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Chemistry & Chemical Reactivity

10th Edition
John C. Kotz + 3 others
ISBN: 9781337399074

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BuyFindarrow_forward

Chemistry & Chemical Reactivity

10th Edition
John C. Kotz + 3 others
ISBN: 9781337399074
Textbook Problem

One way of viewing the unit cell of perovskite was illustrated in Example 12.2. Another way is shown here. Prove that this view also leads to a formula of CaTiO3.

images

Perovskite unit cell

Interpretation Introduction

Interpretation:

From the view, the formula CaTiO3 has to be proved.

Explanation

The Ca2+ ion at eight corners therefore,

Number of Ca2+atoms per unit=(8corneratoms×1/8)Number of Ca2+atoms per unit=1

The O2- ion at six faces therefore,

Number of O2-atoms per unit=(6faceO2-

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