Physical Chemistry
Physical Chemistry
2nd Edition
ISBN: 9781133958437
Author: Ball, David W. (david Warren), BAER, Tomas
Publisher: Wadsworth Cengage Learning,
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Chapter 11, Problem 11.65E
Interpretation Introduction

Interpretation:

The validation of the statement that for constant r and V=0, equation 11.56 becomes equation 11.46 is to be stated.

Concept introduction:

Rigid rotor is a system in which more than one particle has fixed relative positions and it rotates in the three dimensional space.

The Schrödinger equation in three dimensional space is given by,

{22μ[1r2r(r2r)+1r2sinθθ(sinθθ)+1r2sin2θ2ϕ2]+V^}Ψ=EΨ

The spherical polar coordinates are θ, ϕ and r.

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Chapter 11 Solutions

Physical Chemistry

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