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Chemistry & Chemical Reactivity

10th Edition
John C. Kotz + 3 others
Publisher: Cengage Learning
ISBN: 9781337399074
BuyFind

Chemistry & Chemical Reactivity

10th Edition
John C. Kotz + 3 others
Publisher: Cengage Learning
ISBN: 9781337399074

Solutions

Chapter
Section
Chapter 15, Problem 37GQ
Textbook Problem

The equilibrium constant for the butane ⇄ isobutane isomerization reaction is 2.5 at 25 °C. If 1.75 mol of butane and 1.25 mol of isobutane are mixed, is the system at equilibrium? If not, when it proceeds to equilibrium, which reagent increases in concentration? Calculate the concentrations of the two compounds when the system reaches equilibrium.

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Chapter 15 Solutions

Chemistry & Chemical Reactivity
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Ch. 15.2 - Write the equilibrium constant expression for each...Ch. 15.2 - Answer the following questions regarding the...Ch. 15.3 - A solution is prepared by dissolving 0.050 mol of...Ch. 15.4 - At some temperature. Kc = 33 for the reaction...Ch. 15.4 - The decomposition of PCl5(g) to form PCl3(g) and...Ch. 15.5 - The conversion of oxygen to ozone has a very small...Ch. 15.6 - Equilibrium exists between butane and isobutane...Ch. 15.6 - Anhydrous ammonia is used directly as a...Ch. 15.6 - Hydrogen is used in the Haber-Bosch process, and...Ch. 15.6 - Freezing point depression is one means of...Ch. 15.6 - What concentration of the monomer (2) will exist...Ch. 15.6 - A 0.64 g sample of the white crystalline dimer (4)...Ch. 15.6 - Predict whether the dissociation of the dimer to...Ch. 15.6 - Which of the organic species mentioned in this...Ch. 15 - Write equilibrium constant expressions for the...Ch. 15 - Write equilibrium constant expressions for the...Ch. 15 - Kc = 5.6 1012 at 500 K for the dissociation of...Ch. 15 - The reaction 2 NO2(g) N2O4(g) has an equilibrium...Ch. 15 - A mixture of SO2, O2, and SO3 at 1000 K contains...Ch. 15 - The equilibrium constant Kc, for the reaction 2...Ch. 15 - The reaction PCl5(g) PCl3(g) + Cl2(g) was...Ch. 15 - An equilibrium mixture of SO2, O2, and SO3 at a...Ch. 15 - The reaction C(s) + CO2(g) 2 CO(g) occurs at high...Ch. 15 - Hydrogen and carbon dioxide react at a high...Ch. 15 - A mixture of CO and Cl2 is placed in a reaction...Ch. 15 - You place 0.0300 mol of pure SO3 in an 8.00-L...Ch. 15 - The value of Kc for the interconversion of butane...Ch. 15 - Cyclohexane, C6H12, a hydrocarbon, can isomerize...Ch. 15 - The equilibrium constant for the dissociation of...Ch. 15 - The equilibrium constant, Kc, for the reaction...Ch. 15 - Carbonyl bromide decomposes to carbon monoxide and...Ch. 15 - Iodine dissolves in water, but its solubility in a...Ch. 15 - Which of the following correctly relates the...Ch. 15 - Which of the following correctly relates the...Ch. 15 - Consider the following equilibria involving SO2(g)...Ch. 15 - The equilibrium constant K for the reaction CO2(g)...Ch. 15 - Calculate K for the reaction SnO2(s) + 2 CO(g) ...Ch. 15 - Calculate K for the reaction Fe(s) + H2O(g) ...Ch. 15 - Relationship of Kc and Kp: (a) Kp for the...Ch. 15 - Relationship of Kc and Kp: (a) The equilibrium...Ch. 15 - Dinitrogen trioxide decomposes to NO and NO2, in...Ch. 15 - Kp for the following reaction is 0.16 at 25 C: 2...Ch. 15 - Consider the isomerization of butane with an...Ch. 15 - The decomposition of NH4HS NH4HS(s) NH3(g) +...Ch. 15 - Suppose 0.086 mol of Br2 is placed in a 1.26-L...Ch. 15 - The equilibrium constant for the reaction N2(g) +...Ch. 15 - Kp for the formation of phosgene, COCl2, is 6.5 ...Ch. 15 - The equilibrium constant, Kc, for the following...Ch. 15 - Carbon tetrachloride can be produced by the...Ch. 15 - Equal numbers of moles of H2 gas and I2 vapor are...Ch. 15 - The equilibrium constant for the butane isobutane...Ch. 15 - At 2300 K the equilibrium constant for the...Ch. 15 - Which of the following correctly relates the two...Ch. 15 - Consider the following equilibrium: COBr2(g) ...Ch. 15 - Heating a metal carbonate leads to decomposition....Ch. 15 - Phosphorus pentachloride decomposes at elevated...Ch. 15 - Ammonium hydrogen sulfide decomposes on heating....Ch. 15 - Ammonium iodide dissociates reversibly to ammonia...Ch. 15 - When solid ammonium carbamate sublimes, it...Ch. 15 - In the gas phase, acetic acid exists as an...Ch. 15 - Assume 3.60 mol of ammonia is placed in a 2.00-L...Ch. 15 - The total pressure for a mixture of N2O4 and NO2...Ch. 15 - Kc for the decomposition of ammonium hydrogen...Ch. 15 - COCl2 decomposes to CO and Cl2 at high...Ch. 15 - A 15-L flask at 300 K contains 6.44 g of a mixture...Ch. 15 - Lanthanum oxalate decomposes when heated to...Ch. 15 - The reaction of hydrogen and iodine to give...Ch. 15 - Sulfuryl chloride, SO2Cl2 is used as a reagent in...Ch. 15 - Hemoglobin (Hb) can form a complex with both O2...Ch. 15 - Limestone decomposes at high temperatures....Ch. 15 - At 1800 K, oxygen dissociates very slightly into...Ch. 15 - Nitrosyl bromide, NOBr, dissociates readily at...Ch. 15 - A Boric acid and glycerin form a complex...Ch. 15 - The dissociation of calcium carbonate has an...Ch. 15 - A sample of N2O4 gas with a pressure of 1.00 atm...Ch. 15 - A reaction important in smog formation is O3(g) +...Ch. 15 - The photograph below shows what occurs when a...Ch. 15 - The photographs below (a) show what occurs when a...Ch. 15 - Decide whether each of the following statements is...Ch. 15 - Neither PbCl2 nor PbF2 is appreciably soluble in...Ch. 15 - Characterize each of the following as product- or...Ch. 15 - The size of a flask containing colorless N2O4(g)...Ch. 15 - Describe an experiment that would allow you to...Ch. 15 - The chapter opening photograph (page 670) showed...Ch. 15 - Suppose a tank initially contains H2S at a...Ch. 15 - Pure PCl5 gas is placed in a 2.00-L flask. After...

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