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Science
ChemistryChemistry & Chemical Reactivity10th Edition

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Chapter 17, Problem 83GQ
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Chemistry & Chemical Reactivity

10th Edition
John C. Kotz + 3 others
ISBN: 9781337399074

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Problem 39PS
Problem 40PS
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Problem 43PS
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Problem 45PS
Problem 46PS
Problem 47PS
Problem 48PS
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Problem 50PS
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Problem 70PS
Problem 71PS
Problem 72PS
Problem 73PS
Problem 74PS
Problem 75PS
Problem 76PS
Problem 77GQ
Problem 78GQ
Problem 79GQ
Problem 80GQ
Problem 81GQ
Problem 82GQ
Problem 83GQ
Problem 84GQ
Problem 85GQ
Problem 86GQ
Problem 87GQ
Problem 88GQ
Problem 89GQ
Problem 90GQ
Problem 91GQ
Problem 92GQ
Problem 93GQ
Problem 94GQ
Problem 95GQ
Problem 96GQ
Problem 97GQ
Problem 98GQ
Problem 99GQ
Problem 100GQ
Problem 101IL
Problem 102IL
Problem 103IL
Problem 104IL
Problem 105IL
Problem 106IL
Problem 107IL
Problem 108IL
Problem 109IL
Problem 110IL
Problem 111IL
Problem 112IL
Problem 113SCQ
Problem 114SCQ
Problem 115SCQ
Problem 116SCQ
Problem 117SCQ
Problem 118SCQ
Problem 119SCQ
Problem 120SCQ
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Chemistry & Chemical Reactivity

10th Edition
John C. Kotz + 3 others
ISBN: 9781337399074
Textbook Problem

Rank the following compounds in order of increasing solubility in water Na2CO3, BaCO3, Ag2CO3.

Interpretation Introduction

Interpretation:

Using Ksp values, the given salts in order of increasing solubility in water has to be arranged.

Concept introduction:

The solubility of a salt is defined as the maximum amount of salt that can be dissolved in definite amount of solvent. It is expressed in moles per liter or grams per liter. Solubility in terms of moles per liter is called molar solubility and is defined as the number of moles of solute (salt) dissolved in per liter of solution.

Solubility product constant Ksp is an equilibrium constant and is defined as the product of the equilibrium concentration of the ions of the salt raised to the power of their coefficients in the balanced chemical equation.

The expression for Ksp of a salt is given as,

AxBy(s)⇌xAy+(aq)+yB−x(aq)Ksp=[Ay+]x[B−x]y

Explanation

Refer to the Appendix J in the textbook for the value of Ksp.

Solubility product constant Ksp for Na2CO3 is 4.89×10−2 .

ICE table (1) for Na2CO3 is as follows.

EquationNa2CO3(s)⇌2Na+(aq)+CO32−(aq)Initial (M)00Change (M)+2s+sEquilibrium (M) 2s s

Ksp=[Na+]2[CO32−]=(2s2)(s)=4s3

Solubility of Na2CO3 is,

s=Ksp43=(4.89×10−2)43=0.23​ mol⋅L−1

Solubility product constant Ksp for BaCO3 is 2.6×10−9 .

ICE table (2) for BaCO3 is as follows.

EquationBaCO3(s)⇌Ba2+(aq)+CO32−(aq)Initial (M)00Change (M)+s+sEquilibrium (M) s s

Ksp=[Ba2+][CO32−]=(s)(s)=s2

Solubility of BaCO3 is,

s=Ksp=2

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Sect-17.1 P-17.1CYUSect-17.2 P-17.2CYUSect-17.2 P-17.3CYUSect-17.2 P-17.4CYUSect-17.2 P-17.5CYUSect-17.3 P-17.6CYUSect-17.3 P-17.7CYUSect-17.4 P-17.8CYUSect-17.4 P-17.9CYUSect-17.4 P-17.10CYU
Sect-17.4 P-17.11CYUSect-17.5 P-17.12CYUSect-17.5 P-17.13CYUSect-17.5 P-17.14CYUSect-17.6 P-17.15CYUSect-17.6 P-17.16CYUSect-17.6 P-1.1ACPSect-17.6 P-1.2ACPSect-17.6 P-1.3ACPSect-17.6 P-1.4ACPSect-17.6 P-1.5ACPSect-17.6 P-2.1ACPSect-17.6 P-2.2ACPCh-17 P-1PSCh-17 P-2PSCh-17 P-3PSCh-17 P-4PSCh-17 P-5PSCh-17 P-6PSCh-17 P-7PSCh-17 P-8PSCh-17 P-9PSCh-17 P-10PSCh-17 P-11PSCh-17 P-12PSCh-17 P-13PSCh-17 P-14PSCh-17 P-15PSCh-17 P-16PSCh-17 P-17PSCh-17 P-18PSCh-17 P-19PSCh-17 P-20PSCh-17 P-21PSCh-17 P-22PSCh-17 P-23PSCh-17 P-24PSCh-17 P-25PSCh-17 P-26PSCh-17 P-27PSCh-17 P-28PSCh-17 P-29PSCh-17 P-30PSCh-17 P-31PSCh-17 P-32PSCh-17 P-33PSCh-17 P-35PSCh-17 P-36PSCh-17 P-37PSCh-17 P-38PSCh-17 P-39PSCh-17 P-40PSCh-17 P-41PSCh-17 P-42PSCh-17 P-43PSCh-17 P-44PSCh-17 P-45PSCh-17 P-46PSCh-17 P-47PSCh-17 P-48PSCh-17 P-49PSCh-17 P-50PSCh-17 P-51PSCh-17 P-52PSCh-17 P-53PSCh-17 P-54PSCh-17 P-55PSCh-17 P-56PSCh-17 P-57PSCh-17 P-58PSCh-17 P-59PSCh-17 P-60PSCh-17 P-61PSCh-17 P-62PSCh-17 P-63PSCh-17 P-64PSCh-17 P-65PSCh-17 P-66PSCh-17 P-67PSCh-17 P-68PSCh-17 P-69PSCh-17 P-70PSCh-17 P-71PSCh-17 P-72PSCh-17 P-73PSCh-17 P-74PSCh-17 P-75PSCh-17 P-76PSCh-17 P-77GQCh-17 P-78GQCh-17 P-79GQCh-17 P-80GQCh-17 P-81GQCh-17 P-82GQCh-17 P-83GQCh-17 P-84GQCh-17 P-85GQCh-17 P-86GQCh-17 P-87GQCh-17 P-88GQCh-17 P-89GQCh-17 P-90GQCh-17 P-91GQCh-17 P-92GQCh-17 P-93GQCh-17 P-94GQCh-17 P-95GQCh-17 P-96GQCh-17 P-97GQCh-17 P-98GQCh-17 P-99GQCh-17 P-100GQCh-17 P-101ILCh-17 P-102ILCh-17 P-103ILCh-17 P-104ILCh-17 P-105ILCh-17 P-106ILCh-17 P-107ILCh-17 P-108ILCh-17 P-109ILCh-17 P-110ILCh-17 P-111ILCh-17 P-112ILCh-17 P-113SCQCh-17 P-114SCQCh-17 P-115SCQCh-17 P-116SCQCh-17 P-117SCQCh-17 P-118SCQCh-17 P-119SCQCh-17 P-120SCQ

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