Chemistry
Chemistry
9th Edition
ISBN: 9781133611097
Author: Steven S. Zumdahl
Publisher: Cengage Learning
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Textbook Question
Chapter 18, Problem 82E

An electrochemical cell consists of a nickel metal electrode immersed in a solution with [Ni2+] = 1.0 M separated by a porous disk from an aluminum metal electrode immersed in a solution with [Al3+] = 1.0 M. Sodium hydroxide is added to the aluminum compartment, causing Al(OH)3(s) to precipitate. After precipitation of Al(OH)3 has ceased, the concentration of OH is 1.0 × 10−4 M and the measured cell potential is 1.82 V. Calculate the Ksp value for Al(OH)3.

Al(OH) 3 ( s ) Al 3+ ( a q ) + 3OH ( a q ) K sp = ?

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Chapter 18 Solutions

Chemistry

Ch. 18 - In making a specific galvanic cell, explain how...Ch. 18 - Prob. 3ALQCh. 18 - Prob. 4ALQCh. 18 - Sketch a cell that forms iron metal from iron(II)...Ch. 18 - Which of the following is the best reducing agent:...Ch. 18 - You are told that metal A is a better reducing...Ch. 18 - Explain the following relationships: G and w, cell...Ch. 18 - Explain why cell potentials are not multiplied by...Ch. 18 - What is the difference between and ? When is equal...Ch. 18 - Consider the following galvanic cell: What happens...Ch. 18 - Look up the reduction potential for Fe3+ to Fe2+....Ch. 18 - If the cell potential is proportional to work and...Ch. 18 - Is the following statement true or false?...Ch. 18 - Define oxidation and reduction in terms of both...Ch. 18 - Assign oxidation numbers to all the atoms in each...Ch. 18 - Specify which of the following equations represent...Ch. 18 - The Ostwald process for the commercial production...Ch. 18 - What is electrochemistry? What are redox...Ch. 18 - When balancing equations in Chapter 3, we did not...Ch. 18 - When magnesium metal is added to a beaker of...Ch. 18 - How can one construct a galvanic cell from two...Ch. 18 - The free energy change for a reaction, G, is an...Ch. 18 - What is wrong with the following statement: The...Ch. 18 - When jump-starting a car with a dead battery, the...Ch. 18 - In theory, most metals should easily corrode in...Ch. 18 - Consider the electrolysis of a molten salt of some...Ch. 18 - Consider the following electrochemical cell: a. If...Ch. 18 - Prob. 29ECh. 18 - Prob. 30ECh. 18 - Balance the following oxidationreduction reactions...Ch. 18 - Balance the following oxidationreduction reactions...Ch. 18 - Chlorine gas was first prepared in 1774 by C. W....Ch. 18 - Prob. 34ECh. 18 - Consider the following galvanic cell: Label the...Ch. 18 - Consider the following galvanic cell: a. Label the...Ch. 18 - Sketch the galvanic cells based on the following...Ch. 18 - Sketch the galvanic cells based on the following...Ch. 18 - Calculate values for the galvanic cells in...Ch. 18 - Calculate values for the galvanic cells in...Ch. 18 - Sketch the galvanic cells based on the following...Ch. 18 - Sketch the galvanic cells based on the following...Ch. 18 - Give the standard line notation for each cell in...Ch. 18 - Give the standard line notation for each cell in...Ch. 18 - Consider the following galvanic cells: For each...Ch. 18 - Give the balanced cell equation and determine for...Ch. 18 - Calculate values for the following g cells. Which...Ch. 18 - Calculate values for the following cells. Which...Ch. 18 - Chlorine dioxide (C1O2), which is produced by the...Ch. 18 - The amount of manganese in steel is determined by...Ch. 18 - Calculate the maximum amount of work that can be...Ch. 18 - Calculate the maximum amount of work that can be...Ch. 18 - Estimate for the half-reaction 2H2O+2eH2+2OH given...Ch. 18 - The equation G = nF also can be applied to...Ch. 18 - Glucose is the major fuel for most living cells....Ch. 18 - Direct methanol fuel cells (DMFCs) have shown some...Ch. 18 - Using data from Table 18.1, place the following in...Ch. 18 - Using data from Table 18.1, place the following in...Ch. 18 - Answer the following questions using data from...Ch. 18 - Answer the following questions using data from...Ch. 18 - Consider only the species (at standard conditions)...Ch. 18 - Prob. 62ECh. 18 - Use the table of standard reduction potentials...Ch. 18 - Use the table of standard reduction potentials...Ch. 18 - Prob. 65ECh. 18 - Prob. 66ECh. 18 - Consider the concentration cell in Fig. 17-10. If...Ch. 18 - Consider the concentration cell shown below....Ch. 18 - Consider a concentration cell similar to the one...Ch. 18 - The overall reaction in the lead storage battery...Ch. 18 - Calculate the pH of the cathode compartment for...Ch. 18 - Consider the cell described below:...Ch. 18 - Consider the cell described below:...Ch. 18 - Calculate G and K at 25C for the reactions in...Ch. 18 - Calculate G and K at 25C for the reactions in...Ch. 18 - Consider the galvanic cell based on the following...Ch. 18 - Consider the galvanic cell based on the following...Ch. 18 - An electrochemical cell consists of a standard...Ch. 18 - Prob. 80ECh. 18 - An electrochemical cell consists of a standard...Ch. 18 - An electrochemical cell consists of a nickel metal...Ch. 18 - Consider a concentration cell that has both...Ch. 18 - You have a concentration cell in which the cathode...Ch. 18 - Under standard conditions, what reaction occurs,...Ch. 18 - A disproportionation reaction involves a substance...Ch. 18 - Consider the following galvanic cell at 25C:...Ch. 18 - An electrochemical cell consists of a silver metal...Ch. 18 - Prob. 89ECh. 18 - For the following half-reaction, = 2.07 V:...Ch. 18 - Calculate for the following half-reaction:...Ch. 18 - The solubility product for CuI(s) is 1.1 102...Ch. 18 - How long will it take to plate out each of the...Ch. 18 - The electrolysis of BiO+ produces pure bismuth....Ch. 18 - What mass of each of the following substances can...Ch. 18 - Aluminum is produced commercially by the...Ch. 18 - An unknown metal M is electrolyzed. It took 74.1 s...Ch. 18 - Prob. 98ECh. 18 - What volume of F2 gas, at 25C and 1.00 atm, is...Ch. 18 - What volumes of H2(g) and O2(g) at STP are...Ch. 18 - A single HallHeroult cell (as shown in Fig. 17-22)...Ch. 18 - A factory wants to produce 1.00 103 kg barium...Ch. 18 - It took 2.30 min using a current of 2.00 A to...Ch. 18 - A solution containing Pt4+ is electrolyzed with a...Ch. 18 - A solution at 25C contains 1.0 M Cd2+, 1.0 M Ag+,...Ch. 18 - Prob. 106ECh. 18 - In the electrolysis of an aqueous solution of...Ch. 18 - Copper can be plated onto a spoon by placing the...Ch. 18 - Prob. 109ECh. 18 - Prob. 110ECh. 18 - What reactions take place at the cathode and the...Ch. 18 - What reaction will take place at the Cathode and...Ch. 18 - Gold is produced electrochemically from an aqueous...Ch. 18 - The blood alcohol (C2H5OH) level can be determined...Ch. 18 - The saturated calomel electrode. abbreviated SCE....Ch. 18 - Consider the following half-reactions: Explain why...Ch. 18 - Consider the standard galvanic cell based on the...Ch. 18 - A standard galvanic cell is constructed so that...Ch. 18 - The black silver sulfide discoloration of...Ch. 18 - Prob. 120AECh. 18 - When aluminum foil is placed in hydrochloric acid,...Ch. 18 - Prob. 122AECh. 18 - A fuel cell designed to react grain alcohol with...Ch. 18 - The overall reaction and equilibrium constant...Ch. 18 - Prob. 125AECh. 18 - The overall reaction and standard cell potential...Ch. 18 - Prob. 127AECh. 18 - The ultimate electron acceptor in the respiration...Ch. 18 - One of the few industrial-scale processes that...Ch. 18 - It took 150. s for a current of 1.25 A to plate...Ch. 18 - Prob. 131AECh. 18 - In the electrolysis of a sodium chloride solution,...Ch. 18 - An aqueous solution of an unknown salt of...Ch. 18 - Which of the following statement(s) is/are true?...Ch. 18 - Consider a galvanic cell based on the following...Ch. 18 - Prob. 136CWPCh. 18 - Consider a galvanic cell based on the following...Ch. 18 - An electrochemical cell consists of a silver metal...Ch. 18 - An aqueous solution of PdCl2 is electrolyzed for...Ch. 18 - Prob. 140CPCh. 18 - Prob. 141CPCh. 18 - The overall reaction in the lead storage battery...Ch. 18 - Consider the following galvanic cell: Calculate...Ch. 18 - A zinc-copper battery is constructed at follows at...Ch. 18 - A galvanic cell is based on the following...Ch. 18 - Consider a cell based on the following...Ch. 18 - Prob. 147CPCh. 18 - You have a concentration cell with Cu electrodes...Ch. 18 - A galvanic cell is based on the following...Ch. 18 - Given the following two standard reduction...Ch. 18 - Consider the following galvanic cell: Calculate...Ch. 18 - Prob. 152CPCh. 18 - Consider the following galvanic cell: A 15 0-mole...Ch. 18 - When copper reacts with nitric acid, a mixture of...Ch. 18 - The following standard reduction potentials have...Ch. 18 - An electrochemical cell is set up using the...Ch. 18 - Three electrochemical cells were connected in...Ch. 18 - A silver concentration cell is set up at 25C as...Ch. 18 - A galvanic cell is based on the following...Ch. 18 - The table below lists the cell potentials for the...
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  • An electrochemical cell is made by placing a zinc electrode in 1.00 L of 0.200 M ZnSO4 solution and a copper electrode in 1.00 L of 0.0100 M CuCl2 solution. a What is the initial voltage of this cell when it is properly constructed? b Calculate the final concentration of Cu2+ in this cell if it is allowed to produce an average current of 1.0 amp for 225 s.
    An electrode is prepared by dipping a silver strip into a solution saturated with silver thiocyanate, AgSCN, and containing 0.10 M SCN . The cell potential of the voltaic cell constructed by connecting this electrode as the cathode to the standard hydrogen half-cell as the anode is 0.45 V. What is the solubility product of silver thiocyanate?
    A galvanic cell is based on the following half-reactions: In this cell, the copper compartment contains a copper electrode and [Cu2+] = 1.00 M, and the vanadium compartment contains a vanadium electrode and V2+ at an unknown concentration. The compartment containing the vanadium (1.00 L of solution) was titrated with 0.0800 M H2EDTA2, resulting in the reaction H2EDTA2(aq)+V2+(aq)VEDTA2(aq)+2H+(aq)K=? The potential of the cell was monitored to determine the stoichiometric point for the process, which occurred at a volume of 500.0 mL H2EDTA2 solution added. At the stoichiometric point, was observed to be 1 .98 V. The solution was buffered at a pH of 10.00. a. Calculate before the titration was carried out. b. Calculate the value of the equilibrium constant, K, for the titration reaction. c. Calculate at the halfway point in the titration.
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