Explain why pure liquids and solids can be ignored while writing the equilibrium constant expression ?

Chemistry: Matter and Change
1st Edition
ISBN:9780078746376
Author:Dinah Zike, Laurel Dingrando, Nicholas Hainen, Cheryl Wistrom
Publisher:Dinah Zike, Laurel Dingrando, Nicholas Hainen, Cheryl Wistrom
Chapter17: Chemical Equilibrium
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Problem 38A
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Explain why pure liquids and solids can be ignored while writing the equilibrium constant expression ?
Expert Solution
Step 1

Introduction-

The reaction is said to be in equilibrium if both the forward and backward reaction is in same pace. In this kind of reaction, the equilibrium constant expression in the terms of concentration (Kc) is the ratio of product of product concentration to the product of reactant concentration.

Step 2

Explanation-

The concentration of reactants or products that is here pure solid or pure liquid is the ratio of no. of moles to that of volume.

Kc =No. of MolesVolume 

 

Number of moles is mass by molar mass.

No. of Moles = MassMolar mass

 

 

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