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ChemistryIntroductory Chemistry: A Foundation9th Edition

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Chapter 12, Problem 87QAP
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Introductory Chemistry: A Foundati...

9th Edition
Steven S. Zumdahl + 1 other
ISBN: 9781337399425

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Introductory Chemistry: A Foundati...

9th Edition
Steven S. Zumdahl + 1 other
ISBN: 9781337399425
Textbook Problem
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The “Chemistry in Focus" segment Taste—It's the Structure That Counts discusses artificial sweeteners. What are the expected bond angles around the nitrogen atom in aspartame?

Interpretation Introduction

Interpretation:

The expected bond angle around the nitrogen atom that is present in aspartame is to be stated.

Concept Introduction:

VSEPR theory is an important model that is frequently used in chemistry to decide the shape and geometry of the molecules. VSEPR model is the extension of Lewis model. As the Lewis model is not able to explain the shape of the molecules. In terms of electron density it is given that both the bonding electrons as well as lone pair of electrons holds the shape of the molecule.

The shape in VSEPR model gives specific angles between the bonds for the corresponding shape and these angles are known as bond angles.

Explanation

The structure of aspartame is shown as,

Figure 1

The structure of aspartame consists of sp3 hybridized carbon that contains four single bonds. Thus, the shape of carbon attached with four atoms in the structure of aspartame is tetrahedral.

The expected bond angle around the nitrogen atom that is present in aspartame is shown as,

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Sect-12.2 P-1CTSect-12.2 P-12.1SCSect-12.5 P-1CTSect-12.6 P-12.2SCSect-12.7 P-12.3SCSect-12.7 P-12.4SCSect-12.9 P-1CTSect-12.9 P-12.5SCCh-12 P-1ALQCh-12 P-2ALQ
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