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ChemistryPhysical ChemistryWhat is the numerical value of the total angular momentum of an electron in an f subshell of an H atom? What is it for an f electron in Li 2 + ?

What is the numerical value of the total angular momentum of an electron in an f subshell of an H atom? What is it for an f electron in Li 2 + ?

BuyFind

Physical Chemistry

2nd Edition
Ball + 3 others
Publisher: Wadsworth Cengage Learning,
ISBN: 9781133958437
BuyFind

Physical Chemistry

2nd Edition
Ball + 3 others
Publisher: Wadsworth Cengage Learning,
ISBN: 9781133958437

Solutions

Chapter
Section
Problem 11.1E
Problem 11.2E
Problem 11.3E
Problem 11.4E
Problem 11.5E
Problem 11.6E
Problem 11.7E
Problem 11.8E
Problem 11.9E
Problem 11.10E
Problem 11.11E
Problem 11.12E
Problem 11.13E
Problem 11.14E
Problem 11.15E
Problem 11.16E
Problem 11.17E
Problem 11.18E
Problem 11.19E
Problem 11.20E
Problem 11.21E
Problem 11.22E
Problem 11.23E
Problem 11.24E
Problem 11.25E
Problem 11.26E
Problem 11.27E
Problem 11.28E
Problem 11.29E
Problem 11.30E
Problem 11.31E
Problem 11.32E
Problem 11.33E
Problem 11.34E
Problem 11.35E
Problem 11.36E
Problem 11.37E
Problem 11.38E
Problem 11.39E
Problem 11.40E
Problem 11.41E
Problem 11.42E
Problem 11.43E
Problem 11.44E
Problem 11.45E
Problem 11.46E
Problem 11.47E
Problem 11.48E
Problem 11.49E
Problem 11.50E
Problem 11.51E
Problem 11.52E
Problem 11.53E
Problem 11.54E
Problem 11.55E
Problem 11.56E
Problem 11.57E
Problem 11.58E
Problem 11.59E
Problem 11.60E
Problem 11.61E
Problem 11.62E
Problem 11.63E
Problem 11.64E
Problem 11.65E
Problem 11.66E
Problem 11.67E
Problem 11.68E
Problem 11.69E
Problem 11.70E
Problem 11.71E
Problem 11.72E
Problem 11.73E
Problem 11.74E
Problem 11.75E
Problem 11.76E
Problem 11.77E
Problem 11.78E
Problem 11.79E
Problem 11.80E
Problem 11.81E
Problem 11.82E
Problem 11.83E
Problem 11.84E
Problem 11.85E
Problem 11.86E
Problem 11.87E
Problem 11.88E
Problem 11.89E
Problem 11.90E
Problem 11.91E
Problem 11.92E
Problem 11.93E
Problem 11.94E
Problem 11.95E
Problem 11.96E
Chapter 11, Problem 11.72E
Textbook Problem

What is the numerical value of the total angular momentum of an electron in an f subshell of an H atom? What is it for an f electron in Li 2 + ?

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Chapter 11,
Problem 11.71E
Chapter 11,
Problem 11.73E

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Chapter 11 Solutions

Physical Chemistry
Ch. 11 - Convert 3.558mdyn/A into units of N/m.Ch. 11 - A swinging pendulum has a frequency of 0.277Hz and...Ch. 11 - Calculate the frequency of a harmonic oscillator...Ch. 11 - A harmonic oscillator has a frequency of 7.04s1...Ch. 11 - An object having mass m at some height above the...Ch. 11 - What are the units on ? Do they make sense in...Ch. 11 - In equation 11.6, in order to properly subtract...Ch. 11 - Verify that the three substitutions mentioned in...Ch. 11 - Verify that the second derivative of given by...Ch. 11 - Derive equation 11.15 from the expression...
Ch. 11 - Derive equation 11.16 from the equation...Ch. 11 - Show that the energy separation between any two...Ch. 11 - a For a pendulum having classical frequency of...Ch. 11 - a A hydrogen atom bonded to a surface is acting as...Ch. 11 - The OH bond in water vibrates at a frequency of...Ch. 11 - Show that 2 and 3 for the harmonic oscillator are...Ch. 11 - Substitute 1 into the complete expression for the...Ch. 11 - Demonstrate that x=0 for any wavefunction of a...Ch. 11 - Calculate px for 0 and 1 for a harmonic...Ch. 11 - Use the expression for 1 in equations 11.17 and...Ch. 11 - Derive equation 11.19 from the information in...Ch. 11 - Simply using arguments based on odd or even...Ch. 11 - Consider Figure 11.4 and choose the correct...Ch. 11 - Based on the trend shown in Figure 11.5, draw the...Ch. 11 - What is x2 for 0 of a harmonic oscillator? Is it...Ch. 11 - Use your answer to exercise 11.25 to determine V...Ch. 11 - Determine the valuess of x for the classical...Ch. 11 - Determine a formula in terms of n for the number...Ch. 11 - What are the values of x for the nodes for 3 of a...Ch. 11 - Derive equation 11.23 from the expression...Ch. 11 - Compare the mass of the electron, me, with a the...Ch. 11 - Reduced mass is not reserved only for atomic...Ch. 11 - a Calculate the expected harmonic-oscillator...Ch. 11 - An OH bond has a frequency of 3650cm1. Using...Ch. 11 - The force constant in the HD molecule (D=2H) is...Ch. 11 - Why cant the quantized values of the 2-D angular...Ch. 11 - Show that 3 of 2-D rotational motion has the same...Ch. 11 - Show that 1 and 2 for 2-D rotational motion are...Ch. 11 - Show that the 2-D rotational motion wavefunctions...Ch. 11 - What are the energies and angular momenta of the...Ch. 11 - A proton rotates in a circle of radius 5.001011m....Ch. 11 - A 25-kg child is on a merry-go-round/calliope,...Ch. 11 - Using Eulers identity, rewrite the first four 2-D...Ch. 11 - a Using the expression for the energy of a 2-D...Ch. 11 - Derive equation 11.35 from 11.34.Ch. 11 - If a zero-point energy were defined for 2-D...Ch. 11 - A colleague proposed a simplification in the...Ch. 11 - The quantized angular momentum is choose one:...Ch. 11 - Use trigonometry to verify the relationships...Ch. 11 - Why cant the square root of equation 11.45 be...Ch. 11 - For both 2-D and 3-D rotations, the radius of the...Ch. 11 - Can you evaluate r for the spherical harmonic Y22?...Ch. 11 - Show that 1,0 and 1,1 for 3-D rotational motion...Ch. 11 - Using the complete form of 3,2 where l=3 and ml=2...Ch. 11 - A 3-D rotational wavefunction has the quantum...Ch. 11 - a Using the he expression for the energy of a 3-D...Ch. 11 - See example 11.17, regarding the sphericalC60...Ch. 11 - In exercise 11.57 regarding C60, what are the...Ch. 11 - Draw the graphical representations see Figure...Ch. 11 - Using the definition of the cosine function as...Ch. 11 - What is the physical explanation of the difference...Ch. 11 - List the charges on hydrogen-like atoms whose...Ch. 11 - Calculate the electrostatic potential energy V...Ch. 11 - Using the Newton law of gravity and the...Ch. 11 - Show that for constant r and V=0, equation 11.56...Ch. 11 - Calculate the difference between the Bohr radius...Ch. 11 - To four significant figures, the first four lines...Ch. 11 - What would the wavelengths of the Balmer series...Ch. 11 - Construct an energy level diagram showing all...Ch. 11 - In Chapter 9, the topic of Rydberg atoms was...Ch. 11 - What is the degeneracy of an h subshell? An n...Ch. 11 - What is the numerical value of the total angular...Ch. 11 - What are the values of E, L, and Lz for an F8+...Ch. 11 - Verify the normalization constant in Table 11.4 by...Ch. 11 - Why does the wavefunction 4,4,0 not exist?...Ch. 11 - Calculate the total electronic energy of a mole of...Ch. 11 - What is the probability of finding an electron in...Ch. 11 - What is the probability of finding an electron in...Ch. 11 - For what wavefunctions and which hydrogen-like...Ch. 11 - For hydrogen-like ions with Z1, does the...Ch. 11 - State how many radial, angular, and total nodes...Ch. 11 - a For what value of does 3d0 have an angular...Ch. 11 - Illustrate that the hydrogen wavefunctions are...Ch. 11 - Verify the specific value of a, the Bohr radius,...Ch. 11 - Show that rmax is given by equation 11.68 for 1s....Ch. 11 - Use the forms of the wavefunctions in Table 11.4...Ch. 11 - Evaluate Lz for 3px, Compare it to the answer in...Ch. 11 - Calculate V for 1s of the H atom and compare it to...Ch. 11 - Verify equation 11.66 for 1s by substituting the...Ch. 11 - Using equations 11.67 as an example, what would be...Ch. 11 - Evaluate r for 1s assume that the operator r is...Ch. 11 - Redraw Figure 11.19 and all plots in Figure 11.20...Ch. 11 - Graph the first five wavefunctions for the...Ch. 11 - Construct three-dimensional plots of the first...Ch. 11 - Set up and evaluate numerically the integral that...Ch. 11 - Plot the 90 surfaces of the hydrogen atom 2s and...

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