Use the table of standard reduction potentials (Table 17-1) to pick a reagent that is capable of each of the following reductions (under standard conditions in acidic solution). a. reduce Cu 2+ to Cu but not reduce Cu 2+ to Cu + b. reduce Br 2 to Br − but not reduce I 2 to I − .

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(a) Interpretation Introduction Interpretation: The table for reduction potential of various species is given. The reagent that is capable of the given reduction is to be picked. Concept introduction: The species with higher reduction potential undergoes reduction thus, oxidizing the other species while the species with lower reduction potential undergoes oxidation and thus, reduces the other species. To determine: The species that are capable of the given reductions. Explanation The species that can reduce Cu 2 + to Cu but cannot reduce Cu 2+ to Cu + are Hg 2 Cl 2 , AgCl , SO 4 2 − . The reduction potential values for the given species are as follows, Cu 2 + + 2 e − → Cu E ° = 0.34 V Cu 2+ + e − → Cu + E ° = 0 (b) Interpretation Introduction Interpretation: The table for reduction potential of various species is given. The reagent that is capable of the given reduction is to be picked. Concept introduction: The species with higher reduction potential undergoes reduction thus, oxidizing the other species while the species with lower reduction potential undergoes oxidation and thus, reduces the other species. To determine: The species that are capable of the given reductions.

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Answer 1

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Chemistry: An Atoms First Approach

2nd Edition

Steven S. Zumdahl + 1 other

Publisher: Cengage Learning

ISBN: 9781305079243

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Chemistry: An Atoms First Approach

2nd Edition

Steven S. Zumdahl + 1 other

Publisher: Cengage Learning

ISBN: 9781305079243

Solutions

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Section

Answer 3

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Section

Answer 4

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Answer 5

(a)

Interpretation Introduction

Interpretation:

The table for reduction potential of various species is given. The reagent that is capable of the given reduction is to be picked.

Concept introduction:

The species with higher reduction potential undergoes reduction thus, oxidizing the other species while the species with lower reduction potential undergoes oxidation and thus, reduces the other species.

To determine: The species that are capable of the given reductions.

Explanation of Solution

The species that can reduce Cu2+ to Cu but cannot reduce Cu2+ to Cu+ are Hg2Cl2,AgCl,SO42− .

The reduction potential values for the given species are as follows,

Cu2++2e−→Cu E°=0.34 VCu2++e−→Cu+ E°=0

Answer 6

(b)

Interpretation Introduction

Interpretation:

The table for reduction potential of various species is given. The reagent that is capable of the given reduction is to be picked.

Concept introduction:

The species with higher reduction potential undergoes reduction thus, oxidizing the other species while the species with lower reduction potential undergoes oxidation and thus, reduces the other species.

To determine: The species that are capable of the given reductions.

Use the table of standard reduction potentials (Table 17-1) to pick a reagent that is capable of each of the following reductions (under standard conditions in acidic solution). a. reduce Cu 2+ to Cu but not reduce Cu 2+ to Cu + b. reduce Br 2 to Br − but not reduce I 2 to I − .

Chemistry: An Atoms First Approach

Solutions

Chemistry: An Atoms First Approach

Use the table of standard reduction potentials (Table 17-1) to pick a reagent that is capable of each of the following reductions (under standard conditions in acidic solution).

a. reduce Cu²⁺ to Cu but not reduce Cu²⁺ to Cu⁺

b. reduce Br₂ to Br⁻ but not reduce I₂ to I⁻.

Explanation of Solution

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Use the table of standard reduction potentials (Table 17-1) to pick a reagent that is capable of each of the following reductions (under standard conditions in acidic solution). a. reduce Cu 2+ to Cu but not reduce Cu 2+ to Cu + b. reduce Br 2 to Br − but not reduce I 2 to I − .

Chemistry: An Atoms First Approach

Solutions

Chemistry: An Atoms First Approach