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ChemistryIntroductory Chemistry: A Foundation9th Edition

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Chapter 17, Problem 88AP
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Introductory Chemistry: A Foundati...

9th Edition
Steven S. Zumdahl + 1 other
ISBN: 9781337399425

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Introductory Chemistry: A Foundati...

9th Edition
Steven S. Zumdahl + 1 other
ISBN: 9781337399425
Textbook Problem
1 views

. Suppose K = 4.5 × 10 − 3 at a certain temperature for the reaction
PCl 5 ( g ) ⇌ PCl 3 ( g ) + Cl 2 ( g )    If it is found that the concentration of PCl5is twice the concentration of PCl3, what must be the concentration of Cl2under these conditions?

Interpretation Introduction

Interpretation:

The concentration of Cl2 under the given conditions is to be calculated.

Concept Introduction:

The equilibrium constant (K) is defined as the ratio of the amounts of reactants and products. It relates the concentration of chemical substances involved in a chemical reaction at the time of equilibrium. It depends on the temperature of a chemical reaction.

Explanation

The given chemical reaction is,

PCl5(g)⇌PCl3(g)+Cl2(g)

An expression for the equilibrium constant of this reaction is,

K=[PCl3][Cl2][PCl5]

The concentration of PCl3 at equilibrium is assumed to be x mol/L.

It is given that the concentration of PCl5 is twice the concentration of PCl3. Therefore, the concentration of PCl5 is 2x mol/L.

The value of equilibrium constant is 4.5×10−3.

Substitute the values of the concentrations of PCl3, PCl5 and equilibrium constant in the above expression

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Sect-17.2 P-1CTSect-17.2 P-2CTSect-17.5 P-17.1SCSect-17.6 P-17.2SCSect-17.7 P-17.3SCSect-17.7 P-17.4SCSect-17.7 P-17.5SCSect-17.9 P-17.6SCSect-17.9 P-17.7SCSect-17.9 P-17.8SC
Ch-17 P-1ALQCh-17 P-2ALQCh-17 P-3ALQCh-17 P-4ALQCh-17 P-5ALQCh-17 P-6ALQCh-17 P-7ALQCh-17 P-8ALQCh-17 P-9ALQCh-17 P-10ALQCh-17 P-11ALQCh-17 P-12ALQCh-17 P-13ALQCh-17 P-14ALQCh-17 P-1QAPCh-17 P-2QAPCh-17 P-3QAPCh-17 P-4QAPCh-17 P-5QAPCh-17 P-6QAPCh-17 P-7QAPCh-17 P-8QAPCh-17 P-9QAPCh-17 P-10QAPCh-17 P-11QAPCh-17 P-12QAPCh-17 P-13QAPCh-17 P-14QAPCh-17 P-15QAPCh-17 P-16QAPCh-17 P-17QAPCh-17 P-18QAPCh-17 P-19QAPCh-17 P-20QAPCh-17 P-21QAPCh-17 P-22QAPCh-17 P-23QAPCh-17 P-24QAPCh-17 P-25QAPCh-17 P-26QAPCh-17 P-27QAPCh-17 P-28QAPCh-17 P-29QAPCh-17 P-30QAPCh-17 P-31QAPCh-17 P-32QAPCh-17 P-33QAPCh-17 P-34QAPCh-17 P-35QAPCh-17 P-36QAPCh-17 P-37QAPCh-17 P-38QAPCh-17 P-39QAPCh-17 P-40QAPCh-17 P-41QAPCh-17 P-42QAPCh-17 P-43QAPCh-17 P-44QAPCh-17 P-45QAPCh-17 P-46QAPCh-17 P-47QAPCh-17 P-48QAPCh-17 P-49QAPCh-17 P-50QAPCh-17 P-51QAPCh-17 P-52QAPCh-17 P-53QAPCh-17 P-54QAPCh-17 P-55QAPCh-17 P-56QAPCh-17 P-57QAPCh-17 P-58QAPCh-17 P-59QAPCh-17 P-60QAPCh-17 P-61QAPCh-17 P-62QAPCh-17 P-63QAPCh-17 P-64QAPCh-17 P-65QAPCh-17 P-66QAPCh-17 P-67QAPCh-17 P-68QAPCh-17 P-69QAPCh-17 P-70QAPCh-17 P-71APCh-17 P-72APCh-17 P-73APCh-17 P-74APCh-17 P-75APCh-17 P-76APCh-17 P-77APCh-17 P-78APCh-17 P-79APCh-17 P-80APCh-17 P-81APCh-17 P-82APCh-17 P-83APCh-17 P-84APCh-17 P-85APCh-17 P-86APCh-17 P-87APCh-17 P-88APCh-17 P-89APCh-17 P-90APCh-17 P-91APCh-17 P-92APCh-17 P-93APCh-17 P-94APCh-17 P-95APCh-17 P-96APCh-17 P-97APCh-17 P-98APCh-17 P-99APCh-17 P-100APCh-17 P-101APCh-17 P-102APCh-17 P-103APCh-17 P-104APCh-17 P-105APCh-17 P-106APCh-17 P-107APCh-17 P-108APCh-17 P-109APCh-17 P-110APCh-17 P-111APCh-17 P-112APCh-17 P-113APCh-17 P-114APCh-17 P-115APCh-17 P-116APCh-17 P-117APCh-17 P-118APCh-17 P-119APCh-17 P-120CPCh-17 P-121CPCh-17 P-122CPCh-17 P-123CPCh-17 P-124CPCh-17 P-125CPCh-17 P-126CPCh-17 P-1CRCh-17 P-2CRCh-17 P-3CRCh-17 P-4CRCh-17 P-5CRCh-17 P-6CRCh-17 P-7CRCh-17 P-8CRCh-17 P-9CRCh-17 P-10CRCh-17 P-11CRCh-17 P-12CRCh-17 P-13CRCh-17 P-14CRCh-17 P-15CRCh-17 P-16CRCh-17 P-17CRCh-17 P-18CRCh-17 P-19CRCh-17 P-20CRCh-17 P-21CRCh-17 P-22CRCh-17 P-23CRCh-17 P-24CR

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