Organic Chemistry
Organic Chemistry
9th Edition
ISBN: 9781305080485
Author: John E. McMurry
Publisher: Cengage Learning
Question
Chapter 19.1, Problem 1P
Interpretation Introduction

a)

Organic Chemistry, Chapter 19.1, Problem 1P , additional homework tip  1

Interpretation:

The name of the ketone shown is to be given.

Concept introduction:

Ketones are named by replacing the terminal –e of the parent alkane with –one. The parent chain is the longest one that includes the ketone group and the numbering begins at the end nearer to the carbonyl carbon. If other functional groups are present the double bonded oxygen is considered as a substituent on the parent chain with the prefix –oxo.

To give:

The name of the ketone shown.

Interpretation Introduction

b)

Organic Chemistry, Chapter 19.1, Problem 1P , additional homework tip  2

Interpretation:

The name of the aldehyde shown is to be given.

Concept introduction:

Aldehydes are named by replacing the terminal –e of the parent alkane with –al. The parent chain is the longest one that includes the –CHO group and the –CHO group is numbered as carbon 1. For cyclic aldehydes in which the –CHO group is directly attached to the ring, the suffix –carbaldehyde is used.

To give:

The name of the aldehyde shown.

Interpretation Introduction

c)

Organic Chemistry, Chapter 19.1, Problem 1P , additional homework tip  3

Interpretation:

The name of the diketone shown is to be given.

Concept introduction:

Ketones are named by replacing the terminal –e of the parent alkane with –one. The parent chain is the longest one that includes the ketone group and the numbering begins at the end nearer to the carbonyl carbon. If other functional groups are present the double bonded oxygen is considered as a substituent on the parent chain with the prefix –oxo.

To give:

The name of the diketone shown.

Interpretation Introduction

d)

Organic Chemistry, Chapter 19.1, Problem 1P , additional homework tip  4

Interpretation:

The name of the aldehyde shown is to be given.

Concept introduction:

Aldehydes are named by replacing the terminal –e of the parent alkane with –al. The parent chain is the longest one that includes the -CHO group and the –CHO group is numbered as carbon 1. For cyclic aldehydes in which the –CHO group is directly attached to the ring, the suffix –carbaldehyde is used.

To give:

The name of the aldehyde shown.

Interpretation Introduction

e)

Organic Chemistry, Chapter 19.1, Problem 1P , additional homework tip  5

Interpretation:

The name of the aldehyde shown is to be given.

Concept introduction:

Aldehydes are named by replacing the terminal –e of the parent alkane with –al. The parent chain is the longest one that includes the –CHO group and the –CHO group is numbered as carbon 1. For cyclic aldehydes in which the –CHO group is directly attached to the ring, the suffix –carbaldehyde is used.

To give:

The name of the aldehyde shown.

Interpretation Introduction

f)

Organic Chemistry, Chapter 19.1, Problem 1P , additional homework tip  6

Interpretation:

The name of the ketone shown is to be given.

Concept introduction:

Ketones are named by replacing the terminal –e of the parent alkane with –one. For alicyclic ketones the number of carbons in the ring determines the parent name. The numbering starts from the carbonyl carbon and the numbering is done such a way that other functional groups and/or substituents get the lowest possible number.

To give:

The name of the ketone shown.

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Chapter 19 Solutions

Organic Chemistry

Ch. 19.8 - Prob. 11PCh. 19.8 - Prob. 12PCh. 19.9 - Prob. 13PCh. 19.10 - Prob. 14PCh. 19.10 - Prob. 15PCh. 19.11 - What carbonyl compound and what phosphorus ylide...Ch. 19.11 - -Carotene, a yellow food-coloring agent and...Ch. 19.12 - Prob. 18PCh. 19.12 - Prob. 19PCh. 19.13 - Prob. 20PCh. 19.13 - Treatment of 2-cyclohexenone with HCN/KCN yields a...Ch. 19.13 - How might conjugate addition reactions of lithium...Ch. 19.14 - How might you use IR spectroscopy to determine...Ch. 19.14 - Prob. 24PCh. 19.14 - Prob. 25PCh. 19.14 - Prob. 26PCh. 19.SE - Each of the following substances can be prepared...Ch. 19.SE - Prob. 28VCCh. 19.SE - Prob. 29VCCh. 19.SE - Prob. 30MPCh. 19.SE - Prob. 31MPCh. 19.SE - Prob. 32MPCh. 19.SE - Prob. 33MPCh. 19.SE - Prob. 34MPCh. 19.SE - Prob. 35MPCh. 19.SE - It is not uncommon for organic chemists to prepare...Ch. 19.SE - Prob. 37MPCh. 19.SE - Prob. 38MPCh. 19.SE - Prob. 39MPCh. 19.SE - Prob. 40MPCh. 19.SE - Aldehydes and ketones react with thiols to yield...Ch. 19.SE - Prob. 42MPCh. 19.SE - When cyclohexanone is heated in the presence of a...Ch. 19.SE - Prob. 44MPCh. 19.SE - The Meerwein-Ponndorf-Verley reaction involves...Ch. 19.SE - Propose a mechanism to account for the formation...Ch. 19.SE - Prob. 47MPCh. 19.SE - Prob. 48MPCh. 19.SE - Treatment of an , -unsaturated ketone with basic...Ch. 19.SE - Prob. 50MPCh. 19.SE - Prob. 51MPCh. 19.SE - Prob. 52MPCh. 19.SE - Prob. 53MPCh. 19.SE - Prob. 54APCh. 19.SE - Draw and name the seven aldehydes and ketones with...Ch. 19.SE - Give IUPAC names for the following compounds:Ch. 19.SE - Draw structures of compounds that fit the...Ch. 19.SE - Predict the products of the reaction of (1)...Ch. 19.SE - Show how you might use a Wittig reaction to...Ch. 19.SE - How would you use a Grignard reaction on an...Ch. 19.SE - Prob. 61APCh. 19.SE - Prob. 62APCh. 19.SE - How would you synthesize the following substances...Ch. 19.SE - Carvone is the major constituent of spearmint oil....Ch. 19.SE - How would you synthesize the following compounds...Ch. 19.SE - At what position would you expect to observe IR...Ch. 19.SE - Acidcatalyzed dehydration of...Ch. 19.SE - Choose the structure that best fits the IR...Ch. 19.SE - Propose structures for molecules that meet the...Ch. 19.SE - Prob. 70APCh. 19.SE - Prob. 71APCh. 19.SE - When 4hydroxybutanal is treated with methanol in...Ch. 19.SE - Prob. 73APCh. 19.SE - Prob. 74APCh. 19.SE - Prob. 75APCh. 19.SE - Prob. 76APCh. 19.SE - Prob. 77APCh. 19.SE - Tamoxifen is a drug used in the treatment of...Ch. 19.SE - Compound A, MW 86, shows an IR absorption at 1730...Ch. 19.SE - Compound B is isomeric with A (Problem 19-79) and...Ch. 19.SE - The 1HNMR spectrum shown is that of a compound...Ch. 19.SE - Prob. 82APCh. 19.SE - Propose structures for ketones or aldehydes that...Ch. 19.SE - Prob. 84APCh. 19.SE - Prob. 85APCh. 19.SE - The proton and carbon NMR spectra for each of...Ch. 19.SE - The proton NMR spectrum for a compound with...
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