Modern Physics
Modern Physics
3rd Edition
ISBN: 9781111794378
Author: Raymond A. Serway, Clement J. Moses, Curt A. Moyer
Publisher: Cengage Learning
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Chapter 11.2, Problem 1E

Compare the effective force constant for the CO molecule deduced here with that of an ordinary laboratory spring that stretches 0.5 m when a 1.0 kg mass is suspended from it.

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Find the amplitude of the ground-state vibrations of the CO molecule. What percentage of the bond length is this? Assume the molecule vibrates like a harmonic oscillator.
Find the number of vibrational degrees of freedom of a CO2 molecule,if the average kinetic energy of it is 4 kT.
The figure above shows the absorption spectrum of the molecule HBr. Following the basic procedures of Section 9.6, find:(a) the energy of the “missing” transition;(b) the effective force constant k;(c) the rotational spacing 2B. Estimate the value of the rotational spacing expected for HBr and compare with the value deduced  from the spectrum. Why are there only single lines and not double lines as in the case of HCl?
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