Chemistry: Principles and Reactions
8th Edition
ISBN: 9781305079373
Author: William L. Masterton, Cecile N. Hurley
Publisher: Cengage Learning
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Chapter 19, Problem 40QAP
Interpretation Introduction
Interpretation: The reason for diamagnetic nature of
Concept introduction: A transition metal cation has no outer s- electrons available for bonding, rather the inner d -electrons (in case of 3d transition metal elements) are available for making coordinate bonds with the ligands. Electrons are distributed in the five d- orbitals according to Hund’s rule which results in a maximum number of unpaired electrons.The abbreviated electronic configuration of an element depicts the electronic configuration of the elements which represents the noble gas configuration.
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Chapter 19 Solutions
Chemistry: Principles and Reactions
Ch. 19 - Prob. 1QAPCh. 19 - Prob. 2QAPCh. 19 - Prob. 3QAPCh. 19 - Platinum(II) forms many complexes, among them...Ch. 19 - Prob. 5QAPCh. 19 - What is the coordination number of the central...Ch. 19 - Prob. 7QAPCh. 19 - Prob. 8QAPCh. 19 - Prob. 9QAPCh. 19 - Prob. 10QAP
Ch. 19 - Prob. 11QAPCh. 19 - Prob. 12QAPCh. 19 - What is the mass percent of sulfur in the...Ch. 19 - Prob. 14QAPCh. 19 - There are four iron atoms in each hemoglobin...Ch. 19 - Vitamin B12 is a coordination compound with cobalt...Ch. 19 - Prob. 17QAPCh. 19 - Prob. 18QAPCh. 19 - Name the following ions or compounds (a)...Ch. 19 - Name the following ions or compounds (a)...Ch. 19 - Prob. 21QAPCh. 19 - Prob. 22QAPCh. 19 - Sketch the geometry of (a)...Ch. 19 - Sketch the geometry of (a) tans-[Cu(Br)2(H2O)4]...Ch. 19 - Prob. 25QAPCh. 19 - Prob. 26QAPCh. 19 - Which of the following octahedral complexes show...Ch. 19 - Prob. 28QAPCh. 19 - Prob. 29QAPCh. 19 - Prob. 30QAPCh. 19 - Prob. 31QAPCh. 19 - Prob. 32QAPCh. 19 - Write an abbreviated orbital diagram and determine...Ch. 19 - Prob. 34QAPCh. 19 - Give the electron distribution in low-spin and/or...Ch. 19 - Prob. 36QAPCh. 19 - Prob. 37QAPCh. 19 - Prob. 38QAPCh. 19 - Prob. 39QAPCh. 19 - Prob. 40QAPCh. 19 - Give the number of unpaired electrons in...Ch. 19 - Prob. 42QAPCh. 19 - Ti(NH3)63+ has a d-orbital electron transition at...Ch. 19 - has a crystal field splitting energy, o, of...Ch. 19 - Prob. 45QAPCh. 19 - Prob. 46QAPCh. 19 - Prob. 47QAPCh. 19 - Prob. 48QAPCh. 19 - Prob. 49QAPCh. 19 - Indicate whether each of the following is true or...Ch. 19 - A child eats 10.0 g of paint containing 5.0% Pb....Ch. 19 - A certain coordination compound has the simplest...Ch. 19 - Prob. 53QAPCh. 19 - In the [Ti(H2O)63+] ion, the splitting between the...
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- Which of the following ligands is expected to be monodentate, and which might be polydentate? (a) CH3NH2 (b) CH3CN (c) N3 (d) en (e) Br (f) phenarrow_forwardClassify each ligand as monodentate, bidentate, and so on. (a) (CH3)3P (b) H2N(CH2)2NH(CH2)2NH2 (c) H2Oarrow_forwardIn each of the following pairs of complexes, which one would undergo the slower ligand dissociation reactions? Justify your answers. a. [Cr(NH3)4Cl2] + or [Mn(NH3)4Cl2] 2+ ? b. Fe(en)2(H2O)2 or Ru(en)2(H2O)2 ? c. [Co(CN)6] 3− or [CoBr6] 3− ?arrow_forward
- Which of these complexes would have the greatest ∆O value? [CoF6]3- [CoCl6]3- [CoBr6]3-arrow_forwardWhich of the following is NOT a monodendate ligand? a. H2O b. H2NCH2CH2NH2 c. OH- d. CN-arrow_forward4 Diamagnetic complexes of cobalt (III) like [Co(NH3)6]3+ and [Co(en)3]3+ are orange- yellow, while paramagnetic cobalt (III) complexes like [CoF6]3– and [Co(H2O)3F3] are blue. Explain, using abridged MO diagrams, this difference in color.arrow_forward
- [Co(ONO)(NH3)5] Cl2 and [Co(NO2(NH3)5]Cl2 interpret the infrared spectroscopy spectrums of complexes to write down the differencesarrow_forwardPredict the d orbital splitting of [RuCl6]2- complex.arrow_forward[CoF6]3- absorbs 700 nm (red) radiation whereas [Co(H2O)6]3+ absorbs 600 nm (orange) radiation. What are the colors (appearance) of the above complexes?arrow_forward
- Crystal field energy diagram for [Mn(CN)6]-3arrow_forwardPredict whether the [Cr(NH3)6]Cl2 complex will be high or low spin configuration knowing that the observed magnetic moment is μobs= 3.3 B.M. Clearly explain it.arrow_forwardexplain why heavier lanthanides form more stable complexes than lighter onesarrow_forward
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