EBK ORGANIC CHEMISTRY AS A SECOND LANGU
4th Edition
ISBN: 9781119234715
Author: Klein
Publisher: VST
expand_more
expand_more
format_list_bulleted
Concept explainers
Question
Chapter 12.6, Problem 16PTS
Interpretation Introduction
Interpretation: The compounds that can be formed by a reaction between Grignard reagent and ester are to be determined.
Concept Introduction: When the alcoholic group is attached to three alkyl groups, it is known as tertiary alcohol. Esters react with two equivalents of Grignard reagent to form tertiary alcohols. Therefore, the alcohols that are bonded to two similar alkyl groups are formed by the reaction of ester and Grignard reagent.
Expert Solution & Answer
Want to see the full answer?
Check out a sample textbook solutionStudents have asked these similar questions
Hydrolysis of an acetal in aqueous acid gives an aldehyde or a ketone and two molecules of alcohol or one molecule of a diol. Draw the structural formulas for the products of hydrolysis of the following acetals in aqueous acid.
Why can’t 2-methyl-2-propanol be prepared by the reduction of a carbonyl compound?
Explain Structure and Bonding of Alcohols, ethers, and epoxides ?
Chapter 12 Solutions
EBK ORGANIC CHEMISTRY AS A SECOND LANGU
Ch. 12.1 - Prob. 1LTSCh. 12.1 - Prob. 1PTSCh. 12.1 - Prob. 2ATSCh. 12.1 - Prob. 3CCCh. 12.2 - Prob. 4CCCh. 12.3 - Prob. 8CCCh. 12.3 - Prob. 9CCCh. 12.4 - Prob. 3LTSCh. 12.4 - Prob. 10PTSCh. 12.4 - Prob. 11ATS
Ch. 12.4 - Prob. 4LTSCh. 12.4 - Prob. 12PTSCh. 12.4 - Prob. 13ATSCh. 12.6 - Prob. 14CCCh. 12.6 - Prob. 5LTSCh. 12.6 - Prob. 15PTSCh. 12.6 - Prob. 16PTSCh. 12.7 - Prob. 18CCCh. 12.9 - Prob. 6LTSCh. 12.9 - Prob. 19PTSCh. 12.9 - Prob. 20ATSCh. 12.9 - Prob. 21CCCh. 12.10 - Prob. 7LTSCh. 12.10 - Prob. 22PTSCh. 12.10 - Prob. 23ATSCh. 12.13 - Prob. 8LTSCh. 12.13 - Prob. 24PTSCh. 12.13 - Prob. 25ATSCh. 12.13 - Prob. 26CCCh. 12.13 - Prob. 9LTSCh. 12.13 - Prob. 27PTSCh. 12.13 - Prob. 28ATSCh. 12 - Prob. 29PPCh. 12 - Prob. 30PPCh. 12 - Prob. 31PPCh. 12 - Prob. 32PPCh. 12 - Prob. 33PPCh. 12 - Prob. 34PPCh. 12 - Prob. 35PPCh. 12 - Prob. 36PPCh. 12 - Prob. 37PPCh. 12 - Prob. 38PPCh. 12 - Prob. 39PPCh. 12 - Prob. 40PPCh. 12 - Prob. 41PPCh. 12 - Prob. 42PPCh. 12 - Prob. 43PPCh. 12 - Prob. 44PPCh. 12 - Prob. 45PPCh. 12 - Prob. 46PPCh. 12 - Prob. 47PPCh. 12 - Prob. 48PPCh. 12 - Prob. 49PPCh. 12 - Prob. 50PPCh. 12 - Prob. 51PPCh. 12 - Prob. 52PPCh. 12 - Prob. 53ASPCh. 12 - Prob. 54ASPCh. 12 - Prob. 55ASPCh. 12 - Prob. 62IPCh. 12 - Prob. 64IPCh. 12 - Prob. 65IPCh. 12 - Prob. 66IPCh. 12 - Prob. 67IPCh. 12 - Prob. 68IPCh. 12 - Prob. 69IPCh. 12 - Prob. 74IP
Knowledge Booster
Learn more about
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.Similar questions
- List the following compounds in order of increasing water solubility: a.ethoxyethane b.propanoic acid c.pentane d.1 butanolarrow_forwardBased on the characteristics of the carbonyl group (C = O), what reactions or transformations take place with aldehydes and ketones? a. nucleophilic additions by oxygenb. electrophilic additions by carbon attackc. nucleophilic additions by carbon attackd. electrophilic substitutions through a carbocationand. acid-base because carbonyl can act as both an electrophile and a nucleophilearrow_forwardWhat is the characteristic reaction of carboxylic acid derivatives? oxidation electrophilic addition nucleophilic elimination nucleophilic acyl substitutionarrow_forward
- draw the structure of ester produced from a reaction of butan-2-ol with 3-bromopropanoic acidarrow_forwardWhat is the oxidation product of this compound? propanone ethanoic acid acetic acid propanoic acidarrow_forwardDraw the structure of the principal organic product formed from the reaction of benzyl bromide with sodium thiomethoxide.arrow_forward
- 22. What kind of compound is made when an aldehyde is treated with a Grignard reagent? Carboxylic acid Primary alcohol Secondary alcohol Tertiary alcoholarrow_forwardDescribe the acidity of different carboxylic acids and predict the products obtained when they react with strong bases.arrow_forwardWrite equations for the following reactions. Give specific examples instead of the general equation. Formation of esters from ether Formation of oxonium salts from ether How ethers are broken down by zinc chloridearrow_forward
- The flavors and aromas of almost any fruit are primarily due to esters. In an experiment, an artificial fruit flavor is prepared using the Fischer esterification (reaction of an alcohol with a carboxylic acid in the presence of sulfuric acid catalyst). Why is it easier to remove excess carboxylic acid from the product than excess alcohol?arrow_forwardThe presence of what product of the autooxidation of ethers makes the distillation of ethers dangerous?arrow_forwardThe following alcohol can be formed via two different Grignard reactions. Draw the GRIGNARD REAGENT which contains a BENZENE ring. Use the covalent format R-Mg-Br instead of the ionic format. Then draw the carbonyl compound Draw the GRIGNARD REAGENT. Use the covalent format R-Mg-Br instead of the ionic format. Then draw the carbonyl compound with a benzene ringarrow_forward
arrow_back_ios
SEE MORE QUESTIONS
arrow_forward_ios
Recommended textbooks for you
- Chemistry for Today: General, Organic, and Bioche...ChemistryISBN:9781305960060Author:Spencer L. Seager, Michael R. Slabaugh, Maren S. HansenPublisher:Cengage LearningChemistry: The Molecular ScienceChemistryISBN:9781285199047Author:John W. Moore, Conrad L. StanitskiPublisher:Cengage LearningOrganic ChemistryChemistryISBN:9781305580350Author:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. FootePublisher:Cengage Learning
- Organic And Biological ChemistryChemistryISBN:9781305081079Author:STOKER, H. Stephen (howard Stephen)Publisher:Cengage Learning,General, Organic, and Biological ChemistryChemistryISBN:9781285853918Author:H. Stephen StokerPublisher:Cengage Learning
Chemistry for Today: General, Organic, and Bioche...
Chemistry
ISBN:9781305960060
Author:Spencer L. Seager, Michael R. Slabaugh, Maren S. Hansen
Publisher:Cengage Learning
Chemistry: The Molecular Science
Chemistry
ISBN:9781285199047
Author:John W. Moore, Conrad L. Stanitski
Publisher:Cengage Learning
Organic Chemistry
Chemistry
ISBN:9781305580350
Author:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote
Publisher:Cengage Learning
Organic And Biological Chemistry
Chemistry
ISBN:9781305081079
Author:STOKER, H. Stephen (howard Stephen)
Publisher:Cengage Learning,
General, Organic, and Biological Chemistry
Chemistry
ISBN:9781285853918
Author:H. Stephen Stoker
Publisher:Cengage Learning
Alcohols, Ethers, and Epoxides: Crash Course Organic Chemistry #24; Author: Crash Course;https://www.youtube.com/watch?v=j04zMFwDeDU;License: Standard YouTube License, CC-BY