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ChemistryIntroductory Chemistry: A Foundation9th Edition

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Chapter 16, Problem 29QAP
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Introductory Chemistry: A Foundati...

9th Edition
Steven S. Zumdahl + 1 other
ISBN: 9781337399425

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Introductory Chemistry: A Foundati...

9th Edition
Steven S. Zumdahl + 1 other
ISBN: 9781337399425
Textbook Problem
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. What is meant by the iou-product constant for water, KW?

What does this constant signify? Write an equation for the chemical reaction from which the constant is derived.

Chapter 16, Problem 29QAP, . What is meant by the iou-product constant for water, KW? What does this constant signify? Write an

Interpretation Introduction

Interpretation:

The ion-product constant for water Kw should be defined along with the significance of this constant. An equation for a chemical reaction should be determined from which Kw is derived.

Concept Introduction:

Water is an amphoteric in nature implies it can act as an acid as well as base.

Ionization of water is given as:

H2O(l)+H2O(l)⇀↽H+(aq)+OH−(aq)

Here, one water molecule is act as an acid by accepting proton and another molecule of water act as a base by donating proton.

At 25°C, the actual concentrations of the products are:

[H+][OH−]=1×10−14

The mathematical product of both [H+] and [OH−] concentrations are always constant known as ion product constant ( Kw )

[H+][OH−]=1×10−14=Kw.

Explanation

H2O(l)+H2O(l)⇀↽H+(aq)+OH−(aq)

Ion-product product constant for water is equal to the product of hydrogen ion concentration and hydroxide ion concentration and the value of ion- product constant is equal to 1×10−14 at 25°C. This is denoted by Kw

[H+][OH−]=1×10−14=Kw

With increase in temperature, concentration of hydrogen ion and concentration of hydroxide increases and due to increase in concentration of both ions, value of ion- product constant also increases

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Sect-16.1 P-16.1SCSect-16.2 P-1CTSect-16.3 P-16.2SCSect-16.4 P-16.3SCSect-16.4 P-1CTSect-16.4 P-16.4SCSect-16.4 P-16.5SCSect-16.4 P-16.6SCSect-16.5 P-16.7SCCh-16 P-1ALQ
Ch-16 P-2ALQCh-16 P-3ALQCh-16 P-4ALQCh-16 P-5ALQCh-16 P-6ALQCh-16 P-7ALQCh-16 P-8ALQCh-16 P-9ALQCh-16 P-10ALQCh-16 P-11ALQCh-16 P-12ALQCh-16 P-13ALQCh-16 P-14ALQCh-16 P-15ALQCh-16 P-16ALQCh-16 P-17ALQCh-16 P-1QAPCh-16 P-2QAPCh-16 P-3QAPCh-16 P-4QAPCh-16 P-5QAPCh-16 P-6QAPCh-16 P-7QAPCh-16 P-8QAPCh-16 P-9QAPCh-16 P-10QAPCh-16 P-11QAPCh-16 P-12QAPCh-16 P-13QAPCh-16 P-14QAPCh-16 P-15QAPCh-16 P-16QAPCh-16 P-17QAPCh-16 P-18QAPCh-16 P-19QAPCh-16 P-20QAPCh-16 P-21QAPCh-16 P-22QAPCh-16 P-23QAPCh-16 P-24QAPCh-16 P-25QAPCh-16 P-26QAPCh-16 P-27QAPCh-16 P-28QAPCh-16 P-29QAPCh-16 P-30QAPCh-16 P-31QAPCh-16 P-32QAPCh-16 P-33QAPCh-16 P-34QAPCh-16 P-35QAPCh-16 P-36QAPCh-16 P-37QAPCh-16 P-38QAPCh-16 P-39QAPCh-16 P-40QAPCh-16 P-41QAPCh-16 P-42QAPCh-16 P-43QAPCh-16 P-44QAPCh-16 P-45QAPCh-16 P-46QAPCh-16 P-47QAPCh-16 P-48QAPCh-16 P-49QAPCh-16 P-50QAPCh-16 P-51QAPCh-16 P-52QAPCh-16 P-53QAPCh-16 P-54QAPCh-16 P-55QAPCh-16 P-56QAPCh-16 P-57QAPCh-16 P-58QAPCh-16 P-59QAPCh-16 P-60QAPCh-16 P-61QAPCh-16 P-62QAPCh-16 P-63QAPCh-16 P-64QAPCh-16 P-65APCh-16 P-66APCh-16 P-67APCh-16 P-68APCh-16 P-69APCh-16 P-70APCh-16 P-71APCh-16 P-72APCh-16 P-73APCh-16 P-74APCh-16 P-75APCh-16 P-76APCh-16 P-77APCh-16 P-78APCh-16 P-79APCh-16 P-80APCh-16 P-81APCh-16 P-82APCh-16 P-83APCh-16 P-84APCh-16 P-85APCh-16 P-86APCh-16 P-87APCh-16 P-88APCh-16 P-89APCh-16 P-90APCh-16 P-91APCh-16 P-92APCh-16 P-93APCh-16 P-94APCh-16 P-95APCh-16 P-96APCh-16 P-97APCh-16 P-98APCh-16 P-99APCh-16 P-100APCh-16 P-101APCh-16 P-102APCh-16 P-103APCh-16 P-104APCh-16 P-105APCh-16 P-106CPCh-16 P-107CPCh-16 P-108CP

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