Chemistry for Engineering Students
4th Edition
ISBN: 9781337398909
Author: Lawrence S. Brown, Tom Holme
Publisher: Cengage Learning
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Textbook Question
Chapter 12, Problem 12.105PAE
12.105 Using the kinetic-molecular theory, explain why an increase in pressure produces more
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In the gas phase, nitrogen dioxide is actually a mixture of nitrogen dioxide (NO2) and dinitrogen tetroxide (N2O4). If the density of such a mixture is 3.06 g/L at 74°C and 1.70 atm,calculate the partial pressures of the gases and KP for the dissociation of N2O4.
Pressure of NO2: ?atm Pressure of N2O4: ?atm KP=?
H2(g) + I2(g) ⇄ 2 HI(g) Kp = 69 at 340 K50.0 g of HI is injected into an evacuated 5.00-L rigid cylinder at 340 K. What is the total pressure inside the cylinder when the system comes to equilibrium?
Which of the following equilibria would be affected by volume changes at constant temperature?
2NO(g) + 3F2(g) ⇌ 2F3NO(g)
BF3(g) + NH3(g) ⇌ H3NBF3(s)
O3(g) + NO(g) ⇌ NO2(g) + O2(g
Chapter 12 Solutions
Chemistry for Engineering Students
Ch. 12 - list chemical reactions important in the...Ch. 12 - Explain that equilibrium is dynamic, and that at...Ch. 12 - Prob. 3COCh. 12 - calculate equilibrium constants from experimental...Ch. 12 - Prob. 5COCh. 12 - calculate molar solubility from Kspor vice versa.Ch. 12 - Prob. 7COCh. 12 - Prob. 8COCh. 12 - calculate the new equilibrium composition of a...Ch. 12 - Explain the importance of both kinetic and...
Ch. 12 - Identify the first chemical step in the production...Ch. 12 - Explain why the hydration process for concrete is...Ch. 12 - Prob. 12.3PAECh. 12 - 12.4 In what geographical region of the country...Ch. 12 - Prob. 12.5PAECh. 12 - Prob. 12.6PAECh. 12 - Prob. 12.7PAECh. 12 - On your desk is a glass half-filled with water and...Ch. 12 - An equilibrium involving the carbonate and...Ch. 12 - A small quantity of a soluble salt is placed in...Ch. 12 - Prob. 12.11PAECh. 12 - Prob. 12.12PAECh. 12 - Write equilibrium (mass action) expressions for...Ch. 12 - What is the difference between homogeneous...Ch. 12 - Write equilibrium expressions for each of the...Ch. 12 - Write equilibrium expressions for each of the...Ch. 12 - 12.17 Which of the following is more likely to...Ch. 12 - The reaction, 3 H2(g) + N2(g) (g), has the fol...Ch. 12 - 12.19 For each of the following equations, write...Ch. 12 - Consider the following equilibria involving SO2(g)...Ch. 12 - Prob. 12.21PAECh. 12 - Prob. 12.22PAECh. 12 - Prob. 12.23PAECh. 12 - Prob. 12.24PAECh. 12 - Prob. 12.25PAECh. 12 - The following data were collected for the...Ch. 12 - The following data were collected for a system at...Ch. 12 - Prob. 12.28PAECh. 12 - Nitrosyl chloride, NOCI, decomposes to NO and Cl,...Ch. 12 - Hydrogen gas and iodine gas react via the...Ch. 12 - 12.31 A system consisting of 0.100 mole of oxygen...Ch. 12 - Prob. 12.32PAECh. 12 - Prob. 12.33PAECh. 12 - 1’he reaction in Exercise 12.33 was repeated. This...Ch. 12 - In the reaction in Exercise 12.33, another trial...Ch. 12 - The experiment in Exercise 12.33 was redesigned so...Ch. 12 - Again the experiment in Exercise 12.33 was...Ch. 12 - At a particular temperature, the equilibrium...Ch. 12 - A student is simulating the carbonic acid—hydrogen...Ch. 12 - Because carbonic acid undergoes a second...Ch. 12 - Because calcium carbonate is a sink for CO32- in a...Ch. 12 - 12.42 The following reaction is in equilibrium in...Ch. 12 - Prob. 12.43PAECh. 12 - Prob. 12.44PAECh. 12 - The following equilibrium is established in a...Ch. 12 - Write the K_, expression for each of the following...Ch. 12 - Prob. 12.47PAECh. 12 - calculate the molar solubility of the following...Ch. 12 - 12.49 The Safe Drinking Water Act of 1974...Ch. 12 - In Exercise 12.49, what is the allowed...Ch. 12 - Prob. 12.51PAECh. 12 - Because barium sulfate is opaque to X-rays, it is...Ch. 12 - The ore cinnabar (HgS) is an important source of...Ch. 12 - Prob. 12.54PAECh. 12 - From the solubility data given for the following...Ch. 12 - The solubility of magnesium fluoride, MgF2, in...Ch. 12 - Solid Na2SO4 is added slowly to a solution that is...Ch. 12 - Will a precipitate of Mg(OH)2 form when 25.0 mL of...Ch. 12 - Use the web to look up boiler scale and explain...Ch. 12 - Prob. 12.60PAECh. 12 - Prob. 12.61PAECh. 12 - 12.62 Write the formula of the conjugate acid of...Ch. 12 - 12.63 For each of the following reactions,...Ch. 12 - What are the products of each of the following...Ch. 12 - Prob. 12.65PAECh. 12 - Prob. 12.66PAECh. 12 - 12.67 Hydrofluoric acid is a weak acid used in the...Ch. 12 - The pH of a 0.129 M solution of a weak acid, HB,...Ch. 12 - Calculate the pH of a 0.10 M solution of propanoic...Ch. 12 - Find the pH of a 0.115 M solution of NH3(aq).Ch. 12 - Acrylic acid is used in the polymer industry in...Ch. 12 - Prob. 12.72PAECh. 12 - Prob. 12.73PAECh. 12 - Prob. 12.74PAECh. 12 - Cyanic acid (HOCN) is a weak acid with AL, = 3.5 X...Ch. 12 - In a particular experiment, the equilibrium...Ch. 12 - Prob. 12.77PAECh. 12 - Prob. 12.78PAECh. 12 - Prob. 12.79PAECh. 12 - Prob. 12.80PAECh. 12 - Prob. 12.81PAECh. 12 - Prob. 12.82PAECh. 12 - Prob. 12.83PAECh. 12 - Prob. 12.84PAECh. 12 - 12.85 In the figure, orange fish are placed in one...Ch. 12 - For the system in the preceding problem, show the...Ch. 12 - Prob. 12.87PAECh. 12 - Which of the following is more likely to...Ch. 12 - Prob. 12.89PAECh. 12 - Prob. 12.90PAECh. 12 - In the following equilibrium in a closed system,...Ch. 12 - Consider the following system:...Ch. 12 - The decomposition of NH4HS , NH4HS(s)NH3(g)+H2S(g)...Ch. 12 - You are designing a process to remove carbonate...Ch. 12 - Equal amounts of two gases, A and B3, are placed...Ch. 12 - Prob. 12.96PAECh. 12 - Prob. 12.97PAECh. 12 - Prob. 12.98PAECh. 12 - Solid CaCO3 ; is placed in a closed container and...Ch. 12 - 12.100 A reaction important in smog formation is...Ch. 12 - 12.101 An engineer working on a design to extract...Ch. 12 - 12.102 A chemical engineer is working to optimize...Ch. 12 - 12.103 Methanol, CH3OH, can be produced by the...Ch. 12 - Prob. 12.104PAECh. 12 - 12.105 Using the kinetic-molecular theory, explain...Ch. 12 - 12.106 The solubility of KCl is 34.7 g per 100 g...Ch. 12 - Prob. 12.107PAECh. 12 - 12.108 A nuclear engineer is considering the...Ch. 12 - 12.109 Copper(II) iodate has a solubility of 0.136...Ch. 12 - 12.110 In Exercise 12.109, what do you predict...Ch. 12 - 12.111 You have three white solids. What...Ch. 12 - Prob. 12.112PAECh. 12 - Prob. 12.113PAECh. 12 - Prob. 12.114PAECh. 12 - Prob. 12.115PAECh. 12 - Prob. 12.116PAECh. 12 - 12.117 The vapor pressure of water at 80.0 °C is...Ch. 12 - Prob. 12.118PAE
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- The following reaction can be used to make H2 for the synthesis of ammonia from the greenhouse gases carbon dioxide and methane: CH4 (g) + CO2 (g) ⇌ 2 CO (g) + 2 H2 (g) At 1200. K, Kp = 3.548 × 106. What is the partial pressure of CH4 at equilibrium when 10.00 atm of CH4 reacts with 15.00 atm of CO2 at 1200. K?arrow_forwardAre the chlorine atoms in equivalent environments in each of the compounds [Co(NH3)4Cl2] and [Co(NH3)3Cl3]?arrow_forwardConsider the following reaction and its value of ΔH°: N2O (g) + NO2 (g) ⇋⇋ 3 NO (g) ΔH° = 155.6 kJ How will the partial pressure of NO2 change if the volume of the system is increased? Select one: a. The partial pressure of NO2 will increase. b. The partial pressure of NO2 will decrease. c. The partial pressure of NO2 will not be affected.arrow_forward
- For the reaction PCl3(g) + Cl2(g) PCl5(g) at a particular temperature, Kc = 32.4. Suppose a system at that temperature is prepared with [PCl5] = 2.5 M, [Cl2] = 0.3 M, and [PCl3] = 0.05 M. Which of the following is correct? The reaction will go to the right and form more PCl3 The reaction will go to the right and form more PCl5 The reaction will go to the left and form more PCl3 The reaction will go to the left and form more PCl5 The system is at equilibriumarrow_forwardNitric acid is produced commercially by the Ostwald process. The first step of the Ostwald process is: 4 NH3(g) + 5 O2(g) ⇌ 4 NO(g) + 6 H2O(g) + energy In which direction will the above system shift in the following situations: (a) Some NH3 is removed. (b)The pressure of the system is decreased by increasing the volume. (c)The temperature of the system is decreased.arrow_forwardMethane, ethyne and hydrogen form the following mixture at equilibrium. 2 CH4(g) ↔ C2H2(g) + 3 H2(g) To study this reaction mixture, a chemist analyzes a 4.0 L sealed flask at 1700°C. There are 0.46 mol of CH4(g), 0.64 mol of C2H2(g) and 0.93 mol of H2(g). What is the value of Kc for the reaction at 1700 oC?arrow_forward
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