Organic Chemistry - Standalone book
10th Edition
ISBN: 9780073511214
Author: Francis A Carey Dr., Robert M. Giuliano
Publisher: McGraw-Hill Education
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Textbook Question
Chapter 13.6, Problem 7P
Write a reasonable mechanism for the formation of cyclohexylbenzene from the reaction of
benzene, cyclohexene, and sulfuric acid.
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Table 1: Distillation Data Table
Glassware
Mass (g)
BEFORE DISTILLATION
Distillation Flask + boiling chips
44.1161 g
Distillation Flask + boiling chips + Unknown Liquid Mixture
61.9474 g
Receiving Flask
30.2201 g
AFTER DISTILLATION
Receiving Flask + Low BP Liquid
36.5895 g
Distillation Flask + boiling chips + High BP Liquid
54.8759 g
DENSITY MEASUREMENT
Volumetric Flask for LBP liquid (empty)
17.2148 g
Volumetric Density Flask + LBP liquid
18.0846 g
Volumetric Flask for HBP liquid (empty)
14.5110 g
Volumetric Flask + HBP liquid
15.3117 g
Additional Calculated Data
Mass of the Unknown Liquid Mixture: 17.8271 g
Vapor temperature stabilized range for the LBP: 56–57°C
LBP liquid mass: 6.3754 g
HBP liquid mass: 10.9546 g
Boiling point for LBP liquid: 66.1–66.3°C
Boiling point for HBP liquid: 90.6–91.2°C
LBP liquid density: 0.870 g/mL
HBP liquid density: 0.801 g/mL
Table 2: Solids Recovery and Melting Point Data
Glassware
Mass (g)…
If it is agreed to change the reference for the atomic mass unit so that 1 atom of 12C will be considered to have a mass of 1 atomic mass unit (amu), what would be the equivalence between the atomic mass unit and the gram?
If it is agreed to change the reference for the atomic mass unit so that 1 atom of 12C will be considered to have a mass of 1 atomic mass unit (amu), what would be the equivalence between the atomic mass unit and the gram?
Chapter 13 Solutions
Organic Chemistry - Standalone book
Ch. 13.2 - Based on Hammonds postulate which holds that the...Ch. 13.3 - Prob. 2PCh. 13.3 - Using : O =N+= O : as the electrophile, write a...Ch. 13.4 - Prob. 4PCh. 13.5 - Prob. 5PCh. 13.6 - Prob. 6PCh. 13.6 - Write a reasonable mechanism for the formation of...Ch. 13.6 - tert-Butylbenzene can be prepared by alkylation of...Ch. 13.6 - Prob. 9PCh. 13.7 - The reaction shown gives a single product in 88...
Ch. 13.7 - Prob. 11PCh. 13.8 - Using benzene and any necessary organic or...Ch. 13.10 - Prob. 13PCh. 13.11 - Prob. 14PCh. 13.12 - Prob. 15PCh. 13.12 - Prob. 16PCh. 13.13 - Prob. 17PCh. 13.13 - Prob. 18PCh. 13.14 - Reaction of chlorobenzene with p-chlorobenzyl...Ch. 13.15 - Prob. 20PCh. 13.15 - Prob. 21PCh. 13.15 - Prob. 22PCh. 13.16 - Prob. 23PCh. 13.16 - Prob. 24PCh. 13.17 - Prob. 25PCh. 13.18 - Prob. 26PCh. 13.19 - Write the structure of the expected product from...Ch. 13.20 - Prob. 28PCh. 13.20 - Prob. 29PCh. 13.21 - Prob. 30PCh. 13.21 - Offer an explanation for the observation that...Ch. 13.21 - Prob. 32PCh. 13 - Write the structure of the organic product in each...Ch. 13 - Prob. 34PCh. 13 - Prob. 35PCh. 13 - Prob. 36PCh. 13 - Prob. 37PCh. 13 - Prob. 38PCh. 13 - Prob. 39PCh. 13 - Treatment of the alcohol shown with sulphuric acid...Ch. 13 - Prob. 41PCh. 13 - Prob. 42PCh. 13 - Prob. 43PCh. 13 - Arrange the following five compounds in order of...Ch. 13 - Prob. 45PCh. 13 - Prob. 46PCh. 13 - Prob. 47PCh. 13 - Give reagents suitable for carrying out each of...Ch. 13 - Prob. 49PCh. 13 - Prob. 50PCh. 13 - Which is the best synthesis of the compound shown?Ch. 13 - What combination of acyl chloride or acid...Ch. 13 - A standard synthetic sequence for building a...Ch. 13 - Prob. 54PCh. 13 - Prob. 55PCh. 13 - Prob. 56PCh. 13 - Prob. 57PCh. 13 - Prob. 58PCh. 13 - Prob. 59PCh. 13 - Prob. 60DSPCh. 13 - Prob. 61DSPCh. 13 - Prob. 62DSPCh. 13 - Prob. 63DSP
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