BuyFind

Physical Chemistry

2nd Edition
Ball + 3 others
Publisher: Wadsworth Cengage Learning,
ISBN: 9781133958437
BuyFind

Physical Chemistry

2nd Edition
Ball + 3 others
Publisher: Wadsworth Cengage Learning,
ISBN: 9781133958437

Solutions

Chapter
Section
Chapter 14, Problem 14.6E
Textbook Problem

The Cu ( H 2 O ) 6 2 + complex has octahedral symmetry. Is a transition from a T 2g state to an E g state allowed if the transition moment operator has a T 1u symmetry label?

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Chapter 14 Solutions

Physical Chemistry
Ch. 14 - The 79Br19F molecule has a bond distance of...Ch. 14 - A molecule of OCS rotates in a five-fold...Ch. 14 - Classify the following molecules as linear,...Ch. 14 - Classify the following molecules as linear,...Ch. 14 - Diatomic sulfur, S2, was detected in the tail of...Ch. 14 - Calculate the values for B of SF6 and UF6, which...Ch. 14 - The moments of inertia for phosphine, PH3, are...Ch. 14 - The moments of inertia of H2O are 1.091040kgm2,...Ch. 14 - Acetylene, HCCH, is a linear molecule with...Ch. 14 - Show that the degeneracy of rotational levels for...Ch. 14 - Calculate the values of the first five rotational...Ch. 14 - Calculate the values of the first five rotational...Ch. 14 - Which of the following molecules should have pure...Ch. 14 - Which of the following molecules should have pure...Ch. 14 - The following are sets of rotational quantum...Ch. 14 - The following are sets of rotational quantum...Ch. 14 - Derive equation 14.21 from the E expression...Ch. 14 - Having used a spectrometer to measure a simple...Ch. 14 - The rotational spectrum of 127I35Cl consists of...Ch. 14 - Lithium hydride, 7Li1H, is a potential fuel for...Ch. 14 - Determine the first four absorptions in the pure...Ch. 14 - Deermine the most populated rotational level,...Ch. 14 - The bond distance in diatomic O2 is 0.1210nm. What...Ch. 14 - Draw a to-scale version of the pure rotational...Ch. 14 - Given a pure rotational spectrum of the HS radical...Ch. 14 - A gas-phase sample is subjected to an electric...Ch. 14 - From the data in Table 14.2, predict B for DCl D...Ch. 14 - A colleague states that the pure rotational...Ch. 14 - Verify equation 14.26.Ch. 14 - CO has a vibrational frequency of 2170.2cm1 and a...Ch. 14 - An acquaintance remarks that a rotational spectrum...Ch. 14 - Consider the values in Table 14.2 and remark on...Ch. 14 - Using the value of v=4320cm1 for diatomic hydrogen...Ch. 14 - Determine E for J=20J=21 for HBr assuming it acts...Ch. 14 - Determine the number of total degrees of freedom...Ch. 14 - Determine the number of total degrees of freedom...Ch. 14 - How many total normal modes of vibration do the...Ch. 14 - How many total normal modes of vibration do the...Ch. 14 - Methane, CH4, has only two IR-active vibrational...Ch. 14 - Show that the two expressions in equation 14.30...Ch. 14 - Use the data in Example 14.12 to determine the...Ch. 14 - The force constant is O2 is 1180N/m. What is its...Ch. 14 - The ground - state vibrational frequency is BrF is...Ch. 14 - Verify that the ratio of vibrational frequencies...Ch. 14 - Considering reduced mass can sometimes yield...Ch. 14 - The FeH diatomic molecule absorbs infrared light...Ch. 14 - Why is nitrogen gas commonly used as a purge gas...Ch. 14 - From the description in the text of the...Ch. 14 - Which of these species will have pure vibrational...Ch. 14 - Which of these species will have pure vibrational...Ch. 14 - Differentiate between fundamental vibrations,...Ch. 14 - Are deviations from an ideal harmonic oscillator...Ch. 14 - Verify that 2V/r2=k, the force constant. Show that...Ch. 14 - Use Figure 14.29 to comment on the variances...Ch. 14 - Using the information in Table 14.4, calculate De...Ch. 14 - Use the equation for the energy of a Morse...Ch. 14 - By how much do D0 and De differ in CO if the...Ch. 14 - By how much do D0 and De differ in H2S if the...Ch. 14 - For H2S, D0=736.0kJ/mol. What is De? Use your...Ch. 14 - In exercise 14.56 above, the vibrational frequency...Ch. 14 - Drive the two equations used to solve exercise...Ch. 14 - From Figure 14.32, label the normal modes of NH3...Ch. 14 - Consider the following two vibrational modes of...Ch. 14 - Each of the following pairs of molecules has the...Ch. 14 - List the individual symmetry elements for the...Ch. 14 - Determine the number of IR-active vibrations for...Ch. 14 - Determine the number of IR-active vibrations for...Ch. 14 - Determine the number of IR-active vibrations for...Ch. 14 - How would you determine if KrF4, if it were...Ch. 14 - Determine the number of IR-active vibrations for...Ch. 14 - Verify that cubane, C8H8, has only three IR-active...Ch. 14 - Carbon dioxide has the following fundamental...Ch. 14 - Would you expect the above combination absorptions...Ch. 14 - Why is it possible to identify group frequency...Ch. 14 - Dioctyl sulfide, (C8H17)2S, and hexadecane,...Ch. 14 - Where would you expect vibrations for ethyl...Ch. 14 - Silane, SiH4, has a tetrahedral geometry and a...Ch. 14 - Electronic energy level transitions typically have...Ch. 14 - What are the forms of equations 14.41 and 14.42 if...Ch. 14 - The table in exercise 14.97 lists some frequencies...Ch. 14 - Derive the expression used to answer Example...Ch. 14 - Two Raman spectra are measured on the same sample....Ch. 14 - Determine the number of Raman-active vibrations...Ch. 14 - The mutual exclusion rule states that for certain...Ch. 14 - Is xenon tetrafluoride, XeF4, tetrahedral or...Ch. 14 - Several equations can be derived from equations...Ch. 14 - Use equation 14.17 to determine the energies of...Ch. 14 - What are the energy changes for the allowed...Ch. 14 - Construct and compare the energy level diagrams...Ch. 14 - Construct and compare the energy level diagrams...

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