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(a)
Interpretation:
The structural formula of 2-Aminoethanol should be written.
Concept Introduction:
The arrangement of atoms present in the molecule of a compound with
(b)
Interpretation:
The structural formula of Diphenylamine should be written.
Concept Introduction:
Amine is a class of organic compounds which is derived by the replacement of one or more hydrogen atoms of ammonia molecule (NH3 ) with an alkyl group. It is a functional group having nitrogen atom with a lone pair.
The arrangement of atoms present in the molecule of a compound with chemical bonding or representation of molecular formula shows the arrangement of atoms is known structural formula.
(c)
Interpretation:
The structural formula of Diisopropylamine should be written.
Concept Introduction:
Amine is a class of organic compounds which is derived by the replacement of one or more hydrogen atoms of ammonia molecule (NH3 ) with an alkyl group. It is a functional group having nitrogen atom with a lone pair.
The arrangement of atoms present in the molecule of a compound with chemical bonding or representation of molecular formula shows the arrangement of atoms is known structural formula.
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Chapter 16 Solutions
Introduction to General, Organic and Biochemistry
- Problem 16-1 How many hydrogen atoms does pyrrolidine have? How many does purine have? Write the xnolecular formula of each amine.arrow_forwardProblem 16-4 Select the stronger base from each pair of amines.arrow_forwardProblem 17-7 Identify all hemiacetals and acetals in the following structures and tell whether each is formed from an aldehyde or a ketone. OH (a) (b) CH3OCH2CH2OCH3 (c)arrow_forward
- Problem 19-2 Complete the equation for each hydrolysis reaction. Draw all products as they are ionized under these experimental conditions.arrow_forwardProblem 15-4 3-Amino-2-butanol has two stereocenters (carbons 2 and 3); thus, 22 = 4 stereoisomers are possible for it. 'CHa H-“C-OH 3I h2n—c— h 4ch3 ch3 H-C-OH I H —C—NH2 ch3 ch3 HO-C-H I H — C— NH2 ch3 ch3 HO-C-H I H,N—C-H ch3 Which stereoisomers are pairs of enantiomers? Which sets of stereoisomers are diastereomers?arrow_forward18-4 Answer true or false. (a) The functional groups of a carboxylic acid are a carbonyl group bonded to a hydroxyl group. (b) The VSEPR model predicts bond angles of 180° about the carbonyl carbon of a carboxyl group. (c) The VSEPR model predicts bond angles of 109.5° about the oxygen of the OH group of a carboxyl group. (d) The carbonyl carbon of a carboxyl group can be a stereocenter, depending on its location within a molecule. (e) Carboxylic acids can be prepared by chromic acid oxidation of primary alcohols and of aldehydes. (f) The product of chromic acid oxidation of hexanoic acid is 1-hexanol.arrow_forward
- Problem 17-6 Show the reaction of benzaldehyde with one molecule of methanol to form a hemiacetal and then with a second molecule of methanol to form an acetal.arrow_forwardProblem 12-5 How many stereoisomers are possible for the following unsaturated alcohol? ch3 ch3 ch3 ch3c=chch2ch2c=chch2ch2c=chch2oharrow_forward18-14 Answer true or false. (a) Carboxylic acids are polar compounds. (b) The most polar bond of a carboxyl group is the C—O single bond. (c) Carboxylic acids have signi?cantly higher boiling points than aldehydes, kebones, and alcohols of comparable molecular weight. (d) The low-molecular-weight carboxylic acids (formic, acetic, propanoic, and butanoic acids) are in?nitely soluble in water. (e) The following compounds are arranged in order of increasing boiling point:arrow_forward
Introduction to General, Organic and BiochemistryChemistryISBN:9781285869759Author:Frederick A. Bettelheim, William H. Brown, Mary K. Campbell, Shawn O. Farrell, Omar TorresPublisher:Cengage Learning