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ChemistryPhysical Chemistry2nd Edition

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Chapter 18, Problem 18.17E
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Physical Chemistry

2nd Edition
Ball + 3 others
ISBN: 9781133958437

Solutions

Chapter
Section
Problem 18.1E
Problem 18.2E
Problem 18.3E
Problem 18.4E
Problem 18.5E
Problem 18.6E
Problem 18.7E
Problem 18.8E
Problem 18.9E
Problem 18.10E
Problem 18.11E
Problem 18.12E
Problem 18.13E
Problem 18.14E
Problem 18.15E
Problem 18.16E
Problem 18.17E
Problem 18.18E
Problem 18.19E
Problem 18.20E
Problem 18.21E
Problem 18.22E
Problem 18.23E
Problem 18.24E
Problem 18.25E
Problem 18.26E
Problem 18.27E
Problem 18.28E
Problem 18.29E
Problem 18.30E
Problem 18.31E
Problem 18.32E
Problem 18.33E
Problem 18.34E
Problem 18.35E
Problem 18.36E
Problem 18.37E
Problem 18.38E
Problem 18.39E
Problem 18.40E
Problem 18.41E
Problem 18.42E
Problem 18.43E
Problem 18.44E
Problem 18.45E
Problem 18.48E
Problem 18.49E
Problem 18.50E
Problem 18.51E
Problem 18.54E
Problem 18.55E
Problem 18.56E
Problem 18.57E
Problem 18.58E
Problem 18.59E
Problem 18.60E
BuyFindarrow_forward

Physical Chemistry

2nd Edition
Ball + 3 others
ISBN: 9781133958437
Textbook Problem

Consider two identical planets that are the same distance from their star. One planet has an atmosphere of argon gas, and the other has an atmosphere of fluorine gas. Assume that all other physical descriptions of the planets are the same. From statistical thermodynamic perspectives, which planet should have the higher atmospheric temperature? Justify your answer by citing specific equations from the chapter.

Interpretation Introduction

Interpretation:

The planet from the given two planets that has higher atmospheric temperature is to be identified. The validation of the corresponding answer by citing specific equations is to be stated.

Concept introduction:

A molecule is made up of atoms that are bonded together by covalent bonds. These bonds undergo a to and fro movement to vibrate. This vibration of the molecule contributes to the overall partition function of the system. The vibrational temperature of a diatomic gas is given as,

θv=hvk

Where,

• k represents the Boltzmann constant with value 1.381×10−23 J/K.

• T represents the temperature (K).

• v represents the ith vibrational frequency.

Explanation

According to statistical thermodynamics, the total energy of the system is given by the sum of all types of energy. The formula of energy is represented as,

E=Etrans+Eelect+Evib+Erot+Enuc

Where,

• Etrans represents the translation energy.

• Eelect represents the electronic energy.

• Evib represents the vibrational energy.

• Erot represents the rotational energy.

• Enuc represents the nuclear energy.

The molecular partition function is represented as,

Q=qtransâ‹…qelectâ‹…qvibâ‹…qrotâ‹…qnuc

Where,

• qtrans represents the translation partition function.

• qelect represents the electronic partition function.

• qvib represents the vibrational partition function

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Chapter 18 Solutions

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Ch-18 P-18.1ECh-18 P-18.2ECh-18 P-18.3ECh-18 P-18.4ECh-18 P-18.5ECh-18 P-18.6ECh-18 P-18.7ECh-18 P-18.8ECh-18 P-18.9ECh-18 P-18.10E
Ch-18 P-18.11ECh-18 P-18.12ECh-18 P-18.13ECh-18 P-18.14ECh-18 P-18.15ECh-18 P-18.16ECh-18 P-18.17ECh-18 P-18.18ECh-18 P-18.19ECh-18 P-18.20ECh-18 P-18.21ECh-18 P-18.22ECh-18 P-18.23ECh-18 P-18.24ECh-18 P-18.25ECh-18 P-18.26ECh-18 P-18.27ECh-18 P-18.28ECh-18 P-18.29ECh-18 P-18.30ECh-18 P-18.31ECh-18 P-18.32ECh-18 P-18.33ECh-18 P-18.34ECh-18 P-18.35ECh-18 P-18.36ECh-18 P-18.37ECh-18 P-18.38ECh-18 P-18.39ECh-18 P-18.40ECh-18 P-18.41ECh-18 P-18.42ECh-18 P-18.43ECh-18 P-18.44ECh-18 P-18.45ECh-18 P-18.48ECh-18 P-18.49ECh-18 P-18.50ECh-18 P-18.51ECh-18 P-18.54ECh-18 P-18.55ECh-18 P-18.56ECh-18 P-18.57ECh-18 P-18.58ECh-18 P-18.59ECh-18 P-18.60E

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