Chemistry: Principles and Reactions
8th Edition
ISBN: 9781305079373
Author: William L. Masterton, Cecile N. Hurley
Publisher: Cengage Learning
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Chapter 19, Problem 43QAP
Ti(NH3)63+ has a d-orbital electron transition at 399 nm. Find Δo at this wavelength.
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Chapter 19 Solutions
Chemistry: Principles and Reactions
Ch. 19 - Prob. 1QAPCh. 19 - Prob. 2QAPCh. 19 - Prob. 3QAPCh. 19 - Platinum(II) forms many complexes, among them...Ch. 19 - Prob. 5QAPCh. 19 - What is the coordination number of the central...Ch. 19 - Prob. 7QAPCh. 19 - Prob. 8QAPCh. 19 - Prob. 9QAPCh. 19 - Prob. 10QAP
Ch. 19 - Prob. 11QAPCh. 19 - Prob. 12QAPCh. 19 - What is the mass percent of sulfur in the...Ch. 19 - Prob. 14QAPCh. 19 - There are four iron atoms in each hemoglobin...Ch. 19 - Vitamin B12 is a coordination compound with cobalt...Ch. 19 - Prob. 17QAPCh. 19 - Prob. 18QAPCh. 19 - Name the following ions or compounds (a)...Ch. 19 - Name the following ions or compounds (a)...Ch. 19 - Prob. 21QAPCh. 19 - Prob. 22QAPCh. 19 - Sketch the geometry of (a)...Ch. 19 - Sketch the geometry of (a) tans-[Cu(Br)2(H2O)4]...Ch. 19 - Prob. 25QAPCh. 19 - Prob. 26QAPCh. 19 - Which of the following octahedral complexes show...Ch. 19 - Prob. 28QAPCh. 19 - Prob. 29QAPCh. 19 - Prob. 30QAPCh. 19 - Prob. 31QAPCh. 19 - Prob. 32QAPCh. 19 - Write an abbreviated orbital diagram and determine...Ch. 19 - Prob. 34QAPCh. 19 - Give the electron distribution in low-spin and/or...Ch. 19 - Prob. 36QAPCh. 19 - Prob. 37QAPCh. 19 - Prob. 38QAPCh. 19 - Prob. 39QAPCh. 19 - Prob. 40QAPCh. 19 - Give the number of unpaired electrons in...Ch. 19 - Prob. 42QAPCh. 19 - Ti(NH3)63+ has a d-orbital electron transition at...Ch. 19 - has a crystal field splitting energy, o, of...Ch. 19 - Prob. 45QAPCh. 19 - Prob. 46QAPCh. 19 - Prob. 47QAPCh. 19 - Prob. 48QAPCh. 19 - Prob. 49QAPCh. 19 - Indicate whether each of the following is true or...Ch. 19 - A child eats 10.0 g of paint containing 5.0% Pb....Ch. 19 - A certain coordination compound has the simplest...Ch. 19 - Prob. 53QAPCh. 19 - In the [Ti(H2O)63+] ion, the splitting between the...
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- Platinum(II) forms many complexes, among them those with the following ligands. Give the formula and charge of each complex. (a) two ammonia molecules and one oxalate ion (C2O42-) (b) two ammonia molecules, one thiocyanate ion (SCN-), and one bromide ion (c) one ethylenediamine molecule and two nitrite ionsarrow_forwardWould you expect the complex [Co(en)3]Cl3 to have any unpaired electrons? Any isomers?arrow_forwardAn aqueous solution of [Rh(C2O4)3]3− is yellow. Predict the approximate wavelength and predominant color of light absorbed by the complex.arrow_forward
- When water ligands in [Ti(H2O)6]3+ are replaced by CN- ligands to give [Ti(CN)6]3-, the maximum absorption shifts from 500 nm to 450 nm. Is this shift in the expected direction? Explain.arrow_forwardHow many unpaired d electrons does ion [Fe(CN)6]3— have when it has a low spin electron configuration?arrow_forward3. At 525 nm, the permanganate ions absorb which color of light?arrow_forward
- The compound hexaamminecobalt(III) chloride is diamagnetic and orange in color with a single absorption peak in its visible absorption spectrum. Is [Co(NH3)6]3+ a high-spin complex or a low-spin complex?arrow_forwardHow do I find the electronic configuration of an unknown transition metal? For instance I am given [M(H2O)6]+2, where M is the unknown first row transition metal with a magnetic moment of 2.83. I know it's oxidation state is 2+arrow_forwardThe complexes (V(H2O)6)^3+ and (VF6)3- are known .what gives rise to their color and which of them has a greater wavelength and why?arrow_forward
- Which of the following transition metals has a vacant f orbital? Cd V W Zrarrow_forwardThe spectrochemical series is I– < Br– < Cl– < F– < OH– < H2O < NH3 < en < NO2– < CN– Which of the following complexes has the greatest number of unpaired electrons? Select one: A. [Fe(CN)6]4– B. [Ni(CN)6]4– C. [Mn(CN)6]4– D. Two of the complexes have an equal number of unpaired electrons that are the greatest number of unpaired electrons. E. [Co(NH3)6]3+ The correct answer should be "B," but can someone explain why?arrow_forwardGive the number of (valence) d electrons associated withthe central metal ion in each of the following complexes:(a) K3[Fe(CN)6], (b) [Mn(H2O)6](NO3)2, (c) Na[Ag(CN)2],(d) [Cr(NH3)4Br2]ClO4, (e) [Sr(EDTA)]2 - .arrow_forward
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