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Introduction to General, Organic a...

11th Edition
Frederick A. Bettelheim + 4 others
Publisher: Cengage Learning
ISBN: 9781285869759
BuyFind

Introduction to General, Organic a...

11th Edition
Frederick A. Bettelheim + 4 others
Publisher: Cengage Learning
ISBN: 9781285869759

Solutions

Chapter
Section
Chapter 12, Problem 12.17P
Textbook Problem
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Draw a structural formula for at least one bromoalkene with the molecular formula C5H9Br that (a) shows cis/trans isomerism and (b) does not show cis /trans isomerism.

Expert Solution
Interpretation Introduction

Interpretation:

To draw a structural formula for at least one bromo-alkene with the molecular formula C5H9Br that show cis-trans isomerism.

Concept Introduction:

Isomers are the compounds that have same molecular formula but different structural formula.

Cis-trans isomerism arises in the compounds when there is a difference in the orientation of the two same groups.

When two same groups are along the same side of the C-C bond it is called as cis isomer, but when the same groups lie opposite to each other along the C-C bond. It is said to be trans isomer.

Example-

Introduction to General, Organic and Biochemistry, Chapter 12, Problem 12.17P , additional homework tip  1 and Introduction to General, Organic and Biochemistry, Chapter 12, Problem 12.17P , additional homework tip  2 are cis-trans isomers.

Explanation of Solution

The parent compound for C5H9Br is C5H10 that can have the skeleton as-

  1. It can not have cis-isomers with molecular formula C5H9Br -

Expert Solution
Interpretation Introduction

Interpretation:

To draw a structural formula for at least Bromo-alkene with the molecular formula C5H9Br that does not show cis-trans isomerism.

Concept Introduction:

Isomers are the compounds that have same molecular formula but different structural formula.

Cis-trans isomerism arises in the compounds when there is a difference in the orientation of the two same groups.

When two same groups are along the same side of the C-C bond it is called as cis isomer, but when the same groups lie opposite to each other along the C-C bond. It is said to be trans isomer.

Example-

Introduction to General, Organic and Biochemistry, Chapter 12, Problem 12.17P , additional homework tip  3 and Introduction to General, Organic and Biochemistry, Chapter 12, Problem 12.17P , additional homework tip  4 are cis-trans isomers.

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Chapter 12 Solutions

Introduction to General, Organic and Biochemistry
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Ch. 12 - Answer true or false. There are two classes of...Ch. 12 - Answer true or false. Both ethylene and acetylene...Ch. 12 - 12-13 What is the difference in structure between...Ch. 12 - There are three compounds with the molecular...Ch. 12 - 12-15 Name and draw structural formulas for all...Ch. 12 - Name and draw structural formulas for alkenes with...Ch. 12 - Draw a structural formula for at least one...Ch. 12 - Each carbon atom in ethane and in ethylene is...Ch. 12 - Prob. 12.19PCh. 12 - 12*20 Predict all bond angles about each...Ch. 12 - Answer true or false. The IUPAC name of an alkene...Ch. 12 - 12*22 Draw a structural formula for each compound....Ch. 12 - 12-23 Draw a structural formula for each compound....Ch. 12 - Prob. 12.24PCh. 12 - 12-25 Write the IUPAC name for each unsaturated...Ch. 12 - Explain why each name is incorrect and then write...Ch. 12 - 12-27 Explain why each name is incorrect and then...Ch. 12 - What structural feature in alkenes makes cis-trans...Ch. 12 - 12-29 Which of these alkenes show cis-trans...Ch. 12 - 12-30 Which of these alkenes shows cis-trans...Ch. 12 - 12-31 Cyclodecene exists as both cis and trans...Ch. 12 - Arachidonic acid is a naturally occurring C„o...Ch. 12 - Following is the structural formula of a naturally...Ch. 12 - If you examine the structural formulas for the...Ch. 12 - 12*35 For each molecule that shows eis-trans...Ch. 12 - Name and draw structural formulas for all...Ch. 12 - /3-Ocimene, a triene found in the fragrance of...Ch. 12 - Answer true or false. Alkenes and alkynes are...Ch. 12 - Answer true or false. Complete combustion of an...Ch. 12 - 12-40 Define alkene addition reaction. Write an...Ch. 12 - Prob. 12.41PCh. 12 - 12-42 Complete these equations.Ch. 12 - Draw structural formulas for all possible...Ch. 12 - 12-44 Draw a structural formula for the product...Ch. 12 - 12-45 Draw a structural formula for the product of...Ch. 12 - Draw a structural formula for an alkene with the...Ch. 12 - 12-47 Draw a structural formula for an alkene with...Ch. 12 - Draw a structural formula for an alkene with the...Ch. 12 - With the notable exception of ethanol, the acid-...Ch. 12 - 12-50 Draw the structural formula of an alkene...Ch. 12 - Acid-catalyzed hydration of 2-pentene gives a...Ch. 12 - Terpin, CloH20O2, is prepared commercially by the...Ch. 12 - Following is the structural formula of...Ch. 12 - Propose an explanation for the following...Ch. 12 - There are nine alkenes with the molecular formula...Ch. 12 - Prob. 12.56PCh. 12 - 12-57 Hydrocarbon A, Cf,Hs, reacts with 2 moles of...Ch. 12 - 12-58 Show how to convert ethylene to these...Ch. 12 - 12-59 Show how to convert 1-butene to these...Ch. 12 - Answer true or false. Ethylene contains one...Ch. 12 - 12-61 (Chemical Connections 12A) What is one...Ch. 12 - (Chemical Connections 12B) Linolenic acid is a...Ch. 12 - (Chemical Connections 12C) What is the meaning of...Ch. 12 - 12-64 (Chemical Connections 120 What is the...Ch. 12 - (Chemical Connections 120 Assume that 1 X IO-12 g...Ch. 12 - (Chemical Connections 12D) What different func...Ch. 12 - 12-67 (Chemical Connections 12D ) In which isomer...Ch. 12 - (Chemical Connections 12E» What types of consumer...Ch. 12 - 12-69 (Chemical Connections 12E) In recycling...Ch. 12 - Write line-angle formulas for all compounds with...Ch. 12 - Refer to the structure of lycopene at the bottom...Ch. 12 - Prob. 12.72PCh. 12 - Prob. 12.73PCh. 12 - Propose a structural formula for the product!s)...Ch. 12 - cis-3-Hexene and fra ns-3-hexene are different...Ch. 12 - Draw the structural formula of an alkene that...Ch. 12 - 12-77 Show how to convert cyclopentene into these...Ch. 12 - In Chapter 21 on the biochemistry of lipids, we...Ch. 12 - The fatty acids in Problem 12-78 occur in animal...Ch. 12 - In omega-3 fatty adds, the last carbon of the last...Ch. 12 - Prob. 12.81P

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