Principles of Instrumental Analysis
7th Edition
ISBN: 9781305577213
Author: Douglas A. Skoog, F. James Holler, Stanley R. Crouch
Publisher: Cengage Learning
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Chapter 14, Problem 14.22QAP
Mixing the chelating reagent B with Ni(II) forms the highly colored NiB22+, whose solutions obey Beer’s lawat 395 nm overa wide range. Provided the analytical concentration of the chelating reagent exceeds that of Ni(II) by a factor of 5 (or more), the cation exists, within the limits of observation, entirely in the form of the complex. Use the accompanying data to evaluate the formation constant Kf for the process
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A dual beam UV-visible spectroscopy was used to determine the levels of Fe(II) in the run-off water of a local mine using the ferrozine assay
(i) During a check of the instrument a step-like feature at 360 nm was observed in spectrum of the standard. Suggest what may give rise to this with reference to the instrument configuration and comment on how it may be remedied.
(ii) The molar absorptivity of the [Fe(Ferrozine)3]2+ complex is 27900 cm−1 M−1 at 562 nm in aqueous solution (pH 5.5). If the EU maximum contaminant level for Fe is 200 ug /L and the contract required detection limit is 100 ug/L, comment on the suitability of the assay for the detection of iron.
(iii) Determine the sample range, in terms of concentration and ppm, of Fe(II) that can be confidently analysed by UV-visible spectroscopy using a 1 cm cuvette. Explain with reference to an appropriate equation and solution phenomena, the origin of the limitations that define this range
Give a lab cation separation scheme for Al3+, Ca2+, Ni2+ cations based on Ksp values and complex ion formations (if any).
The following data were obtained on the initial rates of reaction of a d-metal complex in aqueous solution.
For the experiments a. [Y] = 2.7 mmol/dm3,
and for experiments b. [Y] = 6.1 mmol/dm3
Conc. complex/(mmol dm-3)
8.01
9.22
12.11
Exp. a. v/ (mol dm-3 s-1)
125
144
190
Exp. b. v/ (mol dm-3 s-1)
640
730
960
b) use the data above to calculate the rate constant.
k = ________ (mol/L/s, s-1, L/mol/s, or L2/mol2/s). 3 s.f. normal format.
Chapter 14 Solutions
Principles of Instrumental Analysis
Ch. 14 - Prob. 14.1QAPCh. 14 - A 0.4740-g pesticide sample was decomposed by wet...Ch. 14 - Sketch a photometric titration curve for the...Ch. 14 - Prob. 14.4QAPCh. 14 - Prob. 14.5QAPCh. 14 - The accompanying data (1.00-cm cells) were...Ch. 14 - A 3.03-g petroleum specimen was decomposed by wet...Ch. 14 - Prob. 14.8QAPCh. 14 - Prob. 14.9QAPCh. 14 - The acid-base indicator HIn undergoes the...
Ch. 14 - Prob. 14.11QAPCh. 14 - Prob. 14.12QAPCh. 14 - Copper(II) forms a 1:1 complex with the organic...Ch. 14 - Aluminum forms a 1:1 complex with...Ch. 14 - Prob. 14.15QAPCh. 14 - Prob. 14.16QAPCh. 14 - Prob. 14.17QAPCh. 14 - Prob. 14.18QAPCh. 14 - Prob. 14.19QAPCh. 14 - Given the Information that...Ch. 14 - Prob. 14.21QAPCh. 14 - Mixing the chelating reagent B with Ni(II) forms...Ch. 14 - Prob. 14.23QAP
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