When the 1î-NMR spectrum of acetone, CH3COCH3, is recorded on an instrument operating at 200 MHz, a single sharp resonance at 2.1î is seen. (a) How many hertz downfield from TMS does the acetone resonance correspond to? (b) If the 1î-NMR spectrum of acetone were recorded at 500 MHz, what would the position of the absorption be in î units? (c) How many hertz downfield from TMS does this 500 MHz resonance correspond to?

Organic Chemistry
9th Edition
ISBN:9781305080485
Author:John E. McMurry
Publisher:John E. McMurry
Chapter13: Structure Determination: Nuclear Magnetic Resonance Spectroscopy
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Problem 31AP: When measured on a spectrometer operating at 200 MHz, chloroform (CHCl3) shows a single sharp...
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When the 1î-NMR spectrum of acetone, CH3COCH3, is recorded on an instrument operating at 200 MHz, a single sharp resonance at 2.1î is seen.

(a) How many hertz downfield from TMS does the acetone resonance correspond to?

(b) If the 1î-NMR spectrum of acetone were recorded at 500 MHz, what would the position of the absorption be in î units?

(c) How many hertz downfield from TMS does this 500 MHz resonance correspond to?

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