(a) Interpretation: Interpret the following statement is true or false. ‘cis and trans cycloalkane are present with same molar formula with different connectivity.’. Concept Introduction: The position of the substituent attached on the carbon having restricted rotation decides the cis or trans isomerism. If the substituent facing the same side then cis isomerism is observed while the substituent facing the opposite side then trans isomerism is observed.

Question

1. a. Draw and name the five cycloalkane structures of formula C5H10. Can any of these structures give rise to geometric (cis-trans) isomerism? If so, show the cis and trans stereoisomers. b. Draw and name the eight cycloalkane structures of formula C6H12 that do not show geometric isomerism. c. Draw and name the four cycloalkanes of formula C6H12 that do have cis-trans isomers. 2. Each of the following descriptions applies to more than one alkane. In each case, draw and name two structures that match the description. (a) an isopropylheptane (b) a diethyldecane (c) a cis-diethylcyclohexane (d) a trans-dihalocyclopentane (e) a (2,3-dimethylpentyl)cycloalkane (f) a bicyclononane 3. 2. refer to the photo attached and answer the ff.3-33, 3-34

Answer 1

Question

Chapter 11, Problem 11.33P

Interpretation Introduction

(a)

Interpretation:

Interpret the following statement is true or false.

‘cis and trans cycloalkane are present with same molar formula with different connectivity.’.

Concept Introduction:

The position of the substituent attached on the carbon having restricted rotation decides the cis or trans isomerism.

If the substituent facing the same side then cis isomerism is observed while the substituent facing the opposite side then trans isomerism is observed.

Interpretation Introduction

(b)

Interpretation:

Interpret the following statement is true or false.

‘cis can be transferred to trans isomer by rotation of the carbon single bonded to carbon.’.

Concept Introduction:

The position of the substituent attached on the carbon having restricted rotation decides the cis or trans isomerism.

If the substituent facing the same side then cis isomerism is observed while the substituent facing the opposite side then trans isomerism is observed.

Interpretation Introduction

(c)

Interpretation:

Interpret the following statement is true or false.

‘cis can be transferred to trans isomer by exchanging the two groups.’.

Concept Introduction:

The position of the substituent attached on the carbon having restricted rotation decides the cis or trans isomerism.

If the substituent facing the same side then cis isomerism is observed while the substituent facing the opposite side then trans isomerism is observed.

Interpretation Introduction

(d)

Interpretation:

Interpret the following statement is true or false.

‘configuration means arrangement of atom in space.’.

Concept Introduction:

The position of the substituent attached on the carbon having restricted rotation decides the cis or trans isomerism.

If the substituent facing the same side then cis isomerism is observed while the substituent facing the opposite side then trans isomerism is observed.

Interpretation Introduction

(e)

Interpretation:

Interpret the following statement is true or false.

‘cis-1,4-dimethylcyclohexane and trans-1,4-dimethylcyclohexane are conformers.’.

Concept Introduction:

The position of the substituent attached on the carbon having restricted rotation decides the cis or trans isomerism.

If the substituent facing the same side then cis isomerism is observed while the substituent facing the opposite side then trans isomerism is observed.

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1. a. Draw and name the five cycloalkane structures of formula C5H10. Can any of these structures give rise to geometric (cis-trans) isomerism? If so, show the cis and trans stereoisomers. b. Draw and name the eight cycloalkane structures of formula C6H12 that do not show geometric isomerism. c. Draw and name the four cycloalkanes of formula C6H12 that do have cis-trans isomers. 2. Each of the following descriptions applies to more than one alkane. In each case, draw and name two structures that match the description. (a) an isopropylheptane (b) a diethyldecane (c) a cis-diethylcyclohexane (d) a trans-dihalocyclopentane (e) a (2,3-dimethylpentyl)cycloalkane (f) a bicyclononane 3. 2. refer to the photo attached and answer the ff.3-33, 3-34

1. Considering compounds that have the same number of carbon atoms, explain why alkanes and cycloalkanes have different molecular formulas but alkenes and cycloalkanes have the same molecular formulas. 2. Draw the condensed or line-angle structure for an alkene with the formula C5H10. 3. Draw the condensed or line-angle structure for 4 more C5H10 isomers (2 additional alkenes and 2 cyclic isomers).

Which of the following cycloalkanes are capable of geometric (cis-trans) isomerism?Draw the cis and trans isomers.(a) 3-ethyl-1,1-dimethylcyclohexane (b) 1-ethyl-3-methylcycloheptane(c) 1-ethyl-3-methylcyclopentane (d) 1-cyclopropyl-2-methylcyclohexane

Answer 2

Question

Chapter 11, Problem 11.33P

Interpretation Introduction

(a)

Interpretation:

Interpret the following statement is true or false.

‘cis and trans cycloalkane are present with same molar formula with different connectivity.’.

Concept Introduction:

The position of the substituent attached on the carbon having restricted rotation decides the cis or trans isomerism.

If the substituent facing the same side then cis isomerism is observed while the substituent facing the opposite side then trans isomerism is observed.

Interpretation Introduction

(b)

Interpretation:

Interpret the following statement is true or false.

‘cis can be transferred to trans isomer by rotation of the carbon single bonded to carbon.’.

Concept Introduction:

The position of the substituent attached on the carbon having restricted rotation decides the cis or trans isomerism.

If the substituent facing the same side then cis isomerism is observed while the substituent facing the opposite side then trans isomerism is observed.

Interpretation Introduction

(c)

Interpretation:

Interpret the following statement is true or false.

‘cis can be transferred to trans isomer by exchanging the two groups.’.

Concept Introduction:

The position of the substituent attached on the carbon having restricted rotation decides the cis or trans isomerism.

If the substituent facing the same side then cis isomerism is observed while the substituent facing the opposite side then trans isomerism is observed.

Interpretation Introduction

(d)

Interpretation:

Interpret the following statement is true or false.

‘configuration means arrangement of atom in space.’.

Concept Introduction:

The position of the substituent attached on the carbon having restricted rotation decides the cis or trans isomerism.

If the substituent facing the same side then cis isomerism is observed while the substituent facing the opposite side then trans isomerism is observed.

Interpretation Introduction

(e)

Interpretation:

Interpret the following statement is true or false.

‘cis-1,4-dimethylcyclohexane and trans-1,4-dimethylcyclohexane are conformers.’.

Concept Introduction:

The position of the substituent attached on the carbon having restricted rotation decides the cis or trans isomerism.

If the substituent facing the same side then cis isomerism is observed while the substituent facing the opposite side then trans isomerism is observed.

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Answer 3

Question

Chapter 11, Problem 11.33P

Interpretation Introduction

(a)

Interpretation:

Interpret the following statement is true or false.

‘cis and trans cycloalkane are present with same molar formula with different connectivity.’.

Concept Introduction:

The position of the substituent attached on the carbon having restricted rotation decides the cis or trans isomerism.

If the substituent facing the same side then cis isomerism is observed while the substituent facing the opposite side then trans isomerism is observed.

Interpretation Introduction

(b)

Interpretation:

Interpret the following statement is true or false.

‘cis can be transferred to trans isomer by rotation of the carbon single bonded to carbon.’.

Concept Introduction:

The position of the substituent attached on the carbon having restricted rotation decides the cis or trans isomerism.

If the substituent facing the same side then cis isomerism is observed while the substituent facing the opposite side then trans isomerism is observed.

Interpretation Introduction

(c)

Interpretation:

Interpret the following statement is true or false.

‘cis can be transferred to trans isomer by exchanging the two groups.’.

Concept Introduction:

The position of the substituent attached on the carbon having restricted rotation decides the cis or trans isomerism.

If the substituent facing the same side then cis isomerism is observed while the substituent facing the opposite side then trans isomerism is observed.

Interpretation Introduction

(d)

Interpretation:

Interpret the following statement is true or false.

‘configuration means arrangement of atom in space.’.

Concept Introduction:

The position of the substituent attached on the carbon having restricted rotation decides the cis or trans isomerism.

If the substituent facing the same side then cis isomerism is observed while the substituent facing the opposite side then trans isomerism is observed.

Interpretation Introduction

(e)

Interpretation:

Interpret the following statement is true or false.

‘cis-1,4-dimethylcyclohexane and trans-1,4-dimethylcyclohexane are conformers.’.

Concept Introduction:

The position of the substituent attached on the carbon having restricted rotation decides the cis or trans isomerism.

If the substituent facing the same side then cis isomerism is observed while the substituent facing the opposite side then trans isomerism is observed.

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Answer 4

Question

Chapter 11, Problem 11.33P

Interpretation Introduction

(a)

Interpretation:

Interpret the following statement is true or false.

‘cis and trans cycloalkane are present with same molar formula with different connectivity.’.

Concept Introduction:

The position of the substituent attached on the carbon having restricted rotation decides the cis or trans isomerism.

If the substituent facing the same side then cis isomerism is observed while the substituent facing the opposite side then trans isomerism is observed.

Interpretation Introduction

(b)

Interpretation:

Interpret the following statement is true or false.

‘cis can be transferred to trans isomer by rotation of the carbon single bonded to carbon.’.

Concept Introduction:

The position of the substituent attached on the carbon having restricted rotation decides the cis or trans isomerism.

If the substituent facing the same side then cis isomerism is observed while the substituent facing the opposite side then trans isomerism is observed.

Interpretation Introduction

(c)

Interpretation:

Interpret the following statement is true or false.

‘cis can be transferred to trans isomer by exchanging the two groups.’.

Concept Introduction:

The position of the substituent attached on the carbon having restricted rotation decides the cis or trans isomerism.

If the substituent facing the same side then cis isomerism is observed while the substituent facing the opposite side then trans isomerism is observed.

Interpretation Introduction

(d)

Interpretation:

Interpret the following statement is true or false.

‘configuration means arrangement of atom in space.’.

Concept Introduction:

The position of the substituent attached on the carbon having restricted rotation decides the cis or trans isomerism.

If the substituent facing the same side then cis isomerism is observed while the substituent facing the opposite side then trans isomerism is observed.

Interpretation Introduction

(e)

Interpretation:

Interpret the following statement is true or false.

‘cis-1,4-dimethylcyclohexane and trans-1,4-dimethylcyclohexane are conformers.’.

Concept Introduction:

The position of the substituent attached on the carbon having restricted rotation decides the cis or trans isomerism.

If the substituent facing the same side then cis isomerism is observed while the substituent facing the opposite side then trans isomerism is observed.

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Answer 5

Chapter 11, Problem 11.33P

Interpretation Introduction

(a)

Interpretation:

Interpret the following statement is true or false.

‘cis and trans cycloalkane are present with same molar formula with different connectivity.’.

Concept Introduction:

The position of the substituent attached on the carbon having restricted rotation decides the cis or trans isomerism.

If the substituent facing the same side then cis isomerism is observed while the substituent facing the opposite side then trans isomerism is observed.

Interpretation Introduction

(b)

Interpretation:

Interpret the following statement is true or false.

‘cis can be transferred to trans isomer by rotation of the carbon single bonded to carbon.’.

Concept Introduction:

The position of the substituent attached on the carbon having restricted rotation decides the cis or trans isomerism.

If the substituent facing the same side then cis isomerism is observed while the substituent facing the opposite side then trans isomerism is observed.

Interpretation Introduction

(c)

Interpretation:

Interpret the following statement is true or false.

‘cis can be transferred to trans isomer by exchanging the two groups.’.

Concept Introduction:

The position of the substituent attached on the carbon having restricted rotation decides the cis or trans isomerism.

If the substituent facing the same side then cis isomerism is observed while the substituent facing the opposite side then trans isomerism is observed.

Interpretation Introduction

(d)

Interpretation:

Interpret the following statement is true or false.

‘configuration means arrangement of atom in space.’.

Concept Introduction:

The position of the substituent attached on the carbon having restricted rotation decides the cis or trans isomerism.

If the substituent facing the same side then cis isomerism is observed while the substituent facing the opposite side then trans isomerism is observed.

Interpretation Introduction

(e)

Interpretation:

Interpret the following statement is true or false.

‘cis-1,4-dimethylcyclohexane and trans-1,4-dimethylcyclohexane are conformers.’.

Concept Introduction:

The position of the substituent attached on the carbon having restricted rotation decides the cis or trans isomerism.

If the substituent facing the same side then cis isomerism is observed while the substituent facing the opposite side then trans isomerism is observed.

Answer 6

Chapter 11, Problem 11.33P

Interpretation Introduction

(a)

Interpretation:

Interpret the following statement is true or false.

‘cis and trans cycloalkane are present with same molar formula with different connectivity.’.

Concept Introduction:

The position of the substituent attached on the carbon having restricted rotation decides the cis or trans isomerism.

If the substituent facing the same side then cis isomerism is observed while the substituent facing the opposite side then trans isomerism is observed.

Answer 7

Chapter 11, Problem 11.33P

Interpretation Introduction

(a)

Interpretation:

Interpret the following statement is true or false.

‘cis and trans cycloalkane are present with same molar formula with different connectivity.’.

Concept Introduction:

The position of the substituent attached on the carbon having restricted rotation decides the cis or trans isomerism.

If the substituent facing the same side then cis isomerism is observed while the substituent facing the opposite side then trans isomerism is observed.

Answer 8

Interpretation Introduction

(b)

Interpretation:

Interpret the following statement is true or false.

‘cis can be transferred to trans isomer by rotation of the carbon single bonded to carbon.’.

Concept Introduction:

The position of the substituent attached on the carbon having restricted rotation decides the cis or trans isomerism.

If the substituent facing the same side then cis isomerism is observed while the substituent facing the opposite side then trans isomerism is observed.

Answer 9

Interpretation Introduction

(b)

Interpretation:

Interpret the following statement is true or false.

‘cis can be transferred to trans isomer by rotation of the carbon single bonded to carbon.’.

Concept Introduction:

The position of the substituent attached on the carbon having restricted rotation decides the cis or trans isomerism.

If the substituent facing the same side then cis isomerism is observed while the substituent facing the opposite side then trans isomerism is observed.

Answer 10

Interpretation Introduction

(c)

Interpretation:

Interpret the following statement is true or false.

‘cis can be transferred to trans isomer by exchanging the two groups.’.

Concept Introduction:

The position of the substituent attached on the carbon having restricted rotation decides the cis or trans isomerism.

If the substituent facing the same side then cis isomerism is observed while the substituent facing the opposite side then trans isomerism is observed.

Answer 11

Interpretation Introduction

(c)

Interpretation:

Interpret the following statement is true or false.

‘cis can be transferred to trans isomer by exchanging the two groups.’.

Concept Introduction:

The position of the substituent attached on the carbon having restricted rotation decides the cis or trans isomerism.

If the substituent facing the same side then cis isomerism is observed while the substituent facing the opposite side then trans isomerism is observed.

Answer 12

Interpretation Introduction

(d)

Interpretation:

Interpret the following statement is true or false.

‘configuration means arrangement of atom in space.’.

Concept Introduction:

The position of the substituent attached on the carbon having restricted rotation decides the cis or trans isomerism.

If the substituent facing the same side then cis isomerism is observed while the substituent facing the opposite side then trans isomerism is observed.

Answer 13

Interpretation Introduction

(d)

Interpretation:

Interpret the following statement is true or false.

‘configuration means arrangement of atom in space.’.

Concept Introduction:

The position of the substituent attached on the carbon having restricted rotation decides the cis or trans isomerism.

If the substituent facing the same side then cis isomerism is observed while the substituent facing the opposite side then trans isomerism is observed.

Answer 14

Interpretation Introduction

(e)

Interpretation:

Interpret the following statement is true or false.

‘cis-1,4-dimethylcyclohexane and trans-1,4-dimethylcyclohexane are conformers.’.

Concept Introduction:

The position of the substituent attached on the carbon having restricted rotation decides the cis or trans isomerism.

If the substituent facing the same side then cis isomerism is observed while the substituent facing the opposite side then trans isomerism is observed.

Answer 15

Interpretation Introduction

(e)

Interpretation:

Interpret the following statement is true or false.

‘cis-1,4-dimethylcyclohexane and trans-1,4-dimethylcyclohexane are conformers.’.

Concept Introduction:

The position of the substituent attached on the carbon having restricted rotation decides the cis or trans isomerism.

If the substituent facing the same side then cis isomerism is observed while the substituent facing the opposite side then trans isomerism is observed.

Answer 16

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Ch. 11.2 - Prob. 11.1P Ch. 11.3 - Prob. 11.2P Ch. 11.3 - Prob. 11.3P Ch. 11.4 - Problem 11-4 Write the molecular formula and IUPAC...Ch. 11.6 - Problem 11-5 Write the molecular formula and IUPAC...Ch. 11.7 - Prob. 11.6P Ch. 11.8 - Prob. 11.7P Ch. 11.9 - Prob. 11.8P Ch. 11.10 - Prob. 11.9P Ch. 11 - Answer true or false. A hydrocarbon is composed...

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