Chemistry & Chemical Reactivity
10th Edition
ISBN: 9781337399074
Author: John C. Kotz, Paul M. Treichel, John Townsend, David Treichel
Publisher: Cengage Learning
expand_more
expand_more
format_list_bulleted
Videos
Textbook Question
Chapter 17, Problem 111IL
You have a solution that contains AgNO3, Pb(NO3)2, and Cu(NO3)2. Devise a separation method that results in having Ag+ in one test tube, Pb2+ in another, and Cu2+ in a third test tube. Use solubility guidelines and Ksp and Kf values.
Expert Solution & Answer
Trending nowThis is a popular solution!
Students have asked these similar questions
0.250 g sample of impure CaCl2 is titrated with 40.00 mL 0.105 M AgNO3 solution. Calculate the purity of the sample and the amount of AgCl precipitated at the end. (CaCl2 = 111g/mole AgCl = 143.5 g/mole)
For the chemical reaction that occurs when the precipitate forms,
write a balanced, net-ionic equation for the reaction, and
explain why the reaction is best represented by a net-ionic equation.
Explain the purpose of drying and weighing the filter paper with the precipitate three times.
In the filtrate solution, is [K+] greater than, less than, or equal to [NO3−] ? Justify your answer.
Calculate the number of moles of precipitate that is produced in the experiment.
Calculate the mass percent of I− in the tablet.
In another trial, the student dissolves a tablet in 55.0 mL of water instead of 50.0 mL of water. Predict whether the experimentally determined mass percent of I− will be greater than, less than, or equal to the amount calculated in part (e). Justify your answer.
A student in another lab also wants to determine the I− content of a KI tablet but does not have access to Pb(NO3)2 . However, the student does have access to 0.20 M AgNO3 , which reacts with I−(aq)…
The lead in a 0.2000-g sample is precipitated as PbCrO4. The precipitate is filtered, washed, and dissolved in acid giving a solution containing dichromate ions and lead ions. The dichromate requires 15.50 ml of 0.1 M ferrous sulfate for titration. Calculate the percentage of lead in the sample.
Chapter 17 Solutions
Chemistry & Chemical Reactivity
Ch. 17.1 - You have a 0.30 M solution of formic acid (HCO2H)...Ch. 17.2 - What is the pH of a buffer solution composed of...Ch. 17.2 - Use the Henderson-Hasselbalch equation to...Ch. 17.2 - Using an acetic acid/sodium acetate buffer...Ch. 17.2 - Calculate the pH of 0.500 L of a buffer solution...Ch. 17.3 - The titration of 0.100 M acetic acid with 0.100 M...Ch. 17.3 - Calculate the pH after 75.0 mL of 0.100 M HO has...Ch. 17.4 - The barium ion concentration, [Ba2+], in a...Ch. 17.4 - Calculate the solubility of AgCN in moles per...Ch. 17.4 - Calculate the solubility of Ca(OH)2 in moles per...
Ch. 17.4 - Calculate the solubility of BaSO4 (a) in pure...Ch. 17.5 - Solid Pbl2 (Ksp = 9.8 109) is placed in a beaker...Ch. 17.5 - Prob. 17.13CYUCh. 17.5 - Prob. 17.14CYUCh. 17.6 - Silver nitrate (0.0050 mol) is added to 1.00 L of...Ch. 17.6 - Calculate the value of the equilibrium constant,...Ch. 17.6 - Prob. 1.1ACPCh. 17.6 - What is the minimum volume of 0.0071 M NaCN(aq)...Ch. 17.6 - Use the formation constant of [Au(CN)2] in...Ch. 17.6 - Silver undergoes similar reactions as those shown...Ch. 17.6 - Write a balanced chemical equation for the...Ch. 17.6 - Phosphate ions are abundant in cells, both as the...Ch. 17.6 - A typical total phosphate concentration in a cell,...Ch. 17 - Does the pH of the solution increase, decrease or...Ch. 17 - Does the pH of the solution increase, decrease, or...Ch. 17 - What is the pH of a solution that consists of 0.20...Ch. 17 - What is the pH of 0.15 M acetic acid to which 1.56...Ch. 17 - What is the pH of the solution that results from...Ch. 17 - What is the pH of the solution that results from...Ch. 17 - What is the pH of the buffer solution that...Ch. 17 - Lactic acid (CH3CHOHCO2H) is found in sour milk,...Ch. 17 - What mass of sodium acetate, NaCH3CO2, must he...Ch. 17 - What mass of ammonium chloride, NH4Cl, must be...Ch. 17 - Calculate the pH of a solution that has an acetic...Ch. 17 - Calculate the pH of a solution that has an...Ch. 17 - What must the ratio of acetic acid to acetate ion...Ch. 17 - What must the ratio of H2PO4 to HPO42 be to have a...Ch. 17 - A buffer is composed of formic acid and its...Ch. 17 - A buffer solution is composed of 1.360 g of KH2PO4...Ch. 17 - Which of the following combinations would be the...Ch. 17 - Which of the following combinations would be the...Ch. 17 - Describe how to prepare a buffer solution from...Ch. 17 - Describe how to prepare a buffer solution from NH3...Ch. 17 - Determine the volume (in mL) of 1.00 M NaOH that...Ch. 17 - Determine the volume (in mL) of 1.00 M HC1 that...Ch. 17 - A buffer solution was prepared by adding 4.95 g of...Ch. 17 - You dissolve 0.425 g of NaOH in 2.00 L of a buffer...Ch. 17 - A buffer solution is prepared by adding 0.125 mol...Ch. 17 - What is the pH change when 20.0 mL of 0.100 M NaOH...Ch. 17 - Phenol, C6H5OH, is a weak organic acid. Suppose...Ch. 17 - Assume you dissolve 0.235 g of the weak acid...Ch. 17 - You require 36.78 mL of 0.0105 M HCl to reach the...Ch. 17 - A titration of 25.0 mL of a solution of the weak...Ch. 17 - Without doing detailed calculations, sketch the...Ch. 17 - Without doing detailed calculations, sketch the...Ch. 17 - You titrate 25.0 mL of 0.10 M NH3 with 0.10 M HCl....Ch. 17 - Using Figure 17.11, suggest an indicator to use in...Ch. 17 - Using Figure 17.11, suggest an indicator to use in...Ch. 17 - Name two insoluble salts of each of the following...Ch. 17 - Prob. 38PSCh. 17 - Using the solubility guidelines (Figure 3.10),...Ch. 17 - Predict whether each of the fallowing is insoluble...Ch. 17 - For each of the following insoluble salts, (1)...Ch. 17 - Prob. 42PSCh. 17 - When 1.55 g of solid thallium(I) bromide is added...Ch. 17 - At 20 C, a saturated aqueous solution of silver...Ch. 17 - When 250 mg of SrF2, strontium fluoride, is added...Ch. 17 - Calcium hydroxide, Ca(OH)2, dissolves in water to...Ch. 17 - You add 0.979 g of Pb(OH)2 to 1.00 L of pure water...Ch. 17 - You place 1.234 g of solid Ca(OH)2 in 1.00 L of...Ch. 17 - Estimate the solubility of silver iodide in pure...Ch. 17 - What is the molar concentration of Au+(aq) in a...Ch. 17 - Prob. 51PSCh. 17 - Estimate the solubility of lead(II) bromide (a) in...Ch. 17 - The Ksp value for radium sulfate, RaSO4, is 4.2 ...Ch. 17 - If 55 mg of lead(II) sulfate is placed in 250 mL...Ch. 17 - Prob. 55PSCh. 17 - Prob. 56PSCh. 17 - Calculate the molar solubility of silver...Ch. 17 - Calculate the solubility of silver bromide, AgBr,...Ch. 17 - Compare the solubility, in milligrams per...Ch. 17 - What is the solubility, in milligrams per...Ch. 17 - Calculate the solubility, in moles per liter, of...Ch. 17 - Calculate the solubility, in moles per liter, of...Ch. 17 - Which insoluble compound in each pair should be...Ch. 17 - Which compound in each pair is more soluble in...Ch. 17 - You have a solution that has a lead(II) ion...Ch. 17 - Sodium carbonate is added to a solution in which...Ch. 17 - If the concentration of Zn2+ in 10.0 mL of water...Ch. 17 - You have 95 mL of a solution that has a lead(II)...Ch. 17 - Prob. 69PSCh. 17 - Will a precipitate of Mg(OH)2 form when 25.0 mL of...Ch. 17 - Zinc hydroxide is amphoteric (Section 16.10). Use...Ch. 17 - Solid silver iodide, AgI, can be dissolved by...Ch. 17 - What amount of ammonia (moles) must be added to...Ch. 17 - Can you dissolve 15.0 mg of AuCl in 100.0 mL of...Ch. 17 - What is the solubility of AgCl (a) in pure water...Ch. 17 - Prob. 76PSCh. 17 - Prob. 77GQCh. 17 - Prob. 78GQCh. 17 - Prob. 79GQCh. 17 - Calculate the hydronium ion concentration and the...Ch. 17 - Calculate the hydronium ion concentration and the...Ch. 17 - For each of the following cases, decide whether...Ch. 17 - Prob. 83GQCh. 17 - A sample of hard water contains about 2.0 103 M...Ch. 17 - What is the pH of a buffer solution prepared from...Ch. 17 - Prob. 86GQCh. 17 - Describe the effect on the pH of the following...Ch. 17 - What volume of 0.120 M NaOH must be added to 100....Ch. 17 - A buffer solution is prepared by dissolving 1.50 g...Ch. 17 - What volume of 0.200 M HCl must be added to 500.0...Ch. 17 - What is the equilibrium constant for the following...Ch. 17 - Calculate the equilibrium constant for the...Ch. 17 - Prob. 93GQCh. 17 - The solubility product constant for calcium...Ch. 17 - In principle, the ions Ba2+ and Ca2+ can be...Ch. 17 - A solution contains 0.10 M iodide ion, I, and 0.10...Ch. 17 - A solution contains Ca2+ and Pb2+ ions, both at a...Ch. 17 - Prob. 98GQCh. 17 - Prob. 99GQCh. 17 - Prob. 100GQCh. 17 - Each pair of ions below is found together in...Ch. 17 - Each pair of ions below is found together in...Ch. 17 - The cations Ba2+ and Sr2+ can be precipitated as...Ch. 17 - You will often work with salts of Fe3+, Pb2+, and...Ch. 17 - Aniline hydrochloride, (C6H5NH3)Cl, is a weak...Ch. 17 - The weak base ethanolamine. HOCH2CH2NH2, can be...Ch. 17 - For the titration of 50.0 mL of 0.150 M...Ch. 17 - A buffer solution with it pH of 12.00 consists of...Ch. 17 - To have a buffer with a pH of 2.50, what volume of...Ch. 17 - What mass of Na3PO4 must be added to 80.0 mL of...Ch. 17 - You have a solution that contains AgNO3, Pb(NO3)2,...Ch. 17 - Prob. 112ILCh. 17 - Suggest a method for separating a precipitate...Ch. 17 - Prob. 114SCQCh. 17 - Prob. 115SCQCh. 17 - Two acids, each approximately 0.01 M in...Ch. 17 - Composition diagrams, commonly known as alpha...Ch. 17 - The composition diagram, or alpha plot, for the...Ch. 17 - The chemical name for aspirin is acetylsalicylic...Ch. 17 - Prob. 120SCQ
Knowledge Booster
Learn more about
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.Similar questions
- The Handbook of Chemistry and Physics (http://openstaxcollege.org/l/16Handbook) gives solubilities of the following compounds in grams per 100 mL of water. Because these compounds are only slightly soluble, assume that the volume does not change on dissolution and calculate the solubility product for each. (a) BaSiF6, 0.026 g/100 mL (contains SiF62- ions) (b) Ce(IO3)4, 1.5102 g/100 mL (c) Gd2(SO4)3, 3.98 g/100 mL (d) (NH4)2PtBr6, 0.59 g/100 mL (contains PtBr62- ions)arrow_forwardCalculate the solubility in grams per 100 mL of BaF2 in a 0.10 M BaCl2 solution.arrow_forwardYou will often work with salts of Fe3+, Pb2+, and Al3+ in the laboratory. (All are found in nature, and all are important economically.) If you have a solution containing these three ions, each at a concentration of 0.10 M, what is the order in which their hydroxides precipitate as aqueous NaOH is slowly added to the solution?arrow_forward
- A 0.762 sample of potassium hydrogen phthalate (KHP) was dissolved into 30.0 mL of distilled water, and a few drops of the indicator phenolphthalein was added to the solution. The KHP solution was titrated with 17.92 mL of NaOH. What is the molarity of the NaOH solution used? (MMKHP = 204.22 g/mol)arrow_forwardIron (55.845 g/mol) can be determined gravimetrically by precipitation as Fe(OH)3 (106.867 g/mol) and subsequent inflammation of the precipitate to convert it to Fe2O3 (159.69 g/mol). A 0.7873 g sample to be analyzed was weighed and transferred to a 400 mL beaker, where it was dissolved in 50 mL of H2O and 10 mL of 6M HCl. Then 2 mL of concentrated HNO3 was added to the solution. After boiling to remove excess HNO3 and nitrogen oxides, the solution was diluted to 200 mL, brought to boiling, and Fe(OH)3 was precipitated by the slow addition of 1:1 NH4OH solution until an odor of NH3 was detected (indicating the presence of excess NH3 in the medium). The solution was left in a water bath at 80 ºC for 30 min at rest. The precipitate was then filtered and washed with several portions of hot 1% m/v NH4NO3 until no Cl– was detected in the wash water. Finally, the precipitate was ignited at 500-550 °C, then left in a desiccator to cool and weighed as Fe2O3, resulting in a mass of 0.4512 g.…arrow_forwardUse the solubility product to determine whether CaHPO4 will precipitate from a solution with [Ca2+] = 0.0001 M and [HPO42−] = 0.001 M.arrow_forward
- suppose you have a solution that might contain any or all of the following cations: Cu2+, Ag+, Ba2+, and Mn2+. the addition of HBr causes a precipitate to form. After the precipitate is filtered off, H2SO4 is added to the supernate, and another precipitate forms. This precipitate is filtered off, and a solution of NaOH is added to the supernatant liquid until it is strongly alkaline. No precipitate is formed. Which ions are present in each of the precipitates? which cations are not present in the original solution?arrow_forwardA solution contains 0.220 M Pb2+ and 0.49 M Al3+. Calculate the pH range that would allow Al(OH)3 to precipitate but not Pb(OH)2. The Ksp values for Al(OH)3 and Pb(OH)2 can be found in this table. Lead(II) hydroxide Pb(OH)2 1.43×10–20 Aluminium hydroxide Al(OH)3 4.6×10–33arrow_forwardCalcium oxalate is a sparingly soluble ionic compound composed of calcium ions (Ca2+) and oxalate ions (C2O42–). It is a main culprit in kidney stone disease due to the formation of calcium oxalate crystals in the urine. A typical value for the concentration of calcium in urine is 0.3 grams per liter. Given a Ksp value for calcium oxalate of 1.3 × 10–8, calculate the minimum concentration of oxalate ion in urine that could lead to precipitation of calcium oxalate.arrow_forward
- You have been given an unknown that contains a Group I ion (Ag+ or Hg22+), a Group II ion (Fe2+ or Mn2+) and a Group III ion (Cu2+ or Ni2+). First you place 5 drops in a test tube and add 3 drops of 3 M HCl. You see a white precipitate. Next you add 1mL of 6 M NH3. The precipitate turns a little gray, but you are unsure if it is gray or white. You run some tests to confirm and believe it is gray. 1. What test did you run to confirm the precipitate is gray and what is the identity of the Group I ion (use complete sentences and type your answer in the space below)? Next, you place 5 mL of fresh unknown in a test tube and add 5 mL of HCl (and again see a white precipitate. 2. How do you separate the white precipitate, so that you can test the ions in the solution that aren’t precipitated (use complete sentences and type your answer in the space below)? Now you have separated the solution from the precipitate. You discard the precipitate and need to test…arrow_forwardThe photographs below (a) show what occurs when a solution of iron(III) nitrate istreated with a few drops of aqueous potassium thiocyanate. The nearly colorlessiron(III) ion is converted to a red [Fe(H2O)5SCN)2+ion. (This is a classic test for thepresence of iron(III) ions in solution.)[Fe(H2O)6]3+(aq) + SCN−(aq) ⇄ [Fe(H2O)5SCN]2+(aq) + H2O(ℓ)(a) As more KSCN is added to the solution, the color becomes even more red.Explain this observation.(b) Silver ions form a white precipitate with SCN−ions. What would you observeon adding a few drops of aqueous silver nitrate to a red solution of [Fe(H2O)5 Explain your observations?arrow_forwardCalculate the concentration of cobalt(III) ions in a solution formed by mixing 200 mL of 0.200 M Co(NO3)3 with 250 mL of 5.00 M NH3 solution given Kf of [Co(NH3)6]3+ is 4.5×1033. [Co3+] = ___Marrow_forward
arrow_back_ios
SEE MORE QUESTIONS
arrow_forward_ios
Recommended textbooks for you
Chemistry & Chemical ReactivityChemistryISBN:9781133949640Author:John C. Kotz, Paul M. Treichel, John Townsend, David TreichelPublisher:Cengage Learning
Chemistry & Chemical ReactivityChemistryISBN:9781337399074Author:John C. Kotz, Paul M. Treichel, John Townsend, David TreichelPublisher:Cengage Learning
Chemistry: Principles and PracticeChemistryISBN:9780534420123Author:Daniel L. Reger, Scott R. Goode, David W. Ball, Edward MercerPublisher:Cengage Learning
Chemistry by OpenStax (2015-05-04)ChemistryISBN:9781938168390Author:Klaus Theopold, Richard H Langley, Paul Flowers, William R. Robinson, Mark BlaserPublisher:OpenStax
Chemistry: Principles and ReactionsChemistryISBN:9781305079373Author:William L. Masterton, Cecile N. HurleyPublisher:Cengage Learning
Chemistry & Chemical Reactivity
Chemistry
ISBN:9781133949640
Author:John C. Kotz, Paul M. Treichel, John Townsend, David Treichel
Publisher:Cengage Learning
Chemistry & Chemical Reactivity
Chemistry
ISBN:9781337399074
Author:John C. Kotz, Paul M. Treichel, John Townsend, David Treichel
Publisher:Cengage Learning
Chemistry: Principles and Practice
Chemistry
ISBN:9780534420123
Author:Daniel L. Reger, Scott R. Goode, David W. Ball, Edward Mercer
Publisher:Cengage Learning
Chemistry by OpenStax (2015-05-04)
Chemistry
ISBN:9781938168390
Author:Klaus Theopold, Richard H Langley, Paul Flowers, William R. Robinson, Mark Blaser
Publisher:OpenStax
Chemistry: Principles and Reactions
Chemistry
ISBN:9781305079373
Author:William L. Masterton, Cecile N. Hurley
Publisher:Cengage Learning
O-Level Chemistry | 16 | Qualitative Analysis [1/3]; Author: Bernard Ng;https://www.youtube.com/watch?v=oaU8dReeBgA;License: Standard YouTube License, CC-BY