Chemistry: Principles and Reactions
8th Edition
ISBN: 9781305079373
Author: William L. Masterton, Cecile N. Hurley
Publisher: Cengage Learning
expand_more
expand_more
format_list_bulleted
Concept explainers
Videos
Textbook Question
Chapter 14, Problem 37QAP
Given three acid-base indicators—methyl orange (end point at pH 4), bromthymol blue (end point at pH 7), and phenolphthalein (end point at pH 9)—which would you select for the following
(a) perchloric acid with an aqueous solution of ammonia
(b) nitrous acid with lithium hydroxide
(c) hydrobromic acid with strontium hydroxide
(d) sodium fluoride with nitric acid
Expert Solution & Answer
Trending nowThis is a popular solution!
Students have asked these similar questions
TRIS (also known during medical use as THAM) is an organic compound used extensively in biochemistryand molecular biology as a component of buffer solutions, especially for solutions of nucleic acids. At 37oC,-7body temperature, its Kb value is 5.13 x 10 . What is the approximate ratio of acid to base at pH 7.4, the pH ofblood?
A 250 cm3 volumetric flask contains exactly 200,0 cm3 of a 0,025 mol.dm3sulphuric acid solution. Thereafter ten (10) sodium hydroxide pellets, eachof mass 0,1 g are dropped into the flask. After the pellets have dissolvedcompletely, the flask is topped to the 250 cm3 mark with water and thecontents are thoroughly homogenised. Determine the pH of the resultingsolution.
How to write the methodology? I have a practical of the MEASUREMENT USING PH METER, I don't know how to write the methodology.
Here is the introduction:
A pH meter is an electronic device mainly used for qualitative measurement, for thedetermination of acid and the basic value of a solution. Generally, it measures thehydrogen ion concentration/activity [H+] in a solution. It is denoted as:pH = - log10 [H+]In a pure water solution, the concentration of [H+] and [OH-] ions, respectively, rangefrom 1.0 x 10-1 M to 1.0 x 10-14 M. When [H+] is equal to [OH-] as when pure waterdissociates, the hydrogen ion concentration of pure water is equal to 1.0 x 10-7 M orpH = 7.00, defined as a neutral solution at 25°C, to be of temperaturedependent/endothermic dissociation.[H+] = [OH-] = 1.0 x 10-7 MWhen an ionic or polar substance is dissolved in water, it may change the relativenumbers of H+ and OH-. The higher the pH number, the lower the hydrogen ion concentration, and vice versa.
Solution with an…
Chapter 14 Solutions
Chemistry: Principles and Reactions
Ch. 14 - Write a net ionic equation for the reaction...Ch. 14 - Write a net ionic equation for the reaction...Ch. 14 - Write a balanced net ionic equation for the...Ch. 14 - Write a balanced net ionic equation for the...Ch. 14 - Calculate K for the reactions in Question 1.Ch. 14 - Calculate K for the reactions in Question 2.Ch. 14 - Prob. 7QAPCh. 14 - Calculate K for the reactions in Question 4.Ch. 14 - Calculate [H+] and pH in a solution in which...Ch. 14 - Calculate [OH-] and pH in a solution in which the...
Ch. 14 - A buffer is prepared by dissolving 0.0250 mol of...Ch. 14 - A buffer is prepared by dissolving 0.062 mol of...Ch. 14 - A buffer solution is prepared by adding 15.00 g of...Ch. 14 - A buffer solution is prepared by adding 5.50 g of...Ch. 14 - A solution with a pH of 9.22 is prepared by adding...Ch. 14 - An aqueous solution of 0.057 M weak acid, HX, has...Ch. 14 - Which of the following would form a buffer if...Ch. 14 - Which of the following would form a buffer if...Ch. 14 - Calculate the pH of a solution prepared by mixing...Ch. 14 - Calculate the pH of a solution prepared by mixing...Ch. 14 - Calculate the pH of a solution prepared by mixing...Ch. 14 - Calculate the pH of a solution prepared by mixing...Ch. 14 - Consider the weak acids in Table 13.2. Which...Ch. 14 - Prob. 24QAPCh. 14 - A sodium hydrogen carbonate-sodium carbonate...Ch. 14 - You want to make a buffer with a pH of 10.00 from...Ch. 14 - Prob. 27QAPCh. 14 - The buffer capacity indicates how much OH- or H+...Ch. 14 - A buffer is made up of 0.300 L each of 0.500 M...Ch. 14 - A buffer is made up of 239 mL of 0.187 M potassium...Ch. 14 - Enough water is added to the buffer in Question 29...Ch. 14 - Enough water is added to the buffer in Question 30...Ch. 14 - A buffer is prepared in which the ratio [ H2PO4...Ch. 14 - A buffer is prepared using the butyric...Ch. 14 - Blood is buffered mainly by the HCO3 H2CO3 buffer...Ch. 14 - There is a buffer system in blood H2PO4 HPO42 that...Ch. 14 - Given three acid-base indicators—methyl orange...Ch. 14 - Given the acid-base indicators in Question 37,...Ch. 14 - Metacresol purple is an indicator that changes...Ch. 14 - Thymolphthalein is an indicator that changes from...Ch. 14 - When 25.00 mL of HNO3 are titrated with Sr(OH)2,...Ch. 14 - A solution of KOH has a pH of 13.29. It requires...Ch. 14 - A solution consisting of 25.00 g NH4Cl in 178 mL...Ch. 14 - A 50.0-mL sample of NaHSO3 is titrated with 22.94...Ch. 14 - A sample of 0.220 M triethylamine, (CH3CH2)3 N, is...Ch. 14 - A 35.00-mL sample of 0.487 M KBrO is titrated with...Ch. 14 - A 0.4000 M solution of nitric acid is used to...Ch. 14 - A 0.2481 M solution of KOH is used to titrate...Ch. 14 - Consider the titration of butyric acid (HBut) with...Ch. 14 - Morphine, C17H19O3N, is a weak base (K b =7.4107)....Ch. 14 - Consider a 10.0% (by mass) solution of...Ch. 14 - A solution is prepared by dissolving 0.350 g of...Ch. 14 - Prob. 53QAPCh. 14 - Ammonia gas is bubbled into 275 mL of water to...Ch. 14 - For an aqueous solution of acetic acid to be...Ch. 14 - Prob. 56QAPCh. 14 - Prob. 57QAPCh. 14 - Water is accidentally added to 350.00 mL of a...Ch. 14 - A solution of an unknown weak base...Ch. 14 - Consider an aqueous solution of HF. The molar heat...Ch. 14 - Each symbol in the box below represents a mole of...Ch. 14 - Use the same symbols as in Question 61 ( = anion,...Ch. 14 - The following is the titration curve for the...Ch. 14 - Prob. 64QAPCh. 14 - Follow the directions of Question 64. Consider two...Ch. 14 - Prob. 66QAPCh. 14 - Indicate whether each of the following statements...Ch. 14 - Prob. 68QAPCh. 14 - Consider the following titration curves. The...Ch. 14 - Consider the titration of HF (K a=6.7104) with...Ch. 14 - The species called glacial acetic acid is 98%...Ch. 14 - Four grams of a monoprotic weak acid are dissolved...Ch. 14 - Prob. 73QAPCh. 14 - Fifty cm3 of 1.000 M nitrous acid is titrated with...Ch. 14 - A diprotic acid, H2B(MM=126g/moL), is determined...Ch. 14 - Prob. 76QAPCh. 14 - Two students were asked to determine the Kb of an...Ch. 14 - How many grams of NaOH must be added to 1.00 L of...Ch. 14 - How many grams of NaF must be added to 70.00 mL of...Ch. 14 - Prob. 80QAP
Knowledge Booster
Learn more about
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.Similar questions
- Sketch a titration curve for the titration of potassium hydroxide with HCl, both 0.100 M. Identify three regions in which a particular chemical species or system dominates the acid-base equilibria.arrow_forwardIn a system where a weak acid is an analyte, a strong base is a titrant, what is the milestone pH range, and which of the Metrol thrush phenolphthalein and litmus indicators would you choose?arrow_forwardDiscuss the justification for this statement: “Although one does not normally regard NH+4 as an acid, it is actually only slightly weaker as an acid than hydrocyanic acid, HCN, in aqueous solution.”arrow_forward
- Sodium acetate, CH3COONa was hydrolysed in water, H2O. Show thereaction equations involved. What is the effect of the salt on the pH of thissolution?arrow_forwardFor a titration to be effective, the reaction must be rapid and the yield of the reaction must essentially be 100%. Is Kc > 1, < 1, or ≈ 1 for a titration reaction? Kc is the product of all reaction products (choose from: Multiplied by, added to, divided by, subtracted from) the product of the reactants, with all concentrations of reactants and products raised to their respective stoichiometric powers. As the titration proceeds, the amount of reactants (choose from: Increases, decreases, remains the same) and the amount of products (choose from: Increases, decreases, remains the same). Because the value of the numerator is (Choose from much greater than, much less than, approximately equal to) the value of the denominator, the value of Kc will be (Choose from much greater than, much less than, approximately equal to)1 for an effective titration reaction.arrow_forwardAnswer questions a through c: a. A CHEM 1215L student prepares a dilute solution of sodium hydroxide, NaOH(aq), starting with 6 M sodium hydroxide. She then titrates a 1.372 g sample of KHP with the dilute sodium hydroxide solution, NaOH (aq), to a phenolphthalein end point. If the titration required 21.84 mL of sodium hydroxide, NaOH(aq), calculate the molar concentration of the sodium hydroxide solution, NaOH (aq). (Remember that KHP is potassium hydrogen phthalate KHC8H4O4, NOT potassium hydrogen phosphorus!) b. The student uses the same sodium hydroxide to titrate 10.00 mL of vinegar to a phe- nolphthalein end point. If the titration required 27.48 mL of sodium hydroxide, NaOH (aq), calculate the molar concentration of acetic acid, HC2H3O2 (aq), in the vinegar. c. Calculate the mass percent of acetic acid, HC2H3O2 (aq), in the vinegar using the mo- lar concentration for acetic acid, HC2H3O2 (aq), determined in part band assuming the density of the solution is 1.01 g/mL.arrow_forward
- Topic: Acid-Base Titration a. Differentiate between acidimetry and alkalimetry? b. Define titer.arrow_forwardPyruvic acid is formed in the body from carbohydrate metabolism. In muscles, it is reduced to lactic acid in the course of exertion. The acid-dissociation constant for pyruvic acid is 3.2 * 10-3. Would you expect pyruvic acid to exist primarily as the neutral acid or as dissociated ions in muscle tissue, assuming a pH of 7.4 and an initial acid concentration of 2 * 10-4 M?arrow_forwardA solution of acetic acid CH3COOH, on a laboratory shelf was of undetermined concentration. If the pH of the solution was found to be 2.68, what was the initial concentration of the acid? Ka=1.7x10-5 Ethanolamine, HOC2H4NH2, is a viscous liquid with an ammonia-like odour used to remove hydrogen sulphide from natural gas. A 0.15 mol dm-3 aqueous solution of ethanolamine has a pH of 11.34. What is kb for ethanolamine? What is the concentration of hydroxide ion in a 0.060 mol dm-3 aqueous solution of methylamine, CH3NH2? What is the pH? Kb=4.4x10-4arrow_forward
- Which statement about acid-base indicators is not correct? * A- A weak acid can be used as an acid-base indicator provided that the chemical structures of the weak acid and its conjugate base differ slightly. B- The end point of the titration is not a specific colour but the point where one drop of acid or base from the burette changes the colour of the solution in the conical flask. C- Phenolphthalein can be used to detect the end point of the titration of a strong base with a weak acid. D- All these statements are correct. E- None of these statements are correct.arrow_forward10.0 cm³ of a solution of a strong acid with a pH of 3 is added to a volumetric flask and the total volume is made up to 1.00 dm³ by adding distilled water. The resulting solution is then thoroughly mixed. What is the pH of the diluted solution?arrow_forwardWhat will be the pH of the buffer solution consisting of 94 mL butanoic acid (CH3CH2CH2COOH) 0.189 mol/L and 109 mL sodium butanoate (CH3CH2CH2COONa) 0.207 mol/L, if 10.9 mL KOH 0.5 mol/L is added?Give an answer to at least 3 decimal places.arrow_forward
arrow_back_ios
SEE MORE QUESTIONS
arrow_forward_ios
Recommended textbooks for you
Chemistry: Principles and ReactionsChemistryISBN:9781305079373Author:William L. Masterton, Cecile N. HurleyPublisher:Cengage Learning
Principles of Modern ChemistryChemistryISBN:9781305079113Author:David W. Oxtoby, H. Pat Gillis, Laurie J. ButlerPublisher:Cengage Learning
Chemistry: Principles and PracticeChemistryISBN:9780534420123Author:Daniel L. Reger, Scott R. Goode, David W. Ball, Edward MercerPublisher:Cengage Learning
Chemistry: Principles and Reactions
Chemistry
ISBN:9781305079373
Author:William L. Masterton, Cecile N. Hurley
Publisher:Cengage Learning
Principles of Modern Chemistry
Chemistry
ISBN:9781305079113
Author:David W. Oxtoby, H. Pat Gillis, Laurie J. Butler
Publisher:Cengage Learning
Chemistry: Principles and Practice
Chemistry
ISBN:9780534420123
Author:Daniel L. Reger, Scott R. Goode, David W. Ball, Edward Mercer
Publisher:Cengage Learning
Acid-Base Titration | Acids, Bases & Alkalis | Chemistry | FuseSchool; Author: FuseSchool - Global Education;https://www.youtube.com/watch?v=yFqx6_Y6c2M;License: Standard YouTube License, CC-BY