO,(g) + 0(g) plays a...Ch. 11 - In a heterogeneous system such as wood burning in...Ch. 11 - In wheat-growing areas, such as the plains of the...Ch. 11 - The decomposition of N2O5 in solution in carbon...Ch. 11 - In Exercise 11.39, if the initial concentration of...Ch. 11 - 11.41 For a drug to be effective in treating an...Ch. 11 - Amoxicillin is an antibiotic packaged as a powder....Ch. 11 - As with any drug, aspirin (acetylsalicylic acid)...Ch. 11 - 11.44 A possible reaction for the degradation of...Ch. 11 - The initial concentration of the reactant in a...Ch. 11 - A substance undergoes first-order decomposition....Ch. 11 - 11.47 Show that the half-life of a second-order...Ch. 11 - 11.48 The following data were collected for the...Ch. 11 - The rate of photodecomposition of the herbicide...Ch. 11 - The rate of decomposition of SO?C12 according to...Ch. 11 - 11.51 Peroxyacetyl nitrate (PAN) has the chemical...Ch. 11 - The following series of pictures represents the...Ch. 11 - Hydrogen peroxide (H20i) decomposes into water and...Ch. 11 - use the kineticmolecular theory to explain why an...Ch. 11 - The activation energy for the reaction in which...Ch. 11 - The labels on most pharmaceuticals state that the...Ch. 11 - The following rate constants were obtained in an...Ch. 11 - The table below presents measured rate constants...Ch. 11 - The table below presents rate constants measured...Ch. 11 - Many reactions occur in the formation of...Ch. 11 - Bacteria cause milk to go sour by generating...Ch. 11 - Define the term intermediate in the context of...Ch. 11 - Can a reaction mechanism ever be proven correct?...Ch. 11 - 11.60 What is the rate law tor each of the...Ch. 11 - Describe how the Chapman cycle is a reaction...Ch. 11 - What are the reaction intermediates in the Chapman...Ch. 11 - Propane is used as a household fuel in areas where...Ch. 11 - Five people are responsible for cleaning up after...Ch. 11 - The following mechanism is proposed for a...Ch. 11 - 11.64 HBr is oxidized in the following reaction: 4...Ch. 11 - The reaction of NO?(g) and C0(g) is thought to...Ch. 11 - If a textbook defined a catalyst as "a substance...Ch. 11 - The word catalyst has been adopted outside of...Ch. 11 - In the process by which CFCs contribute to the...Ch. 11 - What distinguishes homogeneous and heterogeneous...Ch. 11 - define the terms adsorbed and desorbed. Do the...Ch. 11 - Based on the kinetic theory of matter, what would...Ch. 11 - Draw a hypothetical activation energy diagram for...Ch. 11 - In Chapter 3, we discussed the conversion of...Ch. 11 - The label on a bottle of 3% (by volume) hydrogen...Ch. 11 - Why is smog appropriately labeled photochemical...Ch. 11 - When oxygen molecules, O2, react with oxygen atoms...Ch. 11 - What is a VOC? What role do VOCs play in...Ch. 11 - Why does the formation of ozone in smog depend on...Ch. 11 - Many urban centers in North America do not meet...Ch. 11 - Ozone is not stable at pressures typically found...Ch. 11 - Why do ozone concentrations lag in time relative...Ch. 11 - Reducing ozone formation in photochemical smog...Ch. 11 - Find a website that tells you whether you live in...Ch. 11 - Use the web to find out what it means if the U.S....Ch. 11 - Western Michigan can experience higher than normal...Ch. 11 - Along the Front Range of Colorado, the greatest...Ch. 11 - According to an article published in 1966 in the...Ch. 11 - 11.92 In the previous problem, the reaction to...Ch. 11 - 11.93 On a particular day, the ozone level in...Ch. 11 - 11.94 The EPA’s 8-hour ozone standard for...Ch. 11 - The following is a thought experiment. Imagine...Ch. 11 - The following statements relate to the reaction...Ch. 11 - The Haber process, which produces ammonia from...Ch. 11 - Experiments show that the reaction of nitrogen...Ch. 11 - Substances that poison a catalyst pose a major...Ch. 11 - 11.100 Chemical engineering design often uses mol%...Ch. 11 - 11.101 The flashing of fireflies is the result of...Ch. 11 - 11.102 Suppose that you are studying a reaction...Ch. 11 - 11.103 You measure an archeological specimen and...Ch. 11 - 11.104 At room temperature, it takes about 3 days...Ch. 11 - 11.105 You are designing a seif-heating food...Ch. 11 - 11.106 Use the web to look up the rates of...Ch. 11 - 11.1047 Fluorine often reacts explosively. What...Ch. 11 - 11.108 In Chapter 4, we noted that compressibility...Ch. 11 - 11.109 A free radical is often used as a catalyst...Ch. 11 - When formic acid is heated, it decomposes to...

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