Physical Chemistry
2nd Edition
ISBN: 9781133958437
Author: Ball, David W. (david Warren), BAER, Tomas
Publisher: Wadsworth Cengage Learning,
expand_more
expand_more
format_list_bulleted
Question
Chapter 15, Problem 15.53E
Interpretation Introduction
Interpretation:
The reason as to why the stability of azulene is attributed to internal charge separation is to be stated.
Concept introduction:
A molecule must be cyclic, planar, completely conjugated and should follow Hückel’s rule to be classified as aromatic. According to the Hückel’s rule, the number of
Expert Solution & Answer
Want to see the full answer?
Check out a sample textbook solutionStudents have asked these similar questions
Explain why the lines in the spectrum for H35Cl and H37Cl give rise to different rotational constants for the two molecules.
What is the full term symbol of the ground electronic state of Li2+?
The 3N-6 vibrational modes of a molecule can be sub-subdivided into three general types ofdeformations.(i) Define these and draw their approximate potential energy functions.
(ii) Order the three types. Start with the one requiring the least energy to animate.(iii) Where are anharmonic modes generally located in the energetic ordering relative toother modes and what other name(s) are they know by?
(iv) Discuss the significance of anharmonic modes and why accurately characterisingthem is key to precise energetic determinations and to accurately modellingspecificity, selectivity and functionality in chemical phenomena.
Chapter 15 Solutions
Physical Chemistry
Ch. 15 - Linearly polarized light can be assigned a...Ch. 15 - Linearly polarized light can be assigned a...Ch. 15 - Prob. 15.3ECh. 15 - Determine the value of R for deuterium (2H) and...Ch. 15 - Prob. 15.5ECh. 15 - Draw a Grotrian-type diagram for the first four...Ch. 15 - What is the value of the change in energy, E, for...Ch. 15 - Prob. 15.8ECh. 15 - List the possible values of L, ML, S, MS, J, and...Ch. 15 - Prob. 15.10E
Ch. 15 - Prob. 15.11ECh. 15 - Prob. 15.12ECh. 15 - Prob. 15.13ECh. 15 - What is the term symbol for the ground state of a...Ch. 15 - Prob. 15.15ECh. 15 - Prob. 15.16ECh. 15 - Prob. 15.17ECh. 15 - Prob. 15.18ECh. 15 - Prob. 15.19ECh. 15 - Prob. 15.20ECh. 15 - Prob. 15.21ECh. 15 - Prob. 15.22ECh. 15 - Use Hunds rules to predict the term symbol of the...Ch. 15 - Prob. 15.24ECh. 15 - Prob. 15.25ECh. 15 - An Mg atom is in the excited electron...Ch. 15 - Prob. 15.27ECh. 15 - Prob. 15.28ECh. 15 - Prob. 15.29ECh. 15 - Prob. 15.30ECh. 15 - Use group-theoretical arguments to determine the...Ch. 15 - The GeF molecule, which exists in the gas phase at...Ch. 15 - The SrH molecule in a 2+ electronic ground state....Ch. 15 - Prob. 15.34ECh. 15 - What are the values of and for NF in its 3...Ch. 15 - Prob. 15.36ECh. 15 - Determine the ground-state term symbol of the...Ch. 15 - Prob. 15.38ECh. 15 - Prob. 15.39ECh. 15 - Prob. 15.40ECh. 15 - Prob. 15.41ECh. 15 - Prob. 15.42ECh. 15 - The 1, 1'-diethyl-2, 2'-dicarbocyanine cation has...Ch. 15 - Prob. 15.44ECh. 15 - Naphthacene, C18H12, consists of four benzene...Ch. 15 - Prob. 15.46ECh. 15 - Prob. 15.47ECh. 15 - Construct the Hckel determinants for...Ch. 15 - Prob. 15.49ECh. 15 - Using the Internet, find a Hckel determinant...Ch. 15 - Prob. 15.51ECh. 15 - Explain why cyclopentadiene easily accepts an...Ch. 15 - Prob. 15.53ECh. 15 - Prob. 15.54ECh. 15 - Prob. 15.55ECh. 15 - Prob. 15.56ECh. 15 - Prob. 15.57ECh. 15 - Prob. 15.58ECh. 15 - Would the light from fireflies be considered an...Ch. 15 - Prob. 15.60ECh. 15 - Prob. 15.61ECh. 15 - Prob. 15.62ECh. 15 - How many 632.8-nm photons must a He-Ne laser emit...Ch. 15 - Prob. 15.64ECh. 15 - Green He-Ne lasers are also available; they emit...Ch. 15 - Blu-ray disks and high-density DVDs use an indium...Ch. 15 - Prob. 15.67ECh. 15 - Explain why X-ray lasers would be extremely...Ch. 15 - Prob. 15.69E
Knowledge Booster
Similar questions
- The SrH molecule in a 2+ electronic ground state. What are the term symbols of the electronic states that can be accessed by allowed electronic transitions?arrow_forwardWhat is the bond order for the lowest excited state of H2+ ? From this single result, propose a general statement about unstable diatomic molecules and bond orders.arrow_forwardWhat is the term symbol for the ground state of a Li, b Al,c Sc?arrow_forward
- What are the values of and for NF in its 3 ground electronic state?arrow_forwardWhat terms (expressed as S, D, etc.) can arise from the [He]2s22p 13d1 excited configuration of carbon?arrow_forwardThe UV spectrum of europium ions (Eu3+, 4f66s0) shows many peaks. Predict the term symbol for the ground state without listing all the micro states.arrow_forward
- Forcefields to model organic molecules commonly employ harmonic potentials.(i) Justify, mathematically, the use of a harmonic potential to describe the stretching ofcovalent bond.(ii) Describe another higher-order polynomial description of the stretching of acovalent bond. (iii) If you want to describe bond stretching far away from the equilibrium, what otherpotential function would you employ? Describe its advantages and disadvantagescompared with the simpler harmonic potential.arrow_forwardWhich of the fol lowing molecules can have (a) a pure rotational spectrum and (b) a rotational Raman spectrum: (i) HCI, Iii) N2O, (i ii) O3, (iv) SF4, (v) XeF4?arrow_forward
arrow_back_ios
arrow_forward_ios
Recommended textbooks for you
- Physical ChemistryChemistryISBN:9781133958437Author:Ball, David W. (david Warren), BAER, TomasPublisher:Wadsworth Cengage Learning,Principles of Modern ChemistryChemistryISBN:9781305079113Author:David W. Oxtoby, H. Pat Gillis, Laurie J. ButlerPublisher:Cengage Learning
Physical Chemistry
Chemistry
ISBN:9781133958437
Author:Ball, David W. (david Warren), BAER, Tomas
Publisher:Wadsworth Cengage Learning,
Principles of Modern Chemistry
Chemistry
ISBN:9781305079113
Author:David W. Oxtoby, H. Pat Gillis, Laurie J. Butler
Publisher:Cengage Learning