Chemistry: The Molecular Science
Chemistry: The Molecular Science
5th Edition
ISBN: 9781285199047
Author: John W. Moore, Conrad L. Stanitski
Publisher: Cengage Learning
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Chapter 11.6, Problem 11.10CE
Interpretation Introduction

Interpretation:

The given reaction occurs in single step or not has to be explained.

Concept Introduction:

The relationship between rate and initial concentration of reactant is described by rate law.  It is an experimentally determined equation and cannot be found out theoretically from the stoichiometry of the reactants and products.

  rate=k[concentrationofthereactant]m

Where, k is the rate constant and m is the order of the reaction.

If one or two species react directly to form products through a single step then it is called an elementary reaction or a single step reaction.  Multistep reaction involves the combination of two or more elementary steps.

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Chapter 11 Solutions

Chemistry: The Molecular Science

Ch. 11.3 - Prob. 11.6PSPCh. 11.3 - Prob. 11.7PSPCh. 11.4 - Prob. 11.6ECh. 11.4 - Prob. 11.7CECh. 11.4 - Prob. 11.8PSPCh. 11.4 - Prob. 11.8CECh. 11.5 - Prob. 11.9PSPCh. 11.5 - The frequency factor A is 6.31 108 L mol1 s1 and...Ch. 11.6 - Prob. 11.10CECh. 11.7 - Prob. 11.11ECh. 11.7 - The Raschig reaction produces the industrially...Ch. 11.7 - Prob. 11.12ECh. 11.8 - The oxidation of thallium(I) ion by cerium(IV) ion...Ch. 11.9 - Prob. 11.11PSPCh. 11.9 - Prob. 11.14CECh. 11 - An excellent way to make highly pure nickel metal...Ch. 11 - Prob. 1QRTCh. 11 - Prob. 2QRTCh. 11 - Prob. 3QRTCh. 11 - Prob. 4QRTCh. 11 - Prob. 5QRTCh. 11 - Prob. 6QRTCh. 11 - Prob. 7QRTCh. 11 - Prob. 8QRTCh. 11 - Prob. 9QRTCh. 11 - Prob. 10QRTCh. 11 - Prob. 11QRTCh. 11 - Cyclobutane can decompose to form ethylene: The...Ch. 11 - Prob. 13QRTCh. 11 - Prob. 14QRTCh. 11 - For the reaction 2NO2(g)2NO(g)+O2(g) make...Ch. 11 - Prob. 16QRTCh. 11 - Prob. 17QRTCh. 11 - Ammonia is produced by the reaction between...Ch. 11 - Prob. 19QRTCh. 11 - Prob. 20QRTCh. 11 - The reaction of CO(g) + NO2(g) is second-order in...Ch. 11 - Nitrosyl bromide, NOBr, is formed from NO and Br2....Ch. 11 - Prob. 23QRTCh. 11 - Prob. 24QRTCh. 11 - Prob. 25QRTCh. 11 - For the reaction these data were obtained at 1100...Ch. 11 - Prob. 27QRTCh. 11 - Prob. 28QRTCh. 11 - Prob. 29QRTCh. 11 - Prob. 30QRTCh. 11 - Prob. 31QRTCh. 11 - Prob. 32QRTCh. 11 - For the reaction of phenyl acetate with water the...Ch. 11 - When phenacyl bromide and pyridine are both...Ch. 11 - The compound p-methoxybenzonitrile N-oxide, which...Ch. 11 - Prob. 36QRTCh. 11 - Radioactive gold-198 is used in the diagnosis of...Ch. 11 - Prob. 38QRTCh. 11 - Prob. 39QRTCh. 11 - Prob. 40QRTCh. 11 - Prob. 41QRTCh. 11 - Prob. 42QRTCh. 11 - Prob. 43QRTCh. 11 - Prob. 44QRTCh. 11 - Prob. 45QRTCh. 11 - Prob. 46QRTCh. 11 - Prob. 47QRTCh. 11 - Prob. 48QRTCh. 11 - Prob. 49QRTCh. 11 - Prob. 50QRTCh. 11 - Prob. 51QRTCh. 11 - Prob. 52QRTCh. 11 - For the reaction of iodine atoms with hydrogen...Ch. 11 - Prob. 54QRTCh. 11 - The activation energy Ea is 139.7 kJ mol1 for the...Ch. 11 - Prob. 56QRTCh. 11 - Prob. 57QRTCh. 11 - Prob. 58QRTCh. 11 - Prob. 59QRTCh. 11 - Prob. 60QRTCh. 11 - Prob. 61QRTCh. 11 - Prob. 62QRTCh. 11 - Prob. 63QRTCh. 11 - Which of the reactions in Question 62 would (a)...Ch. 11 - Prob. 65QRTCh. 11 - Prob. 66QRTCh. 11 - Prob. 67QRTCh. 11 - Prob. 68QRTCh. 11 - Prob. 69QRTCh. 11 - Prob. 70QRTCh. 11 - Prob. 71QRTCh. 11 - For the reaction the rate law is Rate=k[(CH3)3CBr]...Ch. 11 - Prob. 73QRTCh. 11 - Prob. 74QRTCh. 11 - Prob. 75QRTCh. 11 - For this reaction mechanism, write the chemical...Ch. 11 - Prob. 77QRTCh. 11 - Prob. 78QRTCh. 11 - Prob. 79QRTCh. 11 - When enzymes are present at very low...Ch. 11 - Prob. 81QRTCh. 11 - The reaction is catalyzed by the enzyme succinate...Ch. 11 - Prob. 83QRTCh. 11 - Many biochemical reactions are catalyzed by acids....Ch. 11 - Prob. 85QRTCh. 11 - Prob. 86QRTCh. 11 - Prob. 87QRTCh. 11 - Prob. 88QRTCh. 11 - Prob. 89QRTCh. 11 - Prob. 90QRTCh. 11 - Prob. 91QRTCh. 11 - Prob. 92QRTCh. 11 - Prob. 93QRTCh. 11 - Prob. 94QRTCh. 11 - Nitryl fluoride is an explosive compound that can...Ch. 11 - Prob. 96QRTCh. 11 - Prob. 97QRTCh. 11 - For a reaction involving the decomposition of a...Ch. 11 - Prob. 99QRTCh. 11 - Prob. 100QRTCh. 11 - Prob. 101QRTCh. 11 - This graph shows the change in concentration as a...Ch. 11 - Prob. 103QRTCh. 11 - Prob. 104QRTCh. 11 - Prob. 105QRTCh. 11 - Prob. 106QRTCh. 11 - Prob. 107QRTCh. 11 - Prob. 108QRTCh. 11 - Prob. 109QRTCh. 11 - Prob. 110QRTCh. 11 - Prob. 111QRTCh. 11 - Prob. 112QRTCh. 11 - Prob. 113QRTCh. 11 - Prob. 114QRTCh. 11 - Prob. 115QRTCh. 11 - Prob. 116QRTCh. 11 - Prob. 118QRTCh. 11 - Prob. 119QRTCh. 11 - In a time-resolved picosecond spectroscopy...Ch. 11 - If you know some calculus, derive the integrated...Ch. 11 - If you know some calculus, derive the integrated...Ch. 11 - (Section 11-5) A rule of thumb is that for a...Ch. 11 - Prob. 11.BCPCh. 11 - Prob. 11.CCPCh. 11 - Prob. 11.DCP
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  • At 500 K in the presence of a copper surface, ethanol decomposes according to the equation C2H5OH(g)CH3CHO(g)+H2(g) The pressure of C2H5OH was measured as a function of time and the following data were obtained: Time(s) PC2H5OH(torr) 0 250. 100. 237 200. 224 300. 211 400. 198 500. 185 Since the pressure of a gas is directly proportional to the concentration of gas, we can express the rate law for a gaseous reaction in terms of partial pressures. Using the above data, deduce the rate law, the integrated rate law, and the value of the rate constant, all in terms of pressure units in atm and time in seconds. Predict the pressure of C2H5OH after 900. s from the start of the reaction. (Hint: To determine the order of the reaction with respect to C2H5OH, compare how the pressure of C2H5OH decreases with each time listing.)
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