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ChemistryChemistry: An Atoms First Approach2nd Edition
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For which reactions in Exercise 34 is K p equal to K?

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Chemistry: An Atoms First Approach

2nd Edition
Steven S. Zumdahl + 1 other
Publisher: Cengage Learning
ISBN: 9781305079243

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BuyFindarrow_forward

Chemistry: An Atoms First Approach

2nd Edition
Steven S. Zumdahl + 1 other
Publisher: Cengage Learning
ISBN: 9781305079243
Chapter 12, Problem 36E
Textbook Problem
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For which reactions in Exercise 34 is Kp equal to K?

(a)

Interpretation Introduction

Interpretation: The reactions for which K is equal to Kp are to be identified.

Concept introduction: The state when the reactants involved in a chemical reaction and the products formed in the reaction exist in concentrations having no further tendency to change is known as an equilibrium state of the reaction. When the equilibrium constant is expressed in terms of concentration, it is represented K . When the equilibrium constant is expressed in terms of pressure, it is represented Kp . The relation between ‘ K ’ and ‘ Kp ’ is, Kp=K(RT)Δn .

To determine: If the given has reaction has K equal to Kp .

Explanation of Solution

Given

The stated reaction is,

2Fe(s)+32O2(g)⇌Fe2O3(s)

The relation between ‘ K ’ and ‘ Kp ’ is,

Kp=K(RT)Δn

Where,

  • R is the gas constant.
  • T is the temperature.
  • Δn is the change in the number of moles

The value of K is equal to Kp if the value of Δn is zero

(b)

Interpretation Introduction

Interpretation: The reactions for which K is equal to Kp are to be identified.

Concept introduction: The state when the reactants involved in a chemical reaction and the products formed in the reaction exist in concentrations having no further tendency to change is known as an equilibrium state of the reaction. When the equilibrium constant is expressed in terms of concentration, it is represented K . When the equilibrium constant is expressed in terms of pressure, it is represented Kp . The relation between ‘ K ’ and ‘ Kp ’ is, Kp=K(RT)Δn .

To determine: If the given has reaction has K equal to Kp .

(c)

Interpretation Introduction

Interpretation: The reactions for which K is equal to Kp are to be identified.

Concept introduction: The state when the reactants involved in a chemical reaction and the products formed in the reaction exist in concentrations having no further tendency to change is known as an equilibrium state of the reaction. When the equilibrium constant is expressed in terms of concentration, it is represented K . When the equilibrium constant is expressed in terms of pressure, it is represented Kp . The relation between ‘ K ’ and ‘ Kp ’ is, Kp=K(RT)Δn .

To determine: If the given has reaction has K equal to Kp .

(d)

Interpretation Introduction

Interpretation: The reactions for which K is equal to Kp are to be identified.

Concept introduction: The state when the reactants involved in a chemical reaction and the products formed in the reaction exist in concentrations having no further tendency to change is known as an equilibrium state of the reaction. When the equilibrium constant is expressed in terms of concentration, it is represented K . When the equilibrium constant is expressed in terms of pressure, it is represented Kp . The relation between ‘ K ’ and ‘ Kp ’ is, Kp=K(RT)Δn .

To determine: If the given has reaction has K equal to Kp .

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Ch. 12 - Characterize a system at chemical equilibrium with...Ch. 12 - What is the law of mass action? Is it true that...Ch. 12 - Consider the following reactions at some...Ch. 12 - What is the difference between K and Kp? When doc...Ch. 12 - What are homogeneous equilibria? Heterogeneous...Ch. 12 - Distinguish between the terms equilibrium constant...Ch. 12 - Summarize the steps for solving equilibrium...Ch. 12 - A common type of reaction we will study is that...Ch. 12 - What is Le Chteliers principle? Consider the...Ch. 12 - The only stress (change) that also changes the...
Ch. 12 - Consider an equilibrium mixture of four chemicals...Ch. 12 - The boxes shown below represent a set of initial...Ch. 12 - For the reactionH2(g)+I2(g)2HI(g), consider two...Ch. 12 - Given the reactionA(g)+B(g)C(g)+D(g), consider the...Ch. 12 - Consider the reaction A(g)+2B(g)C(g)+D(g) in a...Ch. 12 - Consider the reactionA(g)+B(g)C(g)+D(g). A friend...Ch. 12 - Consider the following statements: Consider the...Ch. 12 - Le Chteliers principle is stated (Section 12-7) as...Ch. 12 - The value of the equilibrium constant K depends on...Ch. 12 - Consider an initial mixture of N2 and H2 gases...Ch. 12 - Consider the following reaction:...Ch. 12 - Consider the same reaction as in Question 11. 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