Chemistry for Today: General, Organic, and Biochemistry
9th Edition
ISBN: 9781305960060
Author: Spencer L. Seager, Michael R. Slabaugh, Maren S. Hansen
Publisher: Cengage Learning
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Chapter 13, Problem 13.24E
Draw the structures of the ethers that can be produced from the following alcohols:
a.
b. 
c. 
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What reagents are used in the esterification of Alcohols and Phenols?
a.Write the reaction involved in Primary Alcohol (Ethanol) and Acetyl Chloride
b. Write the reaction involved in Phenol and Acetyl Chloride
ALCOHOLS
1. WHY IS METHANOL MORE TOXIC THAN ETHANOL?
2. FROM WHAT ALKENE IS ETHANOL MADE? DRAW ITS CONDENSED STRUCTURAL FORMULA
3. HOW DOES RUBBING ALCOHOL A FEVERISH PATIENT?
i. Why is the boiling point of the aldehyde greater than that of the alkane? ii. Why is the boiling point of alcohol the highest? iii. Explain why the solubility of aldehydes and alcohols falls as the molecules get bigger.
Chapter 13 Solutions
Chemistry for Today: General, Organic, and Biochemistry
Ch. 13 - Draw general formulas for an alcohol and phenol,...Ch. 13 - Prob. 13.2ECh. 13 - Assign IUPAC names to the following alcohols: a....Ch. 13 - Assign IUPAC names to the following alcohols: a....Ch. 13 - Several important alcohols are well known by...Ch. 13 - Prob. 13.6ECh. 13 - Draw structural formulas for each of the...Ch. 13 - Draw structural formulas for each of the...Ch. 13 - Name each of the following as a derivative of...Ch. 13 - Name each of the following as a derivative of...
Ch. 13 - Prob. 13.11ECh. 13 - Draw structural formulas for each of the...Ch. 13 - Prob. 13.13ECh. 13 - Classify the following alcohols as primary,...Ch. 13 - Classify the following alcohols as primary,...Ch. 13 - Draw structural formulas for the four aliphatic...Ch. 13 - Why are the boiling points of alcohols much higher...Ch. 13 - Arrange the compounds of each group in order of...Ch. 13 - Prob. 13.19ECh. 13 - Draw structural formulas for the following...Ch. 13 - Prob. 13.21ECh. 13 - Draw the structures of the chief product formed...Ch. 13 - Draw the structures of the chief product formed...Ch. 13 - Draw the structures of the ethers that can be...Ch. 13 - Prob. 13.25ECh. 13 - Give the structure of an alcohol that could be...Ch. 13 - Give the structure of an alcohol that could be...Ch. 13 - What products would result from the following...Ch. 13 - What products would result from the following...Ch. 13 - Each of the following conversions requires more...Ch. 13 - Each of the following conversions requires more...Ch. 13 - The three-carbon diol used in antifreeze is It is...Ch. 13 - Methanol is fairly volatile and evaporates quickly...Ch. 13 - Prob. 13.34ECh. 13 - Prob. 13.35ECh. 13 - Name an alcohol used in each of the following...Ch. 13 - Prob. 13.37ECh. 13 - Prob. 13.38ECh. 13 - Assign a common name to each of the following...Ch. 13 - Assign a common name to each of the following...Ch. 13 - Assign the IUPAC name to each of the following...Ch. 13 - Assign the IUPAC name to each of the following...Ch. 13 - Prob. 13.43ECh. 13 - Draw structural formulas for the following: a....Ch. 13 - Prob. 13.45ECh. 13 - Prob. 13.46ECh. 13 - Prob. 13.47ECh. 13 - Arrange the following compounds in order of...Ch. 13 - Arrange the compounds in Exercise 13.48 in order...Ch. 13 - Prob. 13.50ECh. 13 - Complete the following reactions: a. b....Ch. 13 - Prob. 13.52ECh. 13 - Lipoic acid is required by many microorganisms for...Ch. 13 - Alcohols and thiols can both be oxidized in a...Ch. 13 - Prob. 13.55ECh. 13 - Prob. 13.56ECh. 13 - Prob. 13.57ECh. 13 - Thiols have lower boiling points and are less...Ch. 13 - Prob. 13.59ECh. 13 - Prob. 13.60ECh. 13 - Prob. 13.61ECh. 13 - Prob. 13.62ECh. 13 - A mixture of ethanol and 1propanol is heated to...Ch. 13 - Prob. 13.64ECh. 13 - Prob. 13.65ECh. 13 - Prob. 13.66ECh. 13 - Prob. 13.67ECh. 13 - Figure 13.8 points out that methanol is used as a...Ch. 13 - Figure 13.13 focuses on the use of thiol chemistry...Ch. 13 - Prob. 13.70ECh. 13 - Prob. 13.71ECh. 13 - Prob. 13.72ECh. 13 - The compound that has the greatest polarity is: a....Ch. 13 - Alcoholic beverages contain: a. wood alcohol. b....Ch. 13 - Prob. 13.75ECh. 13 - Which of the following compounds is an ether? a....
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- 1. What functional group increases the boiling point of straight chain primary alcohols and carboxylic acids by 18 degrees Celsius? methane methylane ethylene methylene 2. What type of bonds are present between alcohol molecules that allow them to have a higher boiling point than saturated hydrocarbons? A. Van der Waals forces B. hydrogen bond C. london forces D. dipole-dipole bonds 3. It is a compound composed of 2 similar subunits or held together by ionic or covalent bonds. primer chiral monomer dimerarrow_forwardTrue or false? Tertiary Alcohols are the most reactive in Lucas Test Reactions are dependent on the type of alcohol Alcohols have lower boiling points than alkanes of similar molecular mass. As carbon chain length increases beyond three carbons, solubility in water rapidly decreases 15/15 The Carbon-Carbon functional group dominates the physical properties of methanol. The molecule is completely soluble in water (polar) but only partially so in hexane (nonpolar).arrow_forwardWhat kind of solvent ingredients is usually used in the concentrations of 4-10 percent in skin care products and their function is to soften skin cells and to lessen wrinkles? A. Ethly acetate B. Alpha hydroxyl acids C. Phenols and phenol derivatives D. Aliphatic alcoholsarrow_forward
- What reagents are used in the esterification of Alcohols and Phenols? a. Write the reaction involved in Primary Alcohol (Ethanol) and Acetyl Chloride b. Write the reaction involved in Phenol and Acetyl Chloride What is the purpose of the Chromic acid test? a. What are the reagents used? b. Write oxidation reaction of Primary Alcohols and Secondary Alcoholsarrow_forwardALCOHOLS 1. WHY IS ETHANOL MORE SOLUBLE IN WATER THAN 1-HEXANOL? 2. WHAT IS DENATURED ALCOHOL? AND WHY IS ALCOHOL DENATURED? ETHER 1. WHY DOES DIETHYL ETHER HAVE MUCH LOWER BOILING POINT THAN 1-BUTANOL?arrow_forwardList four reagents which can be used for the oxidation of alcohols 1. 2. 3. 4.arrow_forward
- a) Write the name b) draw the structure product formed from the reaction of 3-methylpent-2-ene 1) H2O in the presence of H2SO4 2)ethanol in the presence of H2SO4arrow_forward3. Dimethyl ether, H3C-O-CH3, is a gas at room temperature and insoluble in water. Draw a structural isomer of dimethyl ether that is much more soluble in water and explain the basis of its increased water solubility.arrow_forward1. Draw the structures of Methyl-benzene, 2-Acetyltoluene, 4-Acetyltoluene 2. What type of intermolecular forces exist for Methyl-benzene, 2-Acetyltoluene, 4-Acetyltoluene 3. based on what you know about the boiling points of Methyl-benzene, 2-Acetyltoluene, 4-Acetyltoluene in which are intermolecular forces strongest? Why?arrow_forward
- 1. Which of the following compounds is most soluble in water: (a) dimethyl ether, (b) diethyl ether or (c) hexane? 2. Give the IUPAC names for the following cyclic ethers. Refer to the image.arrow_forward3 Ethers (general formula R—O—R,) have many important uses. Until recently, methyl tert-butyl ether (MTBE, below) was used as an octane booster and fuel additive for gasoline. It increases the oxygen content of the fuel, which reduces CO emissions. MTBE is synthesized by the catalyzed reaction of 2-methylpropene with methanol.(a) Write a balanced equation for the synthesis of MTBE. (Hint: Alcohols add to alkenes similarly to the way water does.)arrow_forwardMolecule Type Boiling point (°C) CH3CH2CH3 Alkane -42 CH3CHO Aldehyde +21 CH3CH2OH Alcohol +78 i. Why is the boiling point of the aldehyde greater than that of the alkane?ii. Why is the boiling point of alcohol the highest?iii. Explain why the solubility of aldehydes and alcohols falls as the molecules get bigger.arrow_forward
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