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Science
ChemistryChemistry & Chemical Reactivity10th Edition

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Chapter 17, Problem 111IL
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Chemistry & Chemical Reactivity

10th Edition
John C. Kotz + 3 others
ISBN: 9781337399074

Solutions

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Problem 1PS
Problem 2PS
Problem 3PS
Problem 4PS
Problem 5PS
Problem 6PS
Problem 7PS
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Problem 9PS
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Problem 11PS
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Problem 50PS
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Problem 70PS
Problem 71PS
Problem 72PS
Problem 73PS
Problem 74PS
Problem 75PS
Problem 76PS
Problem 77GQ
Problem 78GQ
Problem 79GQ
Problem 80GQ
Problem 81GQ
Problem 82GQ
Problem 83GQ
Problem 84GQ
Problem 85GQ
Problem 86GQ
Problem 87GQ
Problem 88GQ
Problem 89GQ
Problem 90GQ
Problem 91GQ
Problem 92GQ
Problem 93GQ
Problem 94GQ
Problem 95GQ
Problem 96GQ
Problem 97GQ
Problem 98GQ
Problem 99GQ
Problem 100GQ
Problem 101IL
Problem 102IL
Problem 103IL
Problem 104IL
Problem 105IL
Problem 106IL
Problem 107IL
Problem 108IL
Problem 109IL
Problem 110IL
Problem 111IL
Problem 112IL
Problem 113SCQ
Problem 114SCQ
Problem 115SCQ
Problem 116SCQ
Problem 117SCQ
Problem 118SCQ
Problem 119SCQ
Problem 120SCQ
BuyFindarrow_forward

Chemistry & Chemical Reactivity

10th Edition
John C. Kotz + 3 others
ISBN: 9781337399074
Textbook Problem

You have a solution that contains AgNO3, Pb(NO3)2, and Cu(NO3)2. Devise a separation method that results in having Ag+ in one test tube, Pb2+ in another, and Cu2+ in a third test tube. Use solubility guidelines and Ksp and Kf values.

Interpretation Introduction

Interpretation:

Using solubility guideline a method to separate Ag+, Pb2+ and Cu2+ ions from a solution containing Ag(NO3), Pb(NO3)2 and Cu(NO3)2 has to be suggested.

Concept introduction:

Solubility product constant Ksp is an equilibrium constant and is defined as the product of the equilibrium concentration of the ions of the salt raised to the power of their coefficients in the balanced chemical equation.

The expression for Ksp of a salt is given as,

AxBy(s)⇌xAy+(aq)+yB−x(aq)Ksp=[Ay+]x[B−x]y

When in the solution more than one insoluble salt having one common ion is present than the one which requires less amount of the common ion to exceed its solubility product value and precipitate will precipitate out first from the solution. This is known as preferential precipitation or selective precipitation.

Explanation

Ag(NO3), Pb(NO3)2 and Cu(NO3)2 are strong electrolyte and in solution present in the form of ions. In solution Ag+,Pb2+ and Cu2+ ions will be present along with NO3− ions.

Step1: To the solution add HCl,  chlorides of salt will form. Chlorides of Ag+ and Pb2+ are water-insoluble while that of Cu2+ is soluble in water. Therefore AgCl and PbCl2 precipitates out and CuCl2 remains in the solution. Filter off the solution and separate precipitate.

Step2: AgCl and PbCl2 are then further separated on the basis of their Ksp values

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Sect-17.1 P-17.1CYUSect-17.2 P-17.2CYUSect-17.2 P-17.3CYUSect-17.2 P-17.4CYUSect-17.2 P-17.5CYUSect-17.3 P-17.6CYUSect-17.3 P-17.7CYUSect-17.4 P-17.8CYUSect-17.4 P-17.9CYUSect-17.4 P-17.10CYU
Sect-17.4 P-17.11CYUSect-17.5 P-17.12CYUSect-17.5 P-17.13CYUSect-17.5 P-17.14CYUSect-17.6 P-17.15CYUSect-17.6 P-17.16CYUSect-17.6 P-1.1ACPSect-17.6 P-1.2ACPSect-17.6 P-1.3ACPSect-17.6 P-1.4ACPSect-17.6 P-1.5ACPSect-17.6 P-2.1ACPSect-17.6 P-2.2ACPCh-17 P-1PSCh-17 P-2PSCh-17 P-3PSCh-17 P-4PSCh-17 P-5PSCh-17 P-6PSCh-17 P-7PSCh-17 P-8PSCh-17 P-9PSCh-17 P-10PSCh-17 P-11PSCh-17 P-12PSCh-17 P-13PSCh-17 P-14PSCh-17 P-15PSCh-17 P-16PSCh-17 P-17PSCh-17 P-18PSCh-17 P-19PSCh-17 P-20PSCh-17 P-21PSCh-17 P-22PSCh-17 P-23PSCh-17 P-24PSCh-17 P-25PSCh-17 P-26PSCh-17 P-27PSCh-17 P-28PSCh-17 P-29PSCh-17 P-30PSCh-17 P-31PSCh-17 P-32PSCh-17 P-33PSCh-17 P-35PSCh-17 P-36PSCh-17 P-37PSCh-17 P-38PSCh-17 P-39PSCh-17 P-40PSCh-17 P-41PSCh-17 P-42PSCh-17 P-43PSCh-17 P-44PSCh-17 P-45PSCh-17 P-46PSCh-17 P-47PSCh-17 P-48PSCh-17 P-49PSCh-17 P-50PSCh-17 P-51PSCh-17 P-52PSCh-17 P-53PSCh-17 P-54PSCh-17 P-55PSCh-17 P-56PSCh-17 P-57PSCh-17 P-58PSCh-17 P-59PSCh-17 P-60PSCh-17 P-61PSCh-17 P-62PSCh-17 P-63PSCh-17 P-64PSCh-17 P-65PSCh-17 P-66PSCh-17 P-67PSCh-17 P-68PSCh-17 P-69PSCh-17 P-70PSCh-17 P-71PSCh-17 P-72PSCh-17 P-73PSCh-17 P-74PSCh-17 P-75PSCh-17 P-76PSCh-17 P-77GQCh-17 P-78GQCh-17 P-79GQCh-17 P-80GQCh-17 P-81GQCh-17 P-82GQCh-17 P-83GQCh-17 P-84GQCh-17 P-85GQCh-17 P-86GQCh-17 P-87GQCh-17 P-88GQCh-17 P-89GQCh-17 P-90GQCh-17 P-91GQCh-17 P-92GQCh-17 P-93GQCh-17 P-94GQCh-17 P-95GQCh-17 P-96GQCh-17 P-97GQCh-17 P-98GQCh-17 P-99GQCh-17 P-100GQCh-17 P-101ILCh-17 P-102ILCh-17 P-103ILCh-17 P-104ILCh-17 P-105ILCh-17 P-106ILCh-17 P-107ILCh-17 P-108ILCh-17 P-109ILCh-17 P-110ILCh-17 P-111ILCh-17 P-112ILCh-17 P-113SCQCh-17 P-114SCQCh-17 P-115SCQCh-17 P-116SCQCh-17 P-117SCQCh-17 P-118SCQCh-17 P-119SCQCh-17 P-120SCQ

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