   Chapter 14, Problem 67GQ

Chapter
Section
Textbook Problem

The decomposition of gaseous dimethyl ether at ordinary pressures is first-order. Its half-life is 25.0 minutes at 500 °C:CH3OCH3(g) → CH4(g) + CO(g) + H2(g) (a) Starting with 8.00 g of dimethyl ether, what mass remains (in grams) after 125 minutes and after 145 minutes? (b) Calculate the time in minutes required to decrease 7.60 ng (nanograms) to 2.25 ng. (c) What fraction of the original dimethyl ether remains after 150 minutes?

(a)

Interpretation Introduction

Interpretation:

For the given reaction, mass of dimethyl ether remains after 125 minutes and after 145 minutes should be calculated.

Concept introduction:

In order to establish the plausibility of a mechanism, one must compare the rate law of the rate determining step to the experimentally determined rate law.

Rate law: It is generally the rate equation that consists of the reaction rate with the concentration or the pressures of the reactants and constant parameters.

Rate determining step: In a chemical reaction the rate determining step is the slowest step in which the rate of the reaction depends on the rate of that slowest step.

Activation energy: It is defined as the minimum energy required by the reacting species in order to undergo chemical reaction.

Reaction coordinate: It is the diagrammatic representation of a chemical reaction which depicts how the reactants gets transformed into product where the transition state and the intermediates present in the reaction are also depicted.

Intermediate species: It is the species formed during the middle of the chemical reaction between the reactant and the desired product.

Arrhenius equation:

• Arrhenius equation is a formula that represents the temperature dependence of reaction rates
• The Arrhenius equation has to be represented as follows

k=AeEa/RTlnk=lnAeEa/RTlnk=(EaR)(1T)+lnA

• Ea represents the activation energy and it’s unit is kJ/mol
• R represents the universal gas constant and it has the value of 8.314 J/K.mol
• T represents the absolute temperature
• A represents the frequency factor or collision frequency
• e represents the base of natural logarithm
•  Arrhenius equation equation was proposed by Svante Arrhenius in 1889.

Rate constant: The rate constant for a chemical reaction is the proportionality term in the chemical reaction rate law which gives the relationship between the rate and the concentration of the reactant present in the chemical reaction.

Rate order: The order of each reactant in a reaction is represented by the exponential term of the respective reactant present in the rate law and the overall order of the reaction is the sum of all the exponents of all reactants present in the chemical reaction.  The order of the reaction is directly proportional to the concentration of the reactants.

Explanation

Examining the given reaction shows that it is first order reaction hence respective expression should be used.

Rate=k[CH3OCH3]k=0.0693t1/2=0.027726

lnA=kt+lnA0lnA=0

(b)

Interpretation Introduction

Interpretation:

The time required to decrease 7.60ng to 2.25ng has to be determined.

Concept introduction:

In order to establish the plausibility of a mechanism, one must compare the rate law of the rate determining step to the experimentally determined rate law.

Rate law: It is generally the rate equation that consists of the reaction rate with the concentration or the pressures of the reactants and constant parameters.

Rate determining step: In a chemical reaction the rate determining step is the slowest step in which the rate of the reaction depends on the rate of that slowest step.

Activation energy: It is defined as the minimum energy required by the reacting species in order to undergo chemical reaction.

Reaction coordinate: It is the diagrammatic representation of a chemical reaction which depicts how the reactants gets transformed into product where the transition state and the intermediates present in the reaction are also depicted.

Intermediate species: It is the species formed during the middle of the chemical reaction between the reactant and the desired product.

Arrhenius equation:

• Arrhenius equation is a formula that represents the temperature dependence of reaction rates
• The Arrhenius equation has to be represented as follows

k=AeEa/RTlnk=lnAeEa/RTlnk=(EaR)(1T)+lnA

• Ea represents the activation energy and it’s unit is kJ/mol
• R represents the universal gas constant and it has the value of 8.314 J/K.mol
• T represents the absolute temperature
• A represents the frequency factor or collision frequency
• e represents the base of natural logarithm
•  Arrhenius equation equation was proposed by Svante Arrhenius in 1889.

Rate constant: The rate constant for a chemical reaction is the proportionality term in the chemical reaction rate law which gives the relationship between the rate and the concentration of the reactant present in the chemical reaction.

Rate order: The order of each reactant in a reaction is represented by the exponential term of the respective reactant present in the rate law and the overall order of the reaction is the sum of all the exponents of all reactants present in the chemical reaction.  The order of the reaction is directly proportional to the concentration of the reactants.

(c)

Interpretation Introduction

Interpretation:

For the given reaction, fraction of the original dimethyl ether remains after 150 minutes should be calculated.

Concept introduction:

In order to establish the plausibility of a mechanism, one must compare the rate law of the rate determining step to the experimentally determined rate law.

Rate law: It is generally the rate equation that consists of the reaction rate with the concentration or the pressures of the reactants and constant parameters.

Rate determining step: In a chemical reaction the rate determining step is the slowest step in which the rate of the reaction depends on the rate of that slowest step.

Activation energy: It is defined as the minimum energy required by the reacting species in order to undergo chemical reaction.

Reaction coordinate: It is the diagrammatic representation of a chemical reaction which depicts how the reactants gets transformed into product where the transition state and the intermediates present in the reaction are also depicted.

Intermediate species: It is the species formed during the middle of the chemical reaction between the reactant and the desired product.

Arrhenius equation:

• Arrhenius equation is a formula that represents the temperature dependence of reaction rates
• The Arrhenius equation has to be represented as follows

k=AeEa/RTlnk=lnAeEa/RTlnk=(EaR)(1T)+lnA

• Ea represents the activation energy and it’s unit is kJ/mol
• R represents the universal gas constant and it has the value of 8.314 J/K.mol
• T represents the absolute temperature
• A represents the frequency factor or collision frequency
• e represents the base of natural logarithm
•  Arrhenius equation equation was proposed by Svante Arrhenius in 1889.

Rate constant: The rate constant for a chemical reaction is the proportionality term in the chemical reaction rate law which gives the relationship between the rate and the concentration of the reactant present in the chemical reaction.

Rate order: The order of each reactant in a reaction is represented by the exponential term of the respective reactant present in the rate law and the overall order of the reaction is the sum of all the exponents of all reactants present in the chemical reaction.  The order of the reaction is directly proportional to the concentration of the reactants.

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