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ChemistryChemistry9th Edition

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Chapter 12, Problem 73AE
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Chemistry

9th Edition
Steven S. Zumdahl
ISBN: 9781133611097

Solutions

Chapter
Section
Problem 1RQ
Problem 2RQ
Problem 3RQ
Problem 4RQ
Problem 5RQ
Problem 6RQ
Problem 7RQ
Problem 8RQ
Problem 9RQ
Problem 10RQ
Problem 11RQ
Problem 1ALQ
Problem 2ALQ
Problem 3ALQ
Problem 4ALQ
Problem 5ALQ
Problem 6ALQ
Problem 7ALQ
Problem 8ALQ
Problem 9ALQ
Problem 10Q
Problem 11Q
Problem 12Q
Problem 13Q
Problem 14Q
Problem 15Q
Problem 16Q
Problem 17Q
Problem 18Q
Problem 19Q
Problem 20Q
Problem 21Q
Problem 22Q
Problem 23E
Problem 24E
Problem 25E
Problem 26E
Problem 27E
Problem 28E
Problem 29E
Problem 30E
Problem 31E
Problem 32E
Problem 33E
Problem 34E
Problem 35E
Problem 36E
Problem 37E
Problem 38E
Problem 39E
Problem 40E
Problem 41E
Problem 42E
Problem 43E
Problem 44E
Problem 45E
Problem 46E
Problem 47E
Problem 48E
Problem 49E
Problem 50E
Problem 51E
Problem 52E
Problem 53E
Problem 54E
Problem 55E
Problem 56E
Problem 57E
Problem 58E
Problem 59E
Problem 60E
Problem 61E
Problem 62E
Problem 63AE
Problem 64AE
Problem 65AE
Problem 66AE
Problem 67AE
Problem 68AE
Problem 69AE
Problem 70AE
Problem 71AE
Problem 72AE
Problem 73AE
Problem 74AE
Problem 75AE
Problem 76AE
Problem 77AE
Problem 78AE
Problem 79AE
Problem 80AE
Problem 81AE
Problem 82AE
Problem 83AE
Problem 84AE
Problem 85AE
Problem 86AE
Problem 87AE
Problem 88AE
Problem 89AE
Problem 90AE
Problem 91AE
Problem 92AE
Problem 93AE
Problem 94CWP
Problem 95CWP
Problem 96CWP
Problem 97CWP
Problem 98CWP
Problem 99CWP
Problem 100CWP
Problem 101CWP
Problem 102CP
Problem 103CP
Problem 104CP
Problem 105CP
Problem 106CP
Problem 107CP
Problem 108CP
Problem 109CP
Problem 110CP
Problem 111CP
Problem 112CP
Problem 113IP
Problem 114IP
Problem 115IP
Problem 116MP
BuyFindarrow_forward

Chemistry

9th Edition
Steven S. Zumdahl
ISBN: 9781133611097
Textbook Problem

Which of the following reactions would you expect to proceed at a faster rate at room temperature? Why? (Hint: Think about which reaction would have the lower activation energy.)

2 Ce 4 + ( a q )   +   Hg 2 2 + ( a q )   →   2 Ce 3 + ( a q )   +   2 Hg 2 + ( a q ) H 3 O + ( a q )   +   OH − ( a q )   →   2 H 2 O ( l )

Interpretation Introduction

Interpretation: Two reactions are given. The reaction that proceeds at faster rate is to be identified. The answer is to be justified.

Concept introduction: The energy difference between activated complex and reactants is known as activation energy. The relationship between the rate of reaction and activation energy is given by the Arrhenius equation,

k=Ae−EaRT

To determine: The reaction that proceeds at faster rate from the given two reactions with proper reason.

Explanation

The minimum energy needed to start the reaction is known as activation energy.

The relationship between the rate of reaction andactivation energy is given by the Arrhenius equation.

k=Ae−EaRT

Where,

  • k is the rate constant.
  • A is the Arrhenius parameter.
  • Ea is the activation energy.
  • R is the universal gas constant.
  • T is the absolute temperature.

It is clear from the above equation that, rate of reaction is inversely proportional to activation energy at constant temperature. Higher the value of activation energy, slower will be the rate of reaction.

The following are the conditions required to make the product from reactant,

  • If this activation energy is less than or equal to that of kinetic energy of molecules upon collision, then breaking of bonds takes place and new product is formed.
  • If the relative orientation of reactants favors the formation of any new bond, then new product is formed.

The reaction of ions with similar charge has higher activation energy because it has the repulsive interaction.

Similarly,the reaction of ions with opposite charge has lower activation energy because it has the electrostatic interaction

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Ch-12 P-1RQCh-12 P-2RQCh-12 P-3RQCh-12 P-4RQCh-12 P-5RQCh-12 P-6RQCh-12 P-7RQCh-12 P-8RQCh-12 P-9RQCh-12 P-10RQ
Ch-12 P-11RQCh-12 P-1ALQCh-12 P-2ALQCh-12 P-3ALQCh-12 P-4ALQCh-12 P-5ALQCh-12 P-6ALQCh-12 P-7ALQCh-12 P-8ALQCh-12 P-9ALQCh-12 P-10QCh-12 P-11QCh-12 P-12QCh-12 P-13QCh-12 P-14QCh-12 P-15QCh-12 P-16QCh-12 P-17QCh-12 P-18QCh-12 P-19QCh-12 P-20QCh-12 P-21QCh-12 P-22QCh-12 P-23ECh-12 P-24ECh-12 P-25ECh-12 P-26ECh-12 P-27ECh-12 P-28ECh-12 P-29ECh-12 P-30ECh-12 P-31ECh-12 P-32ECh-12 P-33ECh-12 P-34ECh-12 P-35ECh-12 P-36ECh-12 P-37ECh-12 P-38ECh-12 P-39ECh-12 P-40ECh-12 P-41ECh-12 P-42ECh-12 P-43ECh-12 P-44ECh-12 P-45ECh-12 P-46ECh-12 P-47ECh-12 P-48ECh-12 P-49ECh-12 P-50ECh-12 P-51ECh-12 P-52ECh-12 P-53ECh-12 P-54ECh-12 P-55ECh-12 P-56ECh-12 P-57ECh-12 P-58ECh-12 P-59ECh-12 P-60ECh-12 P-61ECh-12 P-62ECh-12 P-63AECh-12 P-64AECh-12 P-65AECh-12 P-66AECh-12 P-67AECh-12 P-68AECh-12 P-69AECh-12 P-70AECh-12 P-71AECh-12 P-72AECh-12 P-73AECh-12 P-74AECh-12 P-75AECh-12 P-76AECh-12 P-77AECh-12 P-78AECh-12 P-79AECh-12 P-80AECh-12 P-81AECh-12 P-82AECh-12 P-83AECh-12 P-84AECh-12 P-85AECh-12 P-86AECh-12 P-87AECh-12 P-88AECh-12 P-89AECh-12 P-90AECh-12 P-91AECh-12 P-92AECh-12 P-93AECh-12 P-94CWPCh-12 P-95CWPCh-12 P-96CWPCh-12 P-97CWPCh-12 P-98CWPCh-12 P-99CWPCh-12 P-100CWPCh-12 P-101CWPCh-12 P-102CPCh-12 P-103CPCh-12 P-104CPCh-12 P-105CPCh-12 P-106CPCh-12 P-107CPCh-12 P-108CPCh-12 P-109CPCh-12 P-110CPCh-12 P-111CPCh-12 P-112CPCh-12 P-113IPCh-12 P-114IPCh-12 P-115IPCh-12 P-116MP

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