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The pressure gauge on a cylinder of gas registers the gauge pressure, which is the difference between the interior pressure and the exterior pressure P0. Let’s call the gauge pressure Pg. When the cylinder is full, the mass of the gas in it is mi at a gauge pressure of Pgi. Assuming the temperature of the cylinder remains constant, show that the mass of the gas remaining in the cylinder when the pressure reading is Pgf is given by
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Physics for Scientists and Engineers
- An ideal gas is contained in a vessel at 300 K. The temperature of the gas is then increased to 900 K. (i) By what factor does the average kinetic energy of the molecules change, (a) a factor of 9, (b) a factor of 3, (c) a factor of 3, (d) a factor of 1, or (e) a factor of 13? Using the same choices as in part (i), by what factor does each of the following change: (ii) the rms molecular speed of the molecules, (iii) the average momentum change that one molecule undergoes in a collision with one particular wall, (iv) the rate of collisions of molecules with walls, and (v) the pressure of the gas?arrow_forwardCylinder A contains oxygen (O2) gas, and cylinder B contains nitrogen (N2) gas. If the molecules in the two cylinders have the same rms speeds, which of the following statements is false? (a) The two gases haw different temperatures. (b) The temperature of cylinder B is less than the temperature of cylinder A. (c) The temperature of cylinder B is greater than the temperature of cylinder A. (d) The average kinetic energy of the nitrogen molecules is less than the average kinetic energy of the oxygen molecules.arrow_forwardConsider a gas filling two connected chambers that are separated by a removable barrier (Fig. P20.68). The gas molecules on the left (red) are initially at a higher temperature than the ones on the right (blue). When the barrier between the two chambers is removed, the molecules begin to mix and move from one chamber to the other. a. Describe what happens to the temperature in the left chamber and in the right chamber as time goes on, once the barrier is open. Discuss in terms of the mixing of the molecules from each gas. b. Describe what happens to the most probable speed and average speed in the left chamber and in the right chamber as time goes on, once the barrier is open. Do they increase or decrease by the same factor? Explain. FIGURE P20.68 Problems 68 and 69.arrow_forward
- A vertical cylinder of cross-sectional area A is fitted with a tight-fitting, frictionless piston of mass m (Fig. P16.56). The piston is not restricted in its motion in any way and is supported by the gas at pressure P below it. Atmospheric pressure is P0. We wish to find die height h in Figure P16.56. (a) What analysis model is appropriate to describe the piston? (b) Write an appropriate force equation for the piston from this analysis model in terms of P, P0, m, A, and g. (c) Suppose n moles of an ideal gas are in the cylinder at a temperature of T. Substitute for P in your answer to part (b) to find the height h of the piston above the bottom of the cylinder.arrow_forwardFor a temperature increase of 10 at constant volume, what is the heat absorbed by (a) 3.0 mol of a dilute monatomic gas; (b) 0.50 mol of a dilute diatomic gas; and (c) 15 mol of a dilute polyatomic gas?arrow_forwardA sealed cubical container 20.0 cm on a side contains a gas with three times Avogadros number of neon atoms at a temperature of 20.0C. (a) Find the internal energy of the gas. (b) Find the total translational kinetic energy of the gas. (c) Calculate the average kinetic energy per atom, (d) Use Equation 10.13 to calculate the gas pressure. (e) Calculate the gas pressure using the ideal gas law (Eq. 10.8).arrow_forward
- One cylinder contains helium gas and another contains krypton gas at the same temperature. Mark each of these statements true, false, or impossible to determine from the given information. (a) The rms speeds of atoms in the two gases are the same. (b) The average kinetic energies of atoms in the two gases are the same. (c) The internal energies of 1 mole of gas in each cylinder are the same. (d) The pressures in the two cylinders ale the same.arrow_forward(a) Show that the density of an ideal gas occupying a volume V is given by = PM/KT, where M is the molar mass. (b) Determine the density of oxygen gas at atmospheric pressure and 20.0C.arrow_forwardConsider the Maxwell-Boltzmann distribution function plotted in Problem 28. For those parameters, determine the rms velocity and the most probable speed, as well as the values of f(v) for each of these values. Compare these values with the graph in Problem 28. 28. Plot the Maxwell-Boltzmann distribution function for a gas composed of nitrogen molecules (N2) at a temperature of 295 K. Identify the points on the curve that have a value of half the maximum value. Estimate these speeds, which represent the range of speeds most of the molecules are likely to have. The mass of a nitrogen molecule is 4.68 1026 kg. Equation 20.18 can be used to find the rms velocity given the temperature, Boltzmanns constant, and the mass of the atom or molecule. The mass of a nitrogen molecule is 4.68 1026 kg. vrms=3kBTm=3(1.381023J/K)4.681026kg=511m/s Using the results of Problem 28 and the rms velocity, we can calculate the value of f(v). f(vrms) = (3.11 108)(511)2 e(5.75106(511)2) = 0.00181 The most probable speed, for which this function has its maximum value, is given by Equation 20.20. vmp=2kBTm=2(1.381023J/K)(295K)4.681026kg=417m/s f(vmp) = (3.11108)(417)2 e(5.75106(417)2) = 0.00199 We plot these points on the speed distribution. The most probable speed is indeed at the peak of the distribution function. Since the function is not symmetric, the rms velocity is somewhat higher than the most probable speed. Figure P20.29ANSarrow_forward
- A gas is at 200 K. If we wish to double the rms speed of the molecules of the gas, to what value must we raise its temperature? (a) 283 K (b) 400 K (c) 566 K (d) 800 K (e) 1 130 Karrow_forwardA cylinder with a piston holds 0.50 m3 of oxygen at an absolute pressure of 4.0 atm. The piston is pulled outward, increasing the volume of the gas until the pressure drops to 1.0 atm. If the temperature stays constant, what new volume does the gas occupy? (a) 1.0 m3 (b) 1.5 m3 (c) 2.0 m3 (d) 0.12 m3 (e) 2.5 m3arrow_forwardOn a hot summer day, the density of air at atmospheric pressure at 35.0C is 1.1455 kg/m3. a. What is the number of moles contained in 1.00 m3 of an ideal gas at this temperature and pressure? b. Avogadros number of air molecules has a mass of 2.85 102 kg. What is the mass of 1.00 m3 of air? c. Does the value calculated in part (b) agree with the stated density of air at this temperature?arrow_forward
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