EBK A SMALL SCALE APPROACH TO ORGANIC L
EBK A SMALL SCALE APPROACH TO ORGANIC L
4th Edition
ISBN: 9781305446021
Author: Lampman
Publisher: CENGAGE LEARNING - CONSIGNMENT
bartleby

Concept explainers

Question
Chapter 13, Problem 3Q
Interpretation Introduction

Interpretation:

According to the terpene rule, the structure of caryophyllene needs to be explained.

Concept introduction:

Terpene rule or isoprene rule states that terpenoids structures are obtained by linking isoprene unit. Isoprene (2-methyl-1, 3-butadiene) is the monomer of natural rubber.

Expert Solution & Answer
Check Mark

Answer to Problem 3Q

The structure of caryophyllene fits in the terpene rule as caryophyllene contains a moiety which is similar to the polyisoprene unit.

Explanation of Solution

The structure of caryophyllene is represented as follows:

  EBK A SMALL SCALE APPROACH TO ORGANIC L, Chapter 13, Problem 3Q , additional homework tip  1

The polymerization of isoprene is represented as follows:

  EBK A SMALL SCALE APPROACH TO ORGANIC L, Chapter 13, Problem 3Q , additional homework tip  2

Polymerization of isoprene leads to a basic structure that is present in all terpenoids (shown in red). Similarly, caryophyllene also has a similar moiety (shown red) as present in terpenoids. Thus, the structure of caryophyllene fits in the terpene rule.

Want to see more full solutions like this?

Subscribe now to access step-by-step solutions to millions of textbook problems written by subject matter experts!
Students have asked these similar questions
With the help of a chemical reaction, show the process of complete hydrogenation for 9,12-octadecadienoic acid. What is the side effect and its consequences observed in above processes?
In a paragraph form, provide the experimental procedures of The second stage is the 3-benzoylpropionic acid reaction of Clemmenson, which results in 4-phenyl butanoic acid. Clemmensen reaction is observed in the presence of zinc amalgam and hydrochloric acid.
Would you be able to isolate either Citral from lemon grass or 1-propanol from Aloe africanaby steam distillation? Briefly explain your answer for each case.
Knowledge Booster
Chemistry
Learn more about
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.
Similar questions
    • SEE MORE QUESTIONS
    Recommended textbooks for you
  • EBK A SMALL SCALE APPROACH TO ORGANIC L
    Chemistry
    ISBN:9781305446021
    Author:Lampman
    Publisher:CENGAGE LEARNING - CONSIGNMENT
    Macroscale and Microscale Organic Experiments
    Chemistry
    ISBN:9781305577190
    Author:Kenneth L. Williamson, Katherine M. Masters
    Publisher:Brooks Cole
  • EBK A SMALL SCALE APPROACH TO ORGANIC L
    Chemistry
    ISBN:9781305446021
    Author:Lampman
    Publisher:CENGAGE LEARNING - CONSIGNMENT
    Macroscale and Microscale Organic Experiments
    Chemistry
    ISBN:9781305577190
    Author:Kenneth L. Williamson, Katherine M. Masters
    Publisher:Brooks Cole