Chemistry for Today: General, Organic, and Biochemistry
9th Edition
ISBN: 9781305960060
Author: Spencer L. Seager, Michael R. Slabaugh, Maren S. Hansen
Publisher: Cengage Learning
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Textbook Question
Chapter 14, Problem 14.12E
Each of the following names is wrong. Give the structure and correct name of
each compound.
a
b
c.
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Fill in the blanks;
______ has a higher boiling point than _________?
a. Carbon dioxide; 1-butanamine
b. Butane; 2-butanol
c. None of these are correct
d. 1-methoxypropane; 2-heptene
e. Cyclohexane; 1-propanol
A 5-carbon dialdehyde
A.
glyoxal
B.
phenol
C.
glutaraldehyde
D.
zephron chloride
What is the name of this molecule?
A. 8-chloro-4-propanyloctyne
B. 1-chloro-5-methyl-5-octyne
C. 1-chloro-5-octyne
D. 7-chloro-3-propyl-1-heptyne
Chapter 14 Solutions
Chemistry for Today: General, Organic, and Biochemistry
Ch. 14 - Prob. 14.1ECh. 14 - Prob. 14.2ECh. 14 - Identify each of the following compounds as an...Ch. 14 - Identify each of the following compounds as an...Ch. 14 - Prob. 14.5ECh. 14 - Prob. 14.6ECh. 14 - Prob. 14.7ECh. 14 - Prob. 14.8ECh. 14 - Draw structural formulas and give IUPAC names for...Ch. 14 - Draw structural formulas and give IUPAC names for...
Ch. 14 - Each of the following names is wrong. Give the...Ch. 14 - Each of the following names is wrong. Give the...Ch. 14 - Prob. 14.13ECh. 14 - Prob. 14.14ECh. 14 - Prob. 14.15ECh. 14 - Explain why propane boils at 42C, whereas ethanal,...Ch. 14 - Use a dotted line to show hydrogen bonding between...Ch. 14 - Use a dotted line to show hydrogen bonding between...Ch. 14 - Prob. 14.19ECh. 14 - Prob. 14.20ECh. 14 - Prob. 14.21ECh. 14 - Prob. 14.22ECh. 14 - Prob. 14.23ECh. 14 - Prob. 14.24ECh. 14 - Label each of the following as acetals, ketals, or...Ch. 14 - Label each of the following as acetals, ketals, or...Ch. 14 - Label each of the following structures as a cyclic...Ch. 14 - Label each of the following structures as a...Ch. 14 - What two functional groups react to form the...Ch. 14 - Hemiacetals are sometimes referred to as potential...Ch. 14 - Complete the following statements: a. Oxidation of...Ch. 14 - Prob. 14.32ECh. 14 - Prob. 14.33ECh. 14 - Prob. 14.34ECh. 14 - Prob. 14.35ECh. 14 - Not all aldehyde give a positve Bendicts test....Ch. 14 - A stockroom assistant prepares three bottles, each...Ch. 14 - Glucose, the sugar present within the blood, gives...Ch. 14 - Fructose, present with glucose in honey, reacts...Ch. 14 - Prob. 14.40ECh. 14 - Prob. 14.41ECh. 14 - Complete the following equations. If no reaction...Ch. 14 - Complete the following equations. If no reaction...Ch. 14 - Describe the products that result when hydrogen...Ch. 14 - Prob. 14.45ECh. 14 - Draw structural formulas for the products of the...Ch. 14 - The following compounds are cyclic acetals or...Ch. 14 - The following compounds are cyclic acetals or...Ch. 14 - Write equations to show how the following...Ch. 14 - Prob. 14.50ECh. 14 - Identify the most important aldehyde and ketone...Ch. 14 - Using Table 14.3, name an aldehyde or ketone used...Ch. 14 - Prob. 14.53ECh. 14 - CH3COH(O)CH3COOHacetaldehydeaceticacid You need to...Ch. 14 - The addition of water to aldehydes and ketones...Ch. 14 - Prob. 14.56ECh. 14 - Formaldehyde levels above 0.10mg/1000L of ambient...Ch. 14 - In the IUPAC name for the following ketone, it is...Ch. 14 - Why can formaldehyde (CH2O) be prepared in the...Ch. 14 - Other addition reactions of aldehydes occur....Ch. 14 - Prob. 14.61ECh. 14 - Prob. 14.62ECh. 14 - Vanilla flavoring is either extracted from a...Ch. 14 - Prob. 14.64ECh. 14 - The use of acetone in laboratory experiments must...Ch. 14 - Prob. 14.66ECh. 14 - Prob. 14.67ECh. 14 - Which of the following would be classified as a...
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Arrange these compounds in order of increasing boiling point. (a) 1-butanol, butane, diethylether (b) hexane, 1-hexanol, dipropylether
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Draw compounds that contain the following: (a) A primary alcohol (b) A tertiary nitrile (c) A secondary thiol (d) Both primary and secondary alcohols (e) An isopropyl group (f) A quaternary carbon
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List the following compounds in order of increasing water solubility: a.ethoxyethane b.propanoic acid c.pentane d.1 butanol
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Draw the structures for each of the following molecules. (a) 2-fluorotoluene; (b) 4-ethoxytoluene; (c) 2-ethoxyanisole;(d) 1,3-diphenylheptane; (e) 4,4-diphenyl-1-octene; (f) benzylbenzene
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Draw the structure of 2-pentanone
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Consider a compound with a formula: C5H10O (5 carbons, 10 hydrogens, one oxygen). A correct IUPAC name for one of ketone isomers of this compound is
a
3-Methybutanal
b
4-Methylbutanone
c
3-Methylbutanone
d
None of the above
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Which is FALSE about aldehydes?
A.) In naming correct IUPAC name: Replace -e with -al.
B.) The aldehyde carbon is always number 1
C.) The C=O can be found anywhere in the chain
D.) Decreasing polarity as carbons increases
E.) None of the given choices
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1a) All of the following would be considered isomers of each other except for which compound? Why?
a) 2,2-dimethylpropane
b) 2-methylbutane
c) 3-methylbutane
d) pentane
e)2,3-dimethylbutane
1b)Which of the following pairs are considered isomers?Why?
a) 1-propene and 1-propyne
b)ethyl propanoate and hexanoic acid
c)ethyl methyl ether and 1-butanol
d) hexanoic acid and 2 pentanol
e) ethyl hexyl and 2-octanol
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Draw the structures of the following compound and give it's IUPAC name:
a. Methyl mercaptan
b. sec-BUtyl mercaptan
c. 2-Methyl-2-propanethiol
d. 1-Pentanethiol
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Draw structures corresponding to the following IUPAC names:
(a) 3-Methylbutanal (b) 3-Methylbut-3-enal
(c) 4-Chloropentan-2-one (d) Phenylacetaldehyde
(e) 2,2-Dimethylcyclohexanecarbaldehyde (f ) Cyclohexane-1,3-dione
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Select the functional group with the lowest oxidation state.
a. carboxylic acid
b. nitrile
c. alkene
d. ketone
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3-ethyl-2-butanone
2-methyl-2-phenylethanal
give the structure and correct name for each compound
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