ORGANIC CHEMISTRY,SOLN.MAN.+...-ACCESS
4th Edition
ISBN: 9781119659471
Author: Klein
Publisher: WILEY
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Chapter 11, Problem 22PP
Interpretation Introduction
Interpretation: The required product to be formed is
Concept Introduction: Acetylene is used as the only source of carbon atoms, which contains two carbon atoms. The required product has an even number of carbon atoms, also acetylene has an even number of carbon atoms. Using the appropriate reagent and mechanism, acetylene can be converted into the product.
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10) Synthesis: Make the following products from a suitable cyclic alkene starting material. Look
at the functional group PATTERN present in the molecule, including stereochemistry.
Br
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Br
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Propose a structure for an aromatic hydrocarbon, C,H12, that can form two CH11C1 products on substitution of a hydrogen on the aromatic ring with chlorine.
Choose 2 of the 3 compounds and provide a synthesis starting with benzene and any other carbon compound with four or less carbons.
Chapter 11 Solutions
ORGANIC CHEMISTRY,SOLN.MAN.+...-ACCESS
Ch. 11.1 - Prob. 1CCCh. 11.1 - Prob. 2CCCh. 11.2 - Prob. 1LTSCh. 11.2 - Prob. 3PTSCh. 11.3 - Prob. 2LTSCh. 11.3 - Prob. 6ATSCh. 11.4 - Prob. 3LTSCh. 11.4 - Prob. 7PTSCh. 11.4 - Prob. 8ATSCh. 11.5 - Prob. 4LTS
Ch. 11.5 - Propose an efficient synthesis for each of the...Ch. 11.5 - Prob. 10ATSCh. 11 - Prob. 11PPCh. 11 - Prob. 12PPCh. 11 - Prob. 13PPCh. 11 - Prob. 14PPCh. 11 - Prob. 15PPCh. 11 - Prob. 16PPCh. 11 - Prob. 17PPCh. 11 - Prob. 18PPCh. 11 - Prob. 19PPCh. 11 - Prob. 20PPCh. 11 - Prob. 21PPCh. 11 - Prob. 22PPCh. 11 - Prob. 23PPCh. 11 - Prob. 24PPCh. 11 - Prob. 25PPCh. 11 - Prob. 26ASPCh. 11 - Prob. 27ASPCh. 11 - Prob. 28ASPCh. 11 - Prob. 29ASPCh. 11 - Prob. 30ASPCh. 11 - Prob. 31ASPCh. 11 - Prob. 32ASPCh. 11 - Prob. 33IPCh. 11 - Prob. 34IPCh. 11 - Prob. 35IPCh. 11 - Prob. 36IPCh. 11 - Prob. 37IPCh. 11 - Prob. 38IPCh. 11 - Prob. 39IPCh. 11 - Prob. 42CPCh. 11 - The compound Z-3-hexenyl acetate is one of several...Ch. 11 - When a consumer purchases a tomato, smell is one...Ch. 11 - Prob. 45CPCh. 11 - Prob. 46CP
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- Using acetylene as the starting material, propose a synthesis of 3-hexyne:arrow_forwardStarting with cyclohexane and using any other carbon compounds containing 3 carbons or less, synthesize two of the following compounds. These will be multi-step processes. CH a) H,C b) CH, HO c) HO.arrow_forwardHow to synthesize 2-methylhexane from acetylene?arrow_forward
- Draw the structure of each product from the reaction of benzene with 2-chloro-1-methylcyclohexane using AlCl 3 as the catalyst and Identify the major product.arrow_forwardHow can trans-2-pentene be prepared using ethyne as the starting material?arrow_forwardWhat is the major product obtained from hydroboration–oxidation of 2-methyl-2-butene? Draw the molecule.arrow_forward
- Draw a structural formula for an alkene with the indicated molecular formula that gives the compound shown as the major product (more than one alkene may give the same compound as the major product).arrow_forwardUsing your reaction roadmap as a guide, show how to convert ethylene into 1-butene. All of the carbon atoms of the target molecule must be derived from ethylene. Show all intermediate molecules synthesized along the way. Ethylene 1-Butenearrow_forwardAnother important pattern in organic synthesis is the construction of CC bonds. Using your reaction roadmap as a guide, show how to convert propane into hex-1-en-4-yne. You must use propane as the source of all of the carbon atoms in the hex-1-en-4-yne product. Show all reagents needed and all molecules synthesized along the way.arrow_forward
- What are the products formed from the following reactions: 1) The addition of dimethylborane (Me2BH) to ethylene 2) The addition of dimethylborane (Me2BH) to acetylene Please include the formulas for the products as well. Thank you!arrow_forwardFrom benzene and compounds of 4 carbons or less and any reagents you want; synthesize the following compound.arrow_forwardAnother important pattern in organic synthesis is the construction of C-C bonds. Us- ing your reaction roadmap as a guide, show how to convert propane into hex-1-en-4- yne. You must use propane as the source of all of the carbon atoms in the hex-1-en-4-yne product. Show all reagents needed and all molecules synthesized along the way. Propane Hex-1-en-4-ynearrow_forward
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