Introductory Chemistry: A Foundation
8th Edition
ISBN: 9781285199030
Author: Steven S. Zumdahl, Donald J. DeCoste
Publisher: Cengage Learning
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Textbook Question
Chapter 11, Problem 30QAP
Consider the following representation of a set of
mg src=Images/HTML_99425-11-30QAP_image001.jpg alt="" align="top"/>
ich of the following statements is(are) true?
The areas represented by the
The nucleus is located at the center point of each axis.
The electrons move along the elliptical paths as indicated by the
The atom could not be hydrogen because its electron is found in the
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Chapter 11 Solutions
Introductory Chemistry: A Foundation
Ch. 11.4 - now have evidence that electron energy levels in...Ch. 11.8 - Prob. 11.1SCCh. 11.9 - Prob. 11.2SCCh. 11.10 - Prob. 11.3SCCh. 11.10 - Prob. 1CTCh. 11 - ow does probability ?t into the description of the...Ch. 11 - Prob. 2ALQCh. 11 - Prob. 3ALQCh. 11 - onsider the following statements: “The ionization...Ch. 11 - n going across a row of the periodic table,...
Ch. 11 - Prob. 6ALQCh. 11 - rue or false? The hydrogen atom has a 3 orbital....Ch. 11 - Prob. 8ALQCh. 11 - ake sense of the fact that metals tend to lose...Ch. 11 - Show how using the periodic table helps you find...Ch. 11 - r Questions 11—13, you will need to consider...Ch. 11 - Prob. 12ALQCh. 11 - Prob. 13ALQCh. 11 - Prob. 14ALQCh. 11 - Prob. 15ALQCh. 11 - What evidence do we have that energy levels in an...Ch. 11 - Explain the hydrogen emission spectrum. Why is it...Ch. 11 - There am an infinite number of allowed transitions...Ch. 11 - You have learned that each orbital is allowed two...Ch. 11 - Atom A has valence electrons that are lower in...Ch. 11 - Prob. 21ALQCh. 11 - Prob. 1QAPCh. 11 - hat questions were left unanswered by Rutherford’s...Ch. 11 - Prob. 3QAPCh. 11 - Prob. 4QAPCh. 11 - Prob. 5QAPCh. 11 - Prob. 6QAPCh. 11 - he “Chemistry in Focus" segment Light as a Sex...Ch. 11 - Prob. 8QAPCh. 11 - hen lithium salts are heated in a flame, they emit...Ch. 11 - The energy of a photon of visible light emitted by...Ch. 11 - Prob. 11QAPCh. 11 - When an atom in an excited state returns to its...Ch. 11 - How is the energy carried per photon of light...Ch. 11 - When an atom energy from outside, the atom goes...Ch. 11 - Describe briefly why the study of electromagnetic...Ch. 11 - What does it mean to say that the hydrogen atom...Ch. 11 - Because a given element’s atoms emit only certain...Ch. 11 - How does the energy possessed by an emitted photon...Ch. 11 - Prob. 19QAPCh. 11 - When a tube containing hydrogen atoms is energized...Ch. 11 - What are the essential points of Bohr‘s theory of...Ch. 11 - According to Bohr, what happens to the electron...Ch. 11 - How does the Bohr theory account for the observed...Ch. 11 - Why was Bohr's theory for the hydrogen atom...Ch. 11 - What major assumption (that was analogous to what...Ch. 11 - Discuss briefly the difference between an orbit...Ch. 11 - Why was Schrodinger not able to describe exactly...Ch. 11 - Section 11.6 uses a "firefly" analogy to...Ch. 11 - Your text describes the probability map for an s...Ch. 11 - Consider the following representation of a set of...Ch. 11 - What are the differences between the :math>2s...Ch. 11 - What overall shape do the 2p and 3p orbitals have?...Ch. 11 - Prob. 33QAPCh. 11 - When the electron in hydrogen is in the n=3...Ch. 11 - Although a hydrogen atom has only one electron,...Ch. 11 - Complete the following table. trong>Value of n...Ch. 11 - When describing the electrons in an orbital, we...Ch. 11 - Why can only two electrons occupy a particular...Ch. 11 - How does the energy of a principal energy level...Ch. 11 - The number of sublevels in a principal energy...Ch. 11 - According to the Pauli exclusion principle, a...Ch. 11 - Prob. 42QAPCh. 11 - Which of the following orbital designations...Ch. 11 - Prob. 44QAPCh. 11 - Which orbital is the first be filled in any atom?...Ch. 11 - When a hydrogen atom is in its ground state, in...Ch. 11 - Prob. 47QAPCh. 11 - How are the electron arrangements in a given group...Ch. 11 - Write the full electron configuration ( 1s22s2...Ch. 11 - To which element does each of the following...Ch. 11 - Write the full electron configuration...Ch. 11 - To which element does each of the following...Ch. 11 - Write the complete orbital diagram for each of the...Ch. 11 - Prob. 54QAPCh. 11 - Prob. 55QAPCh. 11 - Prob. 56QAPCh. 11 - Why do we believe that the valence electrons of...Ch. 11 - Would you expect the Valence electrons of rubidium...Ch. 11 - Using the symbol of the previous noble gas in...Ch. 11 - Prob. 60QAPCh. 11 - Prob. 61QAPCh. 11 - How many valence electrons does each of the...Ch. 11 - How many 3d electrons are found in each of the...Ch. 11 - Based on the elements’ locations on the periodic...Ch. 11 - For each of the following elements, indicate which...Ch. 11 - Write the valence-electron configuration of each...Ch. 11 - Prob. 67QAPCh. 11 - The “Chemistry in Focus" segment The Chemistry of...Ch. 11 - What are some of the physical properties that...Ch. 11 - Prob. 70QAPCh. 11 - Give some similarities than exist among the...Ch. 11 - Give some similarities that exist among the...Ch. 11 - Which of the following elements most easily gives...Ch. 11 - Which elements in a given period (horizontal row)...Ch. 11 - Where are the most nonmetallic elements located on...Ch. 11 - Why do the metallic elements of a given period...Ch. 11 - Prob. 77QAPCh. 11 - The “Chemistry in Focus" segment Fireworks...Ch. 11 - Prob. 79QAPCh. 11 - In each of the following sets of elements, which...Ch. 11 - Arrange the following sets of elements in order of...Ch. 11 - In each of the following sets of elements,...Ch. 11 - Consider the bright line spectrum of hydrogen...Ch. 11 - Prob. 84APCh. 11 - The portion of the electromagnetic spectrum...Ch. 11 - A beam of light can be thought of as consisting of...Ch. 11 - Prob. 87APCh. 11 - The Energy levels of hydrogen (and other atoms)...Ch. 11 - According to Bohr, the electron in the hydrogen...Ch. 11 - Prob. 90APCh. 11 - Electrons found in the outemost principal energy...Ch. 11 - Prob. 92APCh. 11 - Prob. 93APCh. 11 - Prob. 94APCh. 11 - Prob. 95APCh. 11 - Prob. 96APCh. 11 - Without referring to your textbook or a periodic...Ch. 11 - Prob. 98APCh. 11 - Prob. 99APCh. 11 - Prob. 100APCh. 11 - ight waves move through space at a speed of ters...Ch. 11 - Prob. 102APCh. 11 - ow does the attractive force that the nucleus...Ch. 11 - Prob. 104APCh. 11 - Prob. 105APCh. 11 - Prob. 106APCh. 11 - hy do we believe that the three electrons in the...Ch. 11 - Prob. 108APCh. 11 - Prob. 109APCh. 11 - Prob. 110APCh. 11 - Prob. 111APCh. 11 - Prob. 112APCh. 11 - Prob. 113APCh. 11 - Prob. 114APCh. 11 - Prob. 115APCh. 11 - Prob. 116APCh. 11 - n each of the following sets of elements, indicate...Ch. 11 - Prob. 118APCh. 11 - Determine the maximum number of electrons that can...Ch. 11 - hich of the following statements is(are) true? The...Ch. 11 - ive the electron configurations for the following...Ch. 11 - Prob. 122CPCh. 11 - Prob. 123CPCh. 11 - Prob. 124CPCh. 11 - Prob. 125CPCh. 11 - Prob. 126CP
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- When metallic sodium is dissolved in liquid sodium chloride, electrons are released into the liquid. These dissolved electrons absorb light with a wavelength near 800 nm. Suppose we treat the positive ions surrounding an electron crudely as defining a three-dimensional cubic box of edge L, and we assume that the absorbed light excites the electron from its ground state to the first excited state. Calculate the edge length L in this simple model.arrow_forwardSketch the major features (number of peaks and relative intensities for the peaks) of the expected photoelectron spectrum for atoms of nitrogen.arrow_forwardConstruct an energy level diagram showing all orbitals for the hydrogen atom up to n=5, labeling each orbital with its appropriate quantum numbers. How many different orbitals are in each shell?arrow_forward
- Tbe relative orbital levels for the hydrogen atom can be represented as Draw the relative orbital energy levels for atoms with more than one electron and explain your answer. Also explain bow the following radial probability distributions support your answer.arrow_forwardUntil recently, it was thought that Ca was unstable, and that the Ca atom therefore had a negative electron affinity. Some new experiments have now measured an electron affinity of +2.0kJmol1 for calcium. What is the longest wavelength of light that could remove an electron from Ca ? In which region of the electromagnetic spectrum does this light fall?arrow_forwardConsider the representations of the p and d atomic orbitals in Figs. 2-15 and 2- 17. What do the + and signs indicate?arrow_forward
- What does wave-particle duality mean? What are its implications in our modem view of atomic structure?arrow_forwardUse the mathematical expression for the 2pz wave function of a one-electron atom (see Table 5.2) to show that the probability of finding an electron in that orbital anywhere in the x-y plane is 0. What are the nodal planes for a dxz orbital and for a dx2y2 orbital?arrow_forward(a) The nitrogen atom has one electron in each of the 2px , 2py , and 2pz orbitals. By using the form of the angular wave functions, show that the total electron density, 2(2px)+2(2py)+2(2pz) , is spherically symmetric (that is, it is independent of the angles and ). The neon atom, which has two electrons in each 2p orbital, is also spherically symmetric. (b) The same result as in part (a) applies to d orbitals, thus a filled or half-filled subshell of d orbitals is spherically symmetric. Identify the spherically symmetric atoms or ions among the following: F , Na, Si, S2,Ar+ , Ni, Cu, Mo, Rh, Sb, W, Au.arrow_forward
- • identify an orbital (as 1s, 3p, etc.) from its quantum numbers, or vice versa.arrow_forwardOne bit of evidence that the quantum mechanical model is correct lies in the magnetic properties of matter. Atoms with unpaired electrons are attracted by magnetic fields and thus are said to exhibit pararamagnetism. The degree to which this effect is observed is directly related to the number of unpaired electrons present in the atom. Consider the ground-state electron configurations for Li, N, Ni, Te, Ba, and Hg. Which of these atoms would be expected to be paramagnetic, and how many unpaired electrons are present in each paramagnetic atom?arrow_forwardUse the aufbau procedure to obtain the electron configuration and orbital diagram for atoms of the following elements. (a) Be (b) B (c) Ne (d) Rbarrow_forward
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