Chemistry
4th Edition
ISBN: 9780078021527
Author: Julia Burdge
Publisher: McGraw-Hill Education
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Textbook Question
Chapter 15.5, Problem 1PPA
Practice Problem
ATTEMPT
Write K? expressions for
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Hydrogen iodide gas is formed from its elements with a value for Kp = 25.5 at a certain temperature:
H2 (g) + I2 (g) <---> 2 HI (g)
What will the equilibrium pressure (in atm) of hydrogen iodide gas be if the initial partial pressure of both reactant gases is 0.150 atm?
(answer in 3 significant figures)
For the equilibrium A + B ⇌ C + D K was measured to be 1.51 × 10⁻² at 25°C and 15.0 at 600°C. What is ∆S° for the reaction? Assume ∆H° and ∆S° are temperature independent. Answer in J/mol x K
Chemistry
Find ΔHfus for water
Mass of cup and warm water: 45.67 gFinal mass of cup, water, and melted ice: 69.76 gMass of empty cup: 2.21 gTemperature of warm water: 63 °CTemperature of ice: 0 °CTemperature at equilibrium: 45.2 °C
Chapter 15 Solutions
Chemistry
Ch. 15.1 - Practice Problem ATTEMPT
In an analysis of the...Ch. 15.1 - Prob. 1PPBCh. 15.1 - Practice Problem CONCEPTUALIZE
Consider the...Ch. 15.2 - Practice ProblemATTEMPT Write the reaction...Ch. 15.2 - Practice Problem BUILD
Write the equation for the...Ch. 15.2 - Practice ProblemCONCEPTUALIZE In principle, in the...Ch. 15.2 - Select the correct equilibrium expression for the...Ch. 15.2 - Prob. 2CPCh. 15.3 - Practice Problem ATTEMPT Write equilibrium...Ch. 15.3 - Practice Problem BUILD
Which of the following...
Ch. 15.3 - Prob. 1PPCCh. 15.3 - Prob. 1CPCh. 15.3 - Prob. 2CPCh. 15.3 - Given the following information: HF ( a q ) ⇄ H +...Ch. 15.3 - Prob. 4CPCh. 15.4 - Practice ProblemATTEMPT The following reactions...Ch. 15.4 - Practice Problem BUILD
The equation represents a...Ch. 15.4 - Practice ProblemCONCEPTUALIZE Consider a chemical...Ch. 15.4 - Use the following information to answer questions...Ch. 15.4 - Prob. 2CPCh. 15.4 - 15.4.3 If for the reaction at a certain...Ch. 15.4 - If K c = 3 for the reaction X + 2Y ⇄ Z at a...Ch. 15.5 - Practice ProblemATTEMPT Write K? expressions for (...Ch. 15.5 - Prob. 1PPBCh. 15.5 - Prob. 1PPCCh. 15.5 - Prob. 1CPCh. 15.5 - Prob. 2CPCh. 15.5 - Prob. 3CPCh. 15.5 - Prob. 4CPCh. 15.5 - Prob. 5CPCh. 15.5 - Prob. 6CPCh. 15.6 - Practice Problem ATTEMPT
For the reaction:
....Ch. 15.6 - Practice ProblemBUILD K p = 2.79 × 10 − 5 for the...Ch. 15.6 - Practice Problem CONCEPTUALIZE
Consider the...Ch. 15.7 - Prob. 1PPACh. 15.7 - Prob. 1PPBCh. 15.7 - Prob. 1PPCCh. 15.8 - Practice ProblemATTEMPT Calculate the equilibrium...Ch. 15.8 - Practice ProblemBUILD Determine the initial...Ch. 15.8 - Practice Problem CONCEPTUALIZE
Consider the...Ch. 15.9 - Prob. 1PPACh. 15.9 - Prob. 1PPBCh. 15.9 - Prob. 1PPCCh. 15.10 - Practice ProblemATTEMPT Aqueous hydrocyanic acid...Ch. 15.10 - Practice Problem BUILD Consider a weak acid, HA,...Ch. 15.10 - Practice ProblemCONCEPTUALIZE Each of the...Ch. 15.11 - Practice Problem ATTEMPT Determine the equilibrium...Ch. 15.11 - Prob. 1PPBCh. 15.11 - Prob. 1PPCCh. 15.12 - Practice ProblemATTEMPT For each change indicated,...Ch. 15.12 - Prob. 1PPBCh. 15.12 - Practice ProblemCONCEPTUALIZE Consider the...Ch. 15.13 - Practice Problem ATTEMPT
For each reaction,...Ch. 15.13 - Practice Problem BUILD
For the following...Ch. 15.13 - Practice Problem CONCEPTUALIZE
Consider the...Ch. 15.14 - Practice Problem ATTEMPT
The reaction of carbon...Ch. 15.14 - Practice Problem BUILD
Consider the hypothetical...Ch. 15.14 - Practice Problem CONCEPTUALIZE
The decomposition...Ch. 15 - The K a for hydrocyanic acid ( HCN ) is 4 .9 × 10...Ch. 15 - 15.2
Determine the concentrations of in a...Ch. 15 - 15.3
Determine the for a weak acid if a 0.10-M...Ch. 15 - Prob. 4KSPCh. 15 - Define equilibrium. Give two examples of a dynamic...Ch. 15 - 15.2 Which of the following statements is correct...Ch. 15 - 15.3 Consider the reversible reaction Explain how...Ch. 15 - What is the law of mass action?Ch. 15 - Briefly describe the importance of equilibrium in...Ch. 15 - Define reaction quotient. How does it differ from...Ch. 15 - Write reaction quotients for the following...Ch. 15 - Write the equation for the reaction that...Ch. 15 - Consider the reaction: 2NO ( g ) + 2H 2 ( g ) ⇄ N...Ch. 15 - The equilibrium constant for the reaction: 2SO 2 (...Ch. 15 - Consider the following equilibrium process at...Ch. 15 - The equilibrium constant for the reaction: 2 H 2 (...Ch. 15 - The first diagram represents a system at...Ch. 15 - These two diagrams represent systems at...Ch. 15 - Define homogeneous equilibrium and heterogeneous...Ch. 15 - What do the symbols K c and K p represent?Ch. 15 - Write the expressions for the equilibrium...Ch. 15 - Write equilibrium constant expressions for K c ,...Ch. 15 - Write the equilibrium constant expressions for K c...Ch. 15 - 15.20 Write the equation relating to , and define...Ch. 15 - 15.21 The equilibrium constant () for the...Ch. 15 - What is K p at 1273°C for the reaction 2CO ( g ) +...Ch. 15 - 15.23 The equilibrium constant for the...Ch. 15 - 15.24 Consider the reaction:
If the equilibrium...Ch. 15 - 15.25 A reaction vessel contains at equilibrium...Ch. 15 - 15.26 The equilibrium constant Kc for the...Ch. 15 - At equilibrium, the pressure of the reacting...Ch. 15 - The equilibrium constant K p for the reaction: PCl...Ch. 15 - Ammonium carbamate ( NH 4 CO 2 NH 2 ) decomposes...Ch. 15 - The following equilibrium constants were...Ch. 15 - 15.31 At a certain temperature, the following...Ch. 15 - 15.32 Pure phosgene gas , was placed in a 1.50-L...Ch. 15 - Consider the equilibrium: 2 NOBr( g ) ⇄ 2 NO( g...Ch. 15 - The following equilibrium constants have been...Ch. 15 - 15.35 The following equilibrium constants have...Ch. 15 - 15.36 The equilibrium constant for the reaction at...Ch. 15 - The following diagrams represent the equilibrium...Ch. 15 - 15.38 Outline the steps for calculating the...Ch. 15 - 15.39 The equilibrium constant K? for the...Ch. 15 - 15.40 For the synthesis of ammonia:
the...Ch. 15 - For the reaction: H 2 ( g ) + CO 2 ( g ) ⇄ H 2 O (...Ch. 15 - At 1000 K, a sample of pure NO, gas decomposes:...Ch. 15 - The equilibrium constant K c for the reaction H 2...Ch. 15 - The dissociation of molecular iodine into iodine...Ch. 15 - The equilibrium constant Kc for the decomposition...Ch. 15 - 15.46 Consider the following equilibrium process...Ch. 15 - 15.47 Consider the heterogeneous equilibrium...Ch. 15 - The equilibrium constant K c for the reaction: H 2...Ch. 15 - The aqueous reaction: L-glutamate + pyruvate ⇄...Ch. 15 - 15.50 Explain Le Châtelier’s principle. How does...Ch. 15 - Use Le Chatelier's principle to explain why the...Ch. 15 - 15.52 List four factors that can shift the...Ch. 15 - Does the addition of a catalyst have any effects...Ch. 15 - 15.54 Consider the following equilibrium system...Ch. 15 - 15.55 Heating solid sodium bicarbonate in a closed...Ch. 15 - 15.56 Consider the following equilibrium...Ch. 15 - 15.57 What effect does an increase in pressure...Ch. 15 - Prob. 58QPCh. 15 - Consider the following equilibrium process: PCl 5...Ch. 15 - Consider the reaction: 2SO 2 ( g ) ⇄ 2 SO 3 ( g )...Ch. 15 - In the uncatalyzed reaction: N 2 O 4 ( g ) ⇄ 2 NO...Ch. 15 - 15.62 Consider the gas-phase reaction:
Predict...Ch. 15 - Consider the following equilibrium reaction in a...Ch. 15 - 15.64 The following diagrams show the reaction at...Ch. 15 - 15.65 The following diagrams show an equilibrium...Ch. 15 - 15.66 Consider the reaction . The first diagram...Ch. 15 - Prob. 67APCh. 15 - Consider the equilibrium system 3A → B . Sketch...Ch. 15 - Baking soda (sodium bicarbonate) undergoes thermal...Ch. 15 - Consider the following reaction at equilibrium: A...Ch. 15 - Prob. 71APCh. 15 - 15.72 Consider the following reacting...Ch. 15 - 15.73 At a certain temperature and a total...Ch. 15 - The decomposition of ammonium hydrogen sulfide: N...Ch. 15 - 15.75 Consider the following reaction at a certain...Ch. 15 - When heated, ammonium carbamate decomposes as...Ch. 15 - A mixture of 0 .47 mole of H2 and 3 .59 moles of...Ch. 15 - When heated at high temperatures, iodine vapor...Ch. 15 - 15.79 One mole of and three moles of are placed...Ch. 15 - At 1130°C , the equilibrium constant ( K c ) for...Ch. 15 - For the purpose of determining K p using Equation...Ch. 15 - The following diagram represents a gas-phase...Ch. 15 - 15.83 Consider the following reaction at
When...Ch. 15 - 15.84 A quantity of 0.20 mole of carbon dioxide...Ch. 15 - 15.85 When dissolved in water, glucose (com sugar)...Ch. 15 - 15 86 At room temperature, solid iodine is in...Ch. 15 - 15.87 A student placed a few ice cubes in a...Ch. 15 - 15.88 A mixture containing 3.9 moles of and 0.88...Ch. 15 - 15.89 The equilibrium constant for the...Ch. 15 - When heated, a gaseous compound A dissociates as...Ch. 15 - 15.91 When a gas was heated under atmospheric...Ch. 15 - The first diagram represents a system at...Ch. 15 - A sealed glass bulb contains a mixture of NO 2 and...Ch. 15 - At 20°C , the vapor pressure of water is 0.0231...Ch. 15 - A 2.50-mol sample of NOCl was initially in a...Ch. 15 - 15.96 About 75 percent of hydrogen for industrial...Ch. 15 - Water is a very weak electrolyte that undergoes...Ch. 15 - 15.98 Consider the following reaction, which takes...Ch. 15 - The equilibrium constant Kc for the reaction: 2NH...Ch. 15 - At 25°C, a mixture of NO 2 and N 2 O 4 gases are...Ch. 15 - 15.101 Consider the reaction between and in a...Ch. 15 - In 1899 the German chemist Ludwig Mond developed a...Ch. 15 - For which of the following reactions is K c equal...Ch. 15 - The equilibrium constant K p for the following...Ch. 15 - At 1024°C, , the pressure of oxygen gas from the...Ch. 15 - 15.06 The equilibrium constant for the following...Ch. 15 - 15.107 Industrially, sodium metal is obtained by...Ch. 15 - Consider the equilibrium reaction described in...Ch. 15 - The K p for the reaction: SO 2 Cl 2 ( g ) ⇄ SO 2 (...Ch. 15 - The "boat" form and the “chair" form of...Ch. 15 - A quantity of 6.75 g of SO 2 Cl 2 was placed in a...Ch. 15 - 15.112 Industrial production of ammonia from...Ch. 15 - 15.113 The equilibrium constant for the formation...Ch. 15 - Consider the reaction: 2NO( g )+ O 2 ( g ) ⇄ 2N O...Ch. 15 - The formation of SO 3 from SO 2 and O 2 is an...Ch. 15 - At 25°C , the equilibrium partial pressures of N O...Ch. 15 - 15.117 The vapor pressure of mercury is 0.0020...Ch. 15 - 15.118 Both ' and are important biological ions....Ch. 15 - Photosynthesis can be represented by: 6C O 2 ( g...Ch. 15 - Consider the decomposition of ammonium chloride at...Ch. 15 - 15.121 Eggshells are composed mostly of calcium...Ch. 15 - In the gas phase, nitrogen dioxide is actually a...Ch. 15 - Consider the potential-energy diagrams for two...Ch. 15 - Iodine is sparingly soluble in water but much more...Ch. 15 - The dependence of the equilibrium constant of a...Ch. 15 - Lime ( CaO ) is used to prevent SO 2 from escaping...Ch. 15 - Lime is used to prevent from escaping from the...Ch. 15 - Lime ( CaO ) is used to prevent SO 2 from escaping...Ch. 15 - Lime ( CaO ) is used to prevent SO 2 from escaping...
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- Please HELP!!! Need correct solution. The equilibrium constant for the chemical equation N₂(g) + 3H₂(g) = 2NH₂(g) is Kp = 0.0328 at 201 C. Calculate the value of K, for the reaction at 201 ˚C.arrow_forward#7 Be sure to answer all parts. Calculate Kp for the following equilibrium: 3 O2(g) ⇌ 2 O3(g) Kc =1.8×10 −56 at 475 K Answer= ____x10____arrow_forwardThe reaction of bromine gas with chlorine gas, Br2(g) + Cl2(g) ⇄ 2 BrCl(g), has a Kp value of 7.20. If 0.400 atm of both Br2 and Cl2 are placed in a closed vessel and allowed to come to equilibrium, what is the equilibrium partial pressure of BrCl(g)? (answer in atm and no scientific notation)arrow_forward
- Consider the following equilibrium: N2O4(g) ⇄2NO2(g). If Kp = 0.144 at 950.0 K, calculate Kc. (no scientific notation)arrow_forwardWhich of the following does not represent a homogeneous equilibrium? [Select all that apply] Group of answer choices N2O4 (g) ⇄ 2 NO2 (g) N2 (g) + 3 H2 (g) ⇄ 2 NH3 (g) CaCO3 (s) ⇄ CaO (s) + CO2 (g) H2 (g) + I2 (g) ⇄ 2 HI (g) Co (s) + 2H+ (aq) ⇄ Co2+ (aq) + H2 (g)arrow_forwardGaseous hydrogen iodide is placed in a closed container at 425 ∘C ∘ C , where it partially decomposes to hydrogen and iodine: 2HI(g)←→H2(g)+I2(g) 2 H I ( g ) ← → H 2 ( g ) + I 2 ( g ) . At equilibrium it is found that [HI]= [ H I ] = 3.51×10−3 M M , [H2]= [ H 2 ] = 4.76×10−4 M M , and [I2]= [ I 2 ] What is the value of KcKc at this temperature? Please provide only typed answer solution no handwritten solution needed allowedarrow_forward
- The equilibrium constant with respect to concentration (Kc) for the reaction between nitrogen monoxide and oxygen gas to produce nitrogen dioxide is 5.4 x 1013 at 25°C. What is the value of the equilibrium constant with respect to partial pressures (Kp) under these same conditions? (answer in 2 significant figures)arrow_forwardCalculate T (in K) given ΔG^0= -19.4 kJ/mol and ΔH^0= 69.9 kJ/mol and ΔS^0= 253 J/mol KΔG^0=ΔH^0−TΔS^0 A) 706 B) 1,760 C) 353 D) 0.353 E) 118arrow_forwardThe Kp for the reaction A (g) ⇌ 2 B (g) is 0.0730. What is Kp for the reaction 4 B (g) ⇌ 2 A (g)? Answer numericla ______arrow_forward
- for the equilibrium 2SO3(g) 2SO2(g) + O2(g), Kc is 4.08×10-3 at 1000 K.Calculate the value for Kp.arrow_forwardCalculate K for the following reaction 2 Fe2+ (aq) + Zr (s) ⟶ 2 Fe(s) + Zr4+ (aq) Zr4+(aq) + 4 e- ⟶ Zr(s); Eo = -1.539 VFe2+(aq) + 2 e- ⟶ Fe(s) Eo = -0.447 V Group of answer choices 7.80x1036 2.79x1018 no correct answer 6.08x1073 2.39x107arrow_forwardSolve all part please. Consider the equilibrium reaction N2O4 (g) ⇌ 2 NO2 (g)a. Using appendix C, find H and S for this reaction (you will need this for b,c). delta s= 176.6J delta H=5802kJb. Knowing that K is temperature dependent and that G = -RTlnK, find the equilibrium constant (K) and T whenthe above reaction is at equilibrium with PNO2 = PN2O4 = 1.0 atm.c. Knowing that K is temperature dependent and that G = -RTlnK, find the equilibrium constant (K) and T whenthe above reaction is at equilibrium with PT = 10.0 atm and PNO2 = 2 PN2O4.arrow_forward
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