Introduction to General, Organic and Biochemistry
11th Edition
ISBN: 9781285869759
Author: Frederick A. Bettelheim, William H. Brown, Mary K. Campbell, Shawn O. Farrell, Omar Torres
Publisher: Cengage Learning
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Textbook Question
Chapter 13, Problem 13.17P
13-17 Following is the structural formula of styrene, the monomer from which the
/=Vch=ch2
Polystyrene
Styrene
Draw a section of a polystyrene chain showing at least three monomer units.
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Introduction to General, Organic and Biochemistry
Ch. 13.2 - Prob. 13.1PCh. 13 - Answer true or false. Alkenes, alkynes, and arenes...Ch. 13 - 13-3 What is the difference in structure between a...Ch. 13 - 13-4 Define aromatic compound.Ch. 13 - 13-5 Why are alkenes, alkynes, and aromatic...Ch. 13 - 13-B Do aromatic rings have double bonds? Are they...Ch. 13 - 13-7 Can an aromatic compound be a saturated...Ch. 13 - Draw at least two structural formulas for each of...Ch. 13 - 13-9 Write a structural formula and the name for...Ch. 13 - 13-10 Account for the fact that the six-membered...
Ch. 13 - 13-11 Explain why the compound 1,4-dichlorobenzene...Ch. 13 - 13-12 One analogy often used to explain the...Ch. 13 - 13-13 Answer true or false. A phenyl group has the...Ch. 13 - Prob. 13.14PCh. 13 - 13-15 Draw structural formulas for these compounds...Ch. 13 - 13-16 We say that naphthalene, anthracene,...Ch. 13 - 13-17 Following is the structural formula of...Ch. 13 - 13-18 Answer true or false. Benzene does not...Ch. 13 - 13-19 Suppose you have unlabeled bottles of...Ch. 13 - 13-20 Three products with the molecular formula...Ch. 13 - 13-21 The reaction of bromine with toluene in the...Ch. 13 - 13-22 What reagents and/or catalysts are necessary...Ch. 13 - 13-23 What reagents and/or catalysts are necessary...Ch. 13 - Prob. 13.24PCh. 13 - 13-25 Answer true or false. (a) Phenols and...Ch. 13 - 13-26 Both phenol and cyclohexanol are only...Ch. 13 - 13-27 Define autoxidation.Ch. 13 - 13*28 Autoxidation is described as a radical-chain...Ch. 13 - 13-29 Show that if you add Steps 2a and 2b of the...Ch. 13 - 13-30 How does vitamin E function as an...Ch. 13 - 13-31 What structural features are common to...Ch. 13 - 13*32 Black-and-white photography is a commercial...Ch. 13 - 13-33 Following is the structural formula of...Ch. 13 - 13-34 (Chemical Connections 13A) From what parts...Ch. 13 - Prob. 13.35PCh. 13 - 13-36 (Chemical Connections 13A, Would you expect...Ch. 13 - Prob. 13.37PCh. 13 - 13-38 (Chemical Connections 13A) What is meant by...Ch. 13 - 13-39 (Chemical Connections 13B) What is a...Ch. 13 - 13-40 (Chemical Connections 130 In the absence of...Ch. 13 - Prob. 13.41PCh. 13 - 13-42 (Chemical Connections 13E) What are the...Ch. 13 - 13-43 (Chemical Connections 13E) Which features of...Ch. 13 - 13-44 (Chemical Connections 13E) What color would...Ch. 13 - Prob. 13.45PCh. 13 - Prob. 13.46PCh. 13 - Prob. 13.47PCh. 13 - 13-48 (Chemical Connections 13F, How many...Ch. 13 - 13-49 (Chemical Connections 13F) In what ways is...Ch. 13 - 13*50 The structure for naphthalene given in...Ch. 13 - 13-51 Draw structural formulas for these...Ch. 13 - 13-52 2,6-Di-/ezY-butyl-4-methylphenol (BHT,...Ch. 13 - 13-53 Write the structural formula for the product...Ch. 13 - 13-54 Styrene reacts with bromine to give a...Ch. 13 - 13-55 When toluene is treated with Br, in the...Ch. 13 - 13-56 Four alternatives to the structure of...Ch. 13 - 13-57 Benzene, as we have seen in this chapter, is...
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13-3 What is the difference in structure between a saturated and an unsaturated hydrocarbon?
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13-5 Why are alkenes, alkynes, and aromatic compounds said to be unsaturated?
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13-16 We say that naphthalene, anthracene, phenanthrene, and benzo[ajpyrene are polynuclear aromatic hydrocarbons. In this context, what does “polynuclear” mean? What does “aromatic” mean? What does “hydrocarbon” mean?
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Among the ingredients listed in one commercial foam shaving gel are isobutane and isopentane. Write the 1UPAC name of each hydrocarbon. Why are these two hydrocarbons added to the formulation of the shaving gel?
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13-48 (Chemical Connections 13F, How many cis-trans isomers are possible for capsaicin? Is the structural formula shown in this Chemical Connection the cis isomer or the trans isomer?
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Consider a cyclohexane ring substituted with one methyl group and one hydroxyl group. Draw the structural formula for a compound with this composition that: Does not show cis/trans isomerism. Does show cis/trans isomerism.
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11-12 Why is it not accurate to describe an unbranchedalkane as a “straight-chain” hydrocarbon?
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As stated in Section 11-9, the wax found in apple skins is an unbranched alkane with the molecular formula C^H^. Explain how the presence of this alkane in apple skins prevents the loss of moisture from within the apple.
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13-54 Styrene reacts with bromine to give a compound with the molecular formula CgH8Br2. Draw a struc tural formula for this compound.
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12-59 Show how to convert 1-butene to these compounds, (a) Butane(b) 2-Butanol (c) 2-Bromobutane(d) 1,2-Dibromobutane
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Dodecane, C12H26, is an unbranched alkane Predict the following: Will it dissolve in water? Will it dissolve in hexane? Will it burn when ignited? Is it a liquid, solid, or gas at room temperature and atmospheric pressure? Is it more or less dense than water?
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12-58 Show how to convert ethylene to these compounds (a) Ethane(b) Ethanol (c) Bromoethane(d) 1,2-Dibromoethane (e) Chloroethane
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