Introduction To General, Organic, And Biochemistry
Introduction To General, Organic, And Biochemistry
12th Edition
ISBN: 9781337571357
Author: Frederick A. Bettelheim, William H. Brown, Mary K. Campbell, Shawn O. Farrell, Omar Torres
Publisher: Cengage Learning
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Chapter 19.2, Problem 19.3QC
Interpretation Introduction

Interpretation:

Haworth projections for of a-D- mannopyranose and ß-D-mannopyranose should be drawn.

Concept introduction:

A common way of writing structural formula which represent the cyclic structure of monosaccharides is said to be the Haworth projection.

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Which of the following organic compound/s would react to 2,4-DNP test? Indicate YES or NO on the boxes provided below the structure.
Problem 4   thx so much !
Problem 1: It is desired to prepare polyester with the number average molecular weight, Mn- 5000 g/mol by reacting of 1 mol butane-1,4 diol (HO-CH2-CH2-CH2-CH2-OH) with 1 mol of adipic acid (HOOC-CH2-CH2-CH2-CH2-COOH). (a) Write chemical equation illustrating synthesis of the polyester.   (b) Calculate the value of the monomer conversion at which the reaction should be stopped to obtain this polymer, assuming perfect stoichiometric balance. What would be polydispersity index for the polymer obtained?   (c) Assuming that 0.5 mol % of the diol is lost to polymerization by a side reaction (dehydratation to a non-reactive substance), what would be the value of Mn if the reaction was carried out to the same extent as in part (b).   (d) For the polymerization process value of polymerization rate constant is 1.5*102 L/(mol*s) at 100° C. How long would it take to prepare the polyester with the number average molecular weight, M, 5,000 g/mol at 100 ° C? There is no diol loss for this part of…

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