The reaction of production of hydrogen cyanide is given. If high temperature is required for thermodynamic or kinetic reasons is to be explained. Concept introduction: The expression for free energy change is, Δ G = Δ H − T Δ S A reaction is said to be spontaneous if the value of Δ G is negative. The sign of entropy depends on the number of moles. If number of moles decreases, then sign of the entropy will be negative whereas, if the number of moles increases, the sign of entropy will be positive.

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Answer 1

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Chapter 16, Problem 52E

Interpretation Introduction

Interpretation: The reaction of production of hydrogen cyanide is given. If high temperature is required for thermodynamic or kinetic reasons is to be explained.

Concept introduction: The expression for free energy change is,

ΔG=ΔH−TΔS

A reaction is said to be spontaneous if the value of ΔG is negative.

The sign of entropy depends on the number of moles. If number of moles decreases, then sign of the entropy will be negative whereas, if the number of moles increases, the sign of entropy will be positive.

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Answer 2

Question

Chapter 16, Problem 52E

Interpretation Introduction

Interpretation: The reaction of production of hydrogen cyanide is given. If high temperature is required for thermodynamic or kinetic reasons is to be explained.

Concept introduction: The expression for free energy change is,

ΔG=ΔH−TΔS

A reaction is said to be spontaneous if the value of ΔG is negative.

The sign of entropy depends on the number of moles. If number of moles decreases, then sign of the entropy will be negative whereas, if the number of moles increases, the sign of entropy will be positive.

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Answer 3

Question

Chapter 16, Problem 52E

Interpretation Introduction

Interpretation: The reaction of production of hydrogen cyanide is given. If high temperature is required for thermodynamic or kinetic reasons is to be explained.

Concept introduction: The expression for free energy change is,

ΔG=ΔH−TΔS

A reaction is said to be spontaneous if the value of ΔG is negative.

The sign of entropy depends on the number of moles. If number of moles decreases, then sign of the entropy will be negative whereas, if the number of moles increases, the sign of entropy will be positive.

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Answer 4

Question

Chapter 16, Problem 52E

Interpretation Introduction

Interpretation: The reaction of production of hydrogen cyanide is given. If high temperature is required for thermodynamic or kinetic reasons is to be explained.

Concept introduction: The expression for free energy change is,

ΔG=ΔH−TΔS

A reaction is said to be spontaneous if the value of ΔG is negative.

The sign of entropy depends on the number of moles. If number of moles decreases, then sign of the entropy will be negative whereas, if the number of moles increases, the sign of entropy will be positive.

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Answer 5

Chapter 16, Problem 52E

Interpretation Introduction

Interpretation: The reaction of production of hydrogen cyanide is given. If high temperature is required for thermodynamic or kinetic reasons is to be explained.

Concept introduction: The expression for free energy change is,

ΔG=ΔH−TΔS

A reaction is said to be spontaneous if the value of ΔG is negative.

The sign of entropy depends on the number of moles. If number of moles decreases, then sign of the entropy will be negative whereas, if the number of moles increases, the sign of entropy will be positive.

Answer 6

Chapter 16, Problem 52E

Interpretation Introduction

Interpretation: The reaction of production of hydrogen cyanide is given. If high temperature is required for thermodynamic or kinetic reasons is to be explained.

Concept introduction: The expression for free energy change is,

ΔG=ΔH−TΔS

A reaction is said to be spontaneous if the value of ΔG is negative.

The sign of entropy depends on the number of moles. If number of moles decreases, then sign of the entropy will be negative whereas, if the number of moles increases, the sign of entropy will be positive.

Answer 7

Chapter 16, Problem 52E

Interpretation Introduction

Interpretation: The reaction of production of hydrogen cyanide is given. If high temperature is required for thermodynamic or kinetic reasons is to be explained.

Concept introduction: The expression for free energy change is,

ΔG=ΔH−TΔS

A reaction is said to be spontaneous if the value of ΔG is negative.

The sign of entropy depends on the number of moles. If number of moles decreases, then sign of the entropy will be negative whereas, if the number of moles increases, the sign of entropy will be positive.

Answer 8

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Answer 9

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Answer 10

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Answer 11

Ch. 16 - Define the following: a. spontaneous process b....Ch. 16 - What is the second law of thermodynamics? For any...Ch. 16 - Prob. 3RQ Ch. 16 - Prob. 4RQ Ch. 16 - Prob. 5RQ Ch. 16 - What is the standard free energy change, G, for a...Ch. 16 - If you calculate a value for G for a reaction...Ch. 16 - Consider the equation G = G + RT ln(Q). What is...Ch. 16 - Even if G is negative, the reaction may not occur....Ch. 16 - Prob. 10RQ

Solution Summary: The author explains that the reaction of production of hydrogen cyanide is thermodynamically favored at any temperature. High temperature is required for kinetic reasons.

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