Physics for Scientists and Engineers with Modern Physics
Physics for Scientists and Engineers with Modern Physics
4th Edition
ISBN: 9780131495081
Author: Douglas C. Giancoli
Publisher: Addison-Wesley
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Textbook Question
Chapter 18, Problem 1Q

Why doesn’t the size of different molecules enter into the ideal gas law?

Expert Solution & Answer
Check Mark
To determine

The reason for the size of different molecules not being considered in ideal gas law.

Answer to Problem 1Q

The size of the molecule is not considered for the different molecules because the average distance between the molecules is far greater than the size of the molecules.

Explanation of Solution

The ideal gas law is defined based on the several basic postulates of the kinetic theory of gases. One of the postulates states that the molecules present in a closed container are sufficiently far enough from each other to consider their size on average.

Therefore, the size of the molecules is not considered as a prime factor in defining the ideal gas law. The ideal gas law considers the average size of all the molecules present in the closed container as they are comparably far away from each other as compared to their diameter.

So, this postulate eliminates the need for the size of the different molecules present it container. It rather uses the average size of molecules for the whole lot of the molecules present.

Conclusion:

Thus, the size of the molecule is not considered for the different molecules because the average distance between the molecules is far greater than the size of the molecules.

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Chapter 18 Solutions

Physics for Scientists and Engineers with Modern Physics

Ch. 18 - As you go higher in the Earths atmosphere, the...Ch. 18 - Prob. 7QCh. 18 - Is temperature a macroscopic or microscopic...Ch. 18 - Explain why the peak of the curve for 310 K in...Ch. 18 - Escape velocity for the Earth refers to the...Ch. 18 - Prob. 11QCh. 18 - If the pressure in a gas is doubled while its...Ch. 18 - What everyday observation would tell you that not...Ch. 18 - Prob. 14QCh. 18 - Alcohol evaporates more quickly than water at room...Ch. 18 - Explain why a hot humid day is far more...Ch. 18 - Is it possible to boil water at room temperature...Ch. 18 - What exactly does it mean when we say that oxygen...Ch. 18 - A length of thin wire is placed over a block of...Ch. 18 - Consider two days when the air temperature is the...Ch. 18 - (a) Why does food cook faster in a pressure...Ch. 18 - How do a gas and a vapor differ?Ch. 18 - (a) At suitable temperatures and pressures, can...Ch. 18 - Why does dry ice not last long at room...Ch. 18 - Under what conditions can liquid CO2 exist? Be...Ch. 18 - Why does exhaled air appear as a little white...Ch. 18 - Prob. 27QCh. 18 - Prob. 1PCh. 18 - Prob. 2PCh. 18 - (I) By what factor will the rms speed of gas...Ch. 18 - (I) A gas is at 20C. To what temperature must it...Ch. 18 - (I) What speed would a 1.0-g paper clip have if it...Ch. 18 - (I) A 1.0-mol sample of hydrogen gas has a...Ch. 18 - (I) Twelve molecules have the following speeds,...Ch. 18 - (II) The rms speed of molecules in a gas at 20.0C...Ch. 18 - (II) If the pressure in a gas is tripled while its...Ch. 18 - Prob. 10PCh. 18 - (II) Show that for a mixture of two gases at the...Ch. 18 - (II) What is the rms speed of nitrogen molecules...Ch. 18 - (II) (a) For an ideal gas at temperature T show...Ch. 18 - Prob. 14PCh. 18 - Prob. 15PCh. 18 - Prob. 16PCh. 18 - Prob. 17PCh. 18 - Prob. 18PCh. 18 - Prob. 19PCh. 18 - (I) A group of 25 particles have the following...Ch. 18 - Prob. 21PCh. 18 - (I) CO2 exists in what phase when the pressure is...Ch. 18 - (I) (a) At atmospheric pressure, in what phases...Ch. 18 - Prob. 25PCh. 18 - Prob. 26PCh. 18 - Prob. 27PCh. 18 - Prob. 28PCh. 18 - Prob. 29PCh. 18 - Prob. 30PCh. 18 - (II) If the air pressure at a particular place in...Ch. 18 - (II) What is the mass of water in a closed room...Ch. 18 - Prob. 33PCh. 18 - Prob. 34PCh. 18 - (II) A pressure cooker is a sealed pot designed to...Ch. 18 - (II) When using a mercury barometer (Section 136),...Ch. 18 - (II) If the humidity is 45% at 30.0C, what is the...Ch. 18 - Prob. 38PCh. 18 - Prob. 40PCh. 18 - (II) For oxygen gas, the van der Waals equation of...Ch. 18 - Prob. 44PCh. 18 - (II) At about what pressure would the mean free...Ch. 18 - Prob. 46PCh. 18 - (II) A very small amount of hydrogen gas is...Ch. 18 - Prob. 48PCh. 18 - Prob. 49PCh. 18 - Prob. 50PCh. 18 - Prob. 51PCh. 18 - Prob. 53PCh. 18 - Prob. 54PCh. 18 - Prob. 55PCh. 18 - A sample of ideal gas must contain at least N =...Ch. 18 - In outer space the density of matter is about one...Ch. 18 - Calculate approximately the total translational...Ch. 18 - (a) Estimate the rms speed of an amino acid, whose...Ch. 18 - The escape speed from the Earth is 1.12 104 m/s,...Ch. 18 - Prob. 61GPCh. 18 - Prob. 62GPCh. 18 - Consider a container of oxygen gas at a...Ch. 18 - In humid climates, people constantly dehumidify...Ch. 18 - Prob. 65GPCh. 18 - Prob. 66GPCh. 18 - Prob. 67GPCh. 18 - At room temperature, it takes approximately 2.45 ...Ch. 18 - Calculate the total water vapor pressure in the...Ch. 18 - Prob. 70GPCh. 18 - The density of atoms, mostly hydrogen, in...Ch. 18 - Prob. 72GPCh. 18 - A sauna has 8.5 m3 of air volume, and the...Ch. 18 - Prob. 74GPCh. 18 - Prob. 75GP
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